To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous comb...To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous combustion experiment was carried out in the laboratory. Different stages of the induced spontaneous combustion process were studied by integrating wavelet technology and nonlinear dynamics theory. The results show that ignition points of all the ore samples are above 330 ℃, indicating that sulfide ores of the pyrite mine are difficult to combust spontaneously under normal mining conditions. Spontaneous combustion process includes three stages： incubation stage, development stage and approaching stage. The average temperature rising rate of the three stages are 1.0 ~C/min, 2.0 ~C/min and 4.2 ~C/min, respectively. During the spontaneous combustion process, mean values of approximate entropy and correlation dimension increase at first, and then decrease in the following stage. The mean value of the maximum Lyapunov exponent increases with the passage of reaction time. In a whole, correlation among the three nonlinear parameters firstly weakens, then enhances, and the best correlation period is at approaching stage. As ignition point increases, the maximum Lyapunov exponent of approaching stage decreases. Therefore, combustible tendency of sulfide ores could be qualitatively evaluated based on the maximum Lyapunov exponent of this stage.展开更多
in order to achieve a more efficient way to accurately detect the position of the fire source of spontaneous combustion underground mine, a simple fire source locating method, based on infrared scanning system which c...in order to achieve a more efficient way to accurately detect the position of the fire source of spontaneous combustion underground mine, a simple fire source locating method, based on infrared scanning system which can determine the point where the highest temperature on the surface of igniting ores occurs, was proposed. First, the differential equations that describe heat flow in ore body were presented and the relationship between the surface temperature distribution and the depth and intensity of inner fire source was established with a relatively simple heat transfer model. With the solution of equation, the expression of the relationship between the surface temperature distribution and the inner fire source was deduced and the mathematical-physical model of heat transfer process was set up. Then, with the model, visualization of fire source on the basis of MATLAB simulation platform was realized. The results show that： 1） within 10 m, when the detecting depth is less than 2 m, the temperature perturbation on ores surface can change rapidly, and then slowly; after 4 m, in contrast, it changes very little, and is even close to zero at 10 m; 2） When it is close to self-ignition duration and the detective depths are 2, 5 and 10 m, respectively, the maximum temperature differences are correspondingly 0.5, 0.04 and 0.005 ℃ in the scope of 1 m×1 m; under the same condition, the maximum temperature differences are 1.391, 0.136 and 0.018 ℃, respectively, in the scope of 2 m×2 m. Therefore, this system can be used to measure the temperature differences on the surface of ore body and determine the highest temperature point directly. Also, it is possible to determine the depth of fire source and its intensity by locating method of fire source indirectly.展开更多
Three representative sulfide ore samples were collected from typical metal mines,and their corresponding pre-oxidized products were obtained under nature environment.The thermal behaviors of each sample at heating rat...Three representative sulfide ore samples were collected from typical metal mines,and their corresponding pre-oxidized products were obtained under nature environment.The thermal behaviors of each sample at heating rates of 5,10,15 and 20 °C/min in air flow from ambient temperature to 800 °C were studied by simultaneous thermal analysis and the TG/DSC curves before and after the pre-oxidation were compared.By the peak temperature of DTG curves,the whole reaction process for each sample was divided into different stages,and the apparent activation energies were calculated by the Ozawa-Flynn-Wall method.The results show that the reaction process of each sample after pre-oxidation is more complex,with quicker reaction rates,fewer heat production quantities,and higher or lower ignition-points.The apparent activation energies decrease from 364.017-474.228 kJ/mol to 244.523- 333.161 kJ/mol.Therefore,sulfide ores are more susceptible to spontaneous combustion after the pre-oxidation.展开更多
基金Projects(51304238,51534008)supported by the National Natural Science Foundation of ChinaProject(2015CX005)supported by Innovation Driven Plan of Central South University,China
文摘To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous combustion experiment was carried out in the laboratory. Different stages of the induced spontaneous combustion process were studied by integrating wavelet technology and nonlinear dynamics theory. The results show that ignition points of all the ore samples are above 330 ℃, indicating that sulfide ores of the pyrite mine are difficult to combust spontaneously under normal mining conditions. Spontaneous combustion process includes three stages： incubation stage, development stage and approaching stage. The average temperature rising rate of the three stages are 1.0 ~C/min, 2.0 ~C/min and 4.2 ~C/min, respectively. During the spontaneous combustion process, mean values of approximate entropy and correlation dimension increase at first, and then decrease in the following stage. The mean value of the maximum Lyapunov exponent increases with the passage of reaction time. In a whole, correlation among the three nonlinear parameters firstly weakens, then enhances, and the best correlation period is at approaching stage. As ignition point increases, the maximum Lyapunov exponent of approaching stage decreases. Therefore, combustible tendency of sulfide ores could be qualitatively evaluated based on the maximum Lyapunov exponent of this stage.
基金Project(2006BAK04B03) supported by the National Basic Research Program of ChinaProject(CX2009B053) supported by Innovation Foundation for Postgraduate Students of Hunan Province,ChinaProject(2009ybfz08) supported by the Doctoral Dissertation of Central South University,China
文摘in order to achieve a more efficient way to accurately detect the position of the fire source of spontaneous combustion underground mine, a simple fire source locating method, based on infrared scanning system which can determine the point where the highest temperature on the surface of igniting ores occurs, was proposed. First, the differential equations that describe heat flow in ore body were presented and the relationship between the surface temperature distribution and the depth and intensity of inner fire source was established with a relatively simple heat transfer model. With the solution of equation, the expression of the relationship between the surface temperature distribution and the inner fire source was deduced and the mathematical-physical model of heat transfer process was set up. Then, with the model, visualization of fire source on the basis of MATLAB simulation platform was realized. The results show that： 1） within 10 m, when the detecting depth is less than 2 m, the temperature perturbation on ores surface can change rapidly, and then slowly; after 4 m, in contrast, it changes very little, and is even close to zero at 10 m; 2） When it is close to self-ignition duration and the detective depths are 2, 5 and 10 m, respectively, the maximum temperature differences are correspondingly 0.5, 0.04 and 0.005 ℃ in the scope of 1 m×1 m; under the same condition, the maximum temperature differences are 1.391, 0.136 and 0.018 ℃, respectively, in the scope of 2 m×2 m. Therefore, this system can be used to measure the temperature differences on the surface of ore body and determine the highest temperature point directly. Also, it is possible to determine the depth of fire source and its intensity by locating method of fire source indirectly.
基金Project(51304051)supported by the National Natural Science Foundation of ChinaProject(2012J05088)supported by the Natural Science Foundation of Fujian Province,China+1 种基金Project(022409)supported by School Talent Award of Fuzhou University,ChinaProject(2013-XQ-18)supported by Science&Technology Development Foundation of Fuzhou University,China
文摘Three representative sulfide ore samples were collected from typical metal mines,and their corresponding pre-oxidized products were obtained under nature environment.The thermal behaviors of each sample at heating rates of 5,10,15 and 20 °C/min in air flow from ambient temperature to 800 °C were studied by simultaneous thermal analysis and the TG/DSC curves before and after the pre-oxidation were compared.By the peak temperature of DTG curves,the whole reaction process for each sample was divided into different stages,and the apparent activation energies were calculated by the Ozawa-Flynn-Wall method.The results show that the reaction process of each sample after pre-oxidation is more complex,with quicker reaction rates,fewer heat production quantities,and higher or lower ignition-points.The apparent activation energies decrease from 364.017-474.228 kJ/mol to 244.523- 333.161 kJ/mol.Therefore,sulfide ores are more susceptible to spontaneous combustion after the pre-oxidation.
