The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resisti...The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resistivity is always not equal to the real resistivity.To determine the real resistivity,a linear relationship of the measured resistivity,contact resistance and the real resistivity was established.Then experiments for six specimens with varying graphite contents were designed and performed to validate the formulation.Results of experiments demonstrate that the slope of the line represents contact resistance,and the intercept indicates the real resistivity.The effects of graphite content on contact resistance and real resistivity are also revealed.Finally,results show that the influence of contact resistance on accuracy of resisitvity measurement becomes more serious if graphite content is beyond 3%.Hence,it is the time to choose this novel methodology to determine the real resistivity of asphalt concrete by taking account of contact resistance.展开更多
Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electro...Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electrochemical properties of the composites were investigated. The samples were characterized by thermogravimetry and differential thermal analysis （TG/DTA）, X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, cyclic voltammetry （CV）, electrochemical impedance spectroscopy （EIS） and charge/discharge measurements. With increasing the graphite content, the reversible capacity of the Co3O4/graphite composites decreases, while cycling stability improves dramatically, and the addition of graphite obviously decreases the average potential of lithium intercalation/deintercalation. The reversible capacity of the composites with 50% graphite rises from 583 to 725 mA-h/g as the calcination temperature increases from 300 to 500 ℃, and the Co304/graphite composites synthesized at 400 ℃ show the best cycling stability without capacity loss in the initial 20 cycles. peaks, corresponding to the lithium intercalaction/deintercalation for The CV profile of the composite presents two couples of redox graphite and Co3O4, respectively. EIS studies indicate that the electrochemical impedance decreases with increasing the graphite content.展开更多
基金Project(51178348)supported by the National Natural Science Foundation of China
文摘The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resistivity is always not equal to the real resistivity.To determine the real resistivity,a linear relationship of the measured resistivity,contact resistance and the real resistivity was established.Then experiments for six specimens with varying graphite contents were designed and performed to validate the formulation.Results of experiments demonstrate that the slope of the line represents contact resistance,and the intercept indicates the real resistivity.The effects of graphite content on contact resistance and real resistivity are also revealed.Finally,results show that the influence of contact resistance on accuracy of resisitvity measurement becomes more serious if graphite content is beyond 3%.Hence,it is the time to choose this novel methodology to determine the real resistivity of asphalt concrete by taking account of contact resistance.
基金Project(2007CB613607) supported by the National Basic Research Program of China Projects(2009FJ1002, 2009CK3062) supported by the Science and Technology Program of Hunan Province, China
文摘Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electrochemical properties of the composites were investigated. The samples were characterized by thermogravimetry and differential thermal analysis （TG/DTA）, X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, cyclic voltammetry （CV）, electrochemical impedance spectroscopy （EIS） and charge/discharge measurements. With increasing the graphite content, the reversible capacity of the Co3O4/graphite composites decreases, while cycling stability improves dramatically, and the addition of graphite obviously decreases the average potential of lithium intercalation/deintercalation. The reversible capacity of the composites with 50% graphite rises from 583 to 725 mA-h/g as the calcination temperature increases from 300 to 500 ℃, and the Co304/graphite composites synthesized at 400 ℃ show the best cycling stability without capacity loss in the initial 20 cycles. peaks, corresponding to the lithium intercalaction/deintercalation for The CV profile of the composite presents two couples of redox graphite and Co3O4, respectively. EIS studies indicate that the electrochemical impedance decreases with increasing the graphite content.
