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介孔磷钨酸铯盐的液相组装及酸性研究 被引量:1
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作者 王美银 黄道丰 +5 位作者 陈欣 周俊夫 任远航 叶林 岳斌 贺鹤勇 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2021年第9期2734-2741,共8页
以磷钨酸(H_(3)PW_(12)O_(40))和氯化铯(CsCl)为原料,两亲型三嵌段共聚物F127为模板剂,按不同的Cs/P比制备了一系列介孔磷钨酸铯盐(Cs_(x)H_(3)−xPW_(12)O_(40),m-CsPW).通过X射线粉末衍射(XRD)、场发射扫描电子显微镜(FES⁃EM)、场发射... 以磷钨酸(H_(3)PW_(12)O_(40))和氯化铯(CsCl)为原料,两亲型三嵌段共聚物F127为模板剂,按不同的Cs/P比制备了一系列介孔磷钨酸铯盐(Cs_(x)H_(3)−xPW_(12)O_(40),m-CsPW).通过X射线粉末衍射(XRD)、场发射扫描电子显微镜(FES⁃EM)、场发射透射电子显微镜(FETEM)、N_(2)吸附-脱附测试和小角X射线散射(SAXS)等手段对所得样品进行了表征.结果表明,样品是由纳米微晶组装而成的晶态介孔材料.以三甲基膦为探针分子,通过^(31)P魔角旋转固体核磁共振波谱(^(31)P MASNMR)测定了样品酸处理前后的酸密度和酸强度.以5,7-二羟基-4-甲基香豆素的Pech⁃mann缩合反应为模型反应,考察了样品的酸性质与催化活性之间的关系. 展开更多
关键词 多酸 ^(31)P魔角旋转固体核磁共振波谱 酸性 Pechmann缩合
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几种典型盐地植物茎叶表面的扫描电镜观察 被引量:11
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作者 赵曼容 贾恢先 《甘肃农业大学学报》 CAS CSCD 1990年第2期146-151,共6页
本文观察了五种典型盐地植物,发现盐角草和盐琐琐的茎叶表皮细胞外壁向外突出形成圆锥体,使结构、功能和环境条件达到了高度统一。另外还发现花花柴茎叶表面有泌盐腺和泌盐孔。为进一步研究它们的抗盐机理提供了结构依据。
关键词 地植物 表皮 扫描电镜 盐孔
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Distribution and genesis of secondary pores in Paleogene clastic reservoirs of Beidagang structural belt in the Huanghua depression 被引量:4
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作者 SU Nina, JIN Zhenkui, SONG Fan Faculty of Natural Resource and Information Technology, China University of Petroleum, Beijing 102249, China 《Mining Science and Technology》 EI CAS 2010年第1期115-120,共6页
The distribution and genesis of secondary pores in Paleogene clastic reservoirs of Beidagang structural belt in the Huanghua depression have been systematically studied. We investigated sedimentary facies and carried ... The distribution and genesis of secondary pores in Paleogene clastic reservoirs of Beidagang structural belt in the Huanghua depression have been systematically studied. We investigated sedimentary facies and carried out a comprehensive analy-sis of the vast amount of data from casting thin sections, scanning electron microscope and physical data. Then we analyzed the pore types, pore evolution, distribution and genesis of secondary pores in our study area and discussed the factors controlling the distribution of secondary pores. The results show that pores in the study area are largely composed of intergranular dissolution pores and constituent dissolved pores. Three secondary pore zones were developed in the study area at depths of 2800~3400 m, 3600~4200 m and 4500~4800 m. Secondary pores have been formed mainly because carbonate cement, feldspar, clastic debris and other plastic substances were dissolved by organic acid, released during the evolution of organic matter and acid water formed by CO2. The development and distribution of secondary pores are vertically controlled by the maturity time of source rocks and hori-zontally by the distribution of acid water. As well, this distribution was affected by the sedimentary facies belt and the development of fault zones. 展开更多
关键词 Huanghua depression Beidagang structural belt PALEOGENE clastic reservoirs secondary pores controlling factor
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Hydrothermal Synthesis and Mechanism for Formation of Novel Micro-Micro-Mesoporous Aluminosilicate Composite Zeolite 被引量:1
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作者 QiJian Zhao Tianbo +2 位作者 Xu Xin Li Fengyan Sun Guida 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2010年第3期36-42,共7页
A novel micro-micro-mesoporous aluminosilicate LS-BFMZ (low-silica-BEA(beta)-faujasite (Y)-mesoporous) composite zeolite with the MCM-41 type structure was synthesized through a novel process involving the self-... A novel micro-micro-mesoporous aluminosilicate LS-BFMZ (low-silica-BEA(beta)-faujasite (Y)-mesoporous) composite zeolite with the MCM-41 type structure was synthesized through a novel process involving the self- assembly of CTAB surfactant micellae with silica-alumina source originated from alkaline treatment of the beta zeolite. The physical properties of the LS-BFMZ composite zeolite were characterized using various techniques, including XRD, IR and SEM techniques. Meanwhile, a possible mechanism regarding the formation of the LS-BFMZ composite zeolite was proposed. 展开更多
关键词 micro-micro-mesoporous ALUMINOSILICATE hydrothermal synthesis formation mechanism
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