The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(...The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(6)? 3, Z=4. The Pd? ion has an square planar geometry, and is coordinated by four S atom donors from four thiourea molecules. The two Cl- anions found in the apical position balance the charge. In the solid state, the title compound forms three dimensional network structures through hydrogen bonds. The intermolecular hydrogen bonds connect the {Pd4}2+ and chloride ion to contribute to the stability of the structure. CCDC: 193379.展开更多
文摘The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(6)? 3, Z=4. The Pd? ion has an square planar geometry, and is coordinated by four S atom donors from four thiourea molecules. The two Cl- anions found in the apical position balance the charge. In the solid state, the title compound forms three dimensional network structures through hydrogen bonds. The intermolecular hydrogen bonds connect the {Pd4}2+ and chloride ion to contribute to the stability of the structure. CCDC: 193379.
