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光热转换纳米容器的制备及其对环氧涂层自修复性能的影响
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作者 张文佼 谢雨桐 +2 位作者 田庆 弓斌 董玉华 《涂料工业》 CAS CSCD 北大核心 2024年第10期9-16,共8页
以金属有机框架NH_(2)-UiO-66为基础,采用“一锅法”负载缓蚀剂BTA与光热材料TiN,合成后再包覆一层与环氧树脂有较好相容性的聚多巴胺,合成了一种具有光热转换性能的纳米容器PDA@(NH_(2)-UiO-66@BTA/TiN),以达到提高光热性能、阻止缓蚀... 以金属有机框架NH_(2)-UiO-66为基础,采用“一锅法”负载缓蚀剂BTA与光热材料TiN,合成后再包覆一层与环氧树脂有较好相容性的聚多巴胺,合成了一种具有光热转换性能的纳米容器PDA@(NH_(2)-UiO-66@BTA/TiN),以达到提高光热性能、阻止缓蚀剂不必要释放的作用。对所得的纳米容器进行形貌表征以及缓蚀剂缓释效果测试,而后将其添加在环氧涂层中进行自修复以及电化学腐蚀测试。结果表明:复合材料具有八面体结构,粒径均匀,聚多巴胺包覆在纳米容器外层后,PDA@NH_(2)-UiO-66@BTA/TiN外壳变厚,外层的聚多巴胺和内层的光热材料TiN能够有效提高纳米容器光热性能,在光照下能够促进缓蚀剂的释放,同时在无光照情况下能够一定程度上阻止内部缓蚀剂的释放。PDA@(NH_(2)-UiO-66@BTA/TiN)作为填料加入环氧树脂后可提高涂层的自修复性能和防腐性能,划痕处的自修复效率达到98.62%,且涂层在光照进行自修复后仍具有较好的防护能力,在3.5%Na Cl溶液中浸泡20 d后阻抗模值依然维持在10~7Ω·cm^(2)以上,且金属基本表面基本没有腐蚀产物。将制备的PDA@(NH_(2)-UiO-66@BTA/TiN)纳米容器添加至环氧涂层中,可显著提升涂层的自修复性和防腐性。 展开更多
关键词 NH2-UiO-66 环氧涂层 光热转换 自修复涂层 电化学腐蚀测试
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电厂循环冷却水阻垢缓蚀剂实验室评价及应用 被引量:10
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作者 刘国强 张燕 +2 位作者 许立国 侯亚琴 高学理 《水处理技术》 CAS CSCD 北大核心 2012年第S1期121-124,共4页
通过循环冷却水静态、动态模拟试验,研究阻垢缓蚀剂性能,确定循环水应用的最佳控制指标。结果表明,试验研究所获取的运行参数对电厂节约用水,循环水系统的防腐、防垢、防菌藻,电厂的安全经济运行和可持续发展具有指导意义。
关键词 循环冷却水处理 阻垢缓蚀剂 动态模拟试验 电化学腐蚀测试测试
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Corrosion damage evolution and mechanical properties of carbon fiber reinforced aluminum laminate 被引量:5
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作者 WU Xin-tong ZHAN Li-hua +3 位作者 HUANG Ming-hui ZHAO Xing WANG Xun ZHAO Guo-qing 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第3期657-668,共12页
Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than ... Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than those with glass or aramid fiber.However,carbon fiber binding metal may lead to galvanic corrosion which limits its application.In this paper,electrochemical methods,optical microscope and scanning electron microscope were used to analyze the corrosion evolution of carbon fiber reinforced aluminum laminate(CARALL)in corrosive environment and explore anti-corrosion ways to protect CARALL.The results show that the connection between carbon fiber and aluminum alloy changes electric potential,causing galvanic corrosion.The galvanic corrosion will obviously accelerate CARALL corroded in solution,leading to a 72.1%decrease in interlaminar shear strength,and the crevice corrosion has a greater impact on CARALL resulting in delamination.The reduction of interlaminar shear strength has a similar linear relationship with the corrosion time.In addition,the adhesive layers between carbon fiber and aluminum alloy cannot protect CARALL,while side edge protection can effectively slow down corrosion rate.Therefore,the exposed edges should be coated with anti-corrosion painting.CARALL has the potential to be used for aerospace components. 展开更多
关键词 carbon fiber reinforced aluminum laminate galvanic corrosion ELECTROCHEMISTRY interlaminar shear strength aluminum alloy
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Galvanic corrosion behavior of plain carbon steel-B_4C composite in 3.5% NaCl solution with electrochemical noise 被引量:2
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作者 S.H.Ettefagh Far A.Davoodi 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第1期1-8,共8页
The galvanic corrosion behavior of metal-matrix composite plain carbon steel/boron carbide (B4C) in 3.5% NaCl solution was studied. The composite was locally produced as a weld band on carbon steel by means of the g... The galvanic corrosion behavior of metal-matrix composite plain carbon steel/boron carbide (B4C) in 3.5% NaCl solution was studied. The composite was locally produced as a weld band on carbon steel by means of the gas tungsten arc welding process and using nickel as the wetting agent. Samples from the weld band, heat-affected zone and parent metal region were extracted precisely and DC/AC electrochemical tests in combination with techniques such as scanning electron microcopy and energy dispersive spectrometry were conducted. The results of the electrochemical tests show that the corrosion resistance of the parent metal sample is higher than that of the welded composite and the HAZ samples. However, as the corrosion potential (Eco^r) of the parent metal is more positive than other two samples, this becomes the cathode in galvanic couples with two other samples. On the other hand, the weld composite sample is also cathodic due to its more positive Ecorr compared to HAZ sample. This means that the HAZ can be particularly at risk of preferential dissolution. The approach can be used in specific areas on plain carbon steel to locally increase hardness and resistance to abrasion and reduce manufacturing costs. 展开更多
关键词 COMPOSITES scanning electron microscopy potentiodynamic polarization electrochemical noise
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