Electrodeposition technique was used to coat calcium phosphate on carbon fiber which can be used to reinforce hydroxyapatite. The differences between fibers treated with and without nitric acid in electrodeposition we...Electrodeposition technique was used to coat calcium phosphate on carbon fiber which can be used to reinforce hydroxyapatite. The differences between fibers treated with and without nitric acid in electrodeposition were evaluated. The X-ray diffractometry results show that CaHPO4·2H2O is obtained as the kind of calcium phosphate coating on carbon fiber. The scanning electron microscopy photographs and deposit kinetic curve indicate that the influences of the functional group attained by nitric acid treatment, the crystal morphology and crystallization of the coating layers on the fiber with and without treatment rate are obviously different. The functional group, especially the acidic group, can act as nucleation centers of electrochemical crystallization.展开更多
In this work,a comprehensive comparison regarding the impacts of M(M=Cu,Co,Mn)substitution for Ni on the structures and the hydrogen storage kinetics of the nanocrystalline and amorphous Mg20Ni10-xMx(M=Cu,Co,Mn; x=0-4...In this work,a comprehensive comparison regarding the impacts of M(M=Cu,Co,Mn)substitution for Ni on the structures and the hydrogen storage kinetics of the nanocrystalline and amorphous Mg20Ni10-xMx(M=Cu,Co,Mn; x=0-4)alloys prepared by melt spinning has been carried out.The analysis of XRD and TEM reveals that the as-spun(M=None,Cu)alloys display an entire nanocrystalline structure,whereas the as-spun(M=Co,Mn)alloys hold a mixed structure of nanocrystalline and amorphous structure when M content x=4,indicating that the substitution of M(M=Co,Mn)for Ni facilitates the glass formation in the Mg2Ni-type alloy.Besides,all the as-spun alloys have a major phase of Mg2Ni but M(M=Co,Mn)substitution brings on the formation of some secondary phases,MgCo2 and Mg phases for M=Co as well as MnNi and Mg phases for M=Mn.Based upon the measurements of the automatic Sieverts apparatus and the automatic galvanostatic system,the impacts engendered by M(M=Cu,Co,Mn)substitution on the gaseous and electrochemical hydrogen storage kinetics of the alloys appear to be evident.The gaseous hydriding kinetics of the alloys first rises and then declines with the growing of M(M=Cu,Co,Mn)content.Particularly,the M(M= Mn)substitution results in a sharp drop in the hydriding kinetics when x=4.The M(M=Cu,Co,Mn)substitution ameliorates the dehydriding kinetics dramatically in the order(M=Co)>(M=Mn)>(M=Cu).The electrochemical kinetics of the alloys visibly grows with M content rising for(M=Cu,Co),while it first increases and then declines for(M=Mn).展开更多
基金Project (2003AA302210) supported by the National High Technology Research and Development Program of Chinaproject(04JJ3083) supported by the Elite Foundation of Hunan Province+1 种基金 China project (030615) supported by the Innovation Pro
文摘Electrodeposition technique was used to coat calcium phosphate on carbon fiber which can be used to reinforce hydroxyapatite. The differences between fibers treated with and without nitric acid in electrodeposition were evaluated. The X-ray diffractometry results show that CaHPO4·2H2O is obtained as the kind of calcium phosphate coating on carbon fiber. The scanning electron microscopy photographs and deposit kinetic curve indicate that the influences of the functional group attained by nitric acid treatment, the crystal morphology and crystallization of the coating layers on the fiber with and without treatment rate are obviously different. The functional group, especially the acidic group, can act as nucleation centers of electrochemical crystallization.
基金Projects(51161015,51371094)supported by National Natural Science Foundations of ChinaProject(2011ZD10)supported by Natural Science Foundation of Inner Mongolia,China
文摘In this work,a comprehensive comparison regarding the impacts of M(M=Cu,Co,Mn)substitution for Ni on the structures and the hydrogen storage kinetics of the nanocrystalline and amorphous Mg20Ni10-xMx(M=Cu,Co,Mn; x=0-4)alloys prepared by melt spinning has been carried out.The analysis of XRD and TEM reveals that the as-spun(M=None,Cu)alloys display an entire nanocrystalline structure,whereas the as-spun(M=Co,Mn)alloys hold a mixed structure of nanocrystalline and amorphous structure when M content x=4,indicating that the substitution of M(M=Co,Mn)for Ni facilitates the glass formation in the Mg2Ni-type alloy.Besides,all the as-spun alloys have a major phase of Mg2Ni but M(M=Co,Mn)substitution brings on the formation of some secondary phases,MgCo2 and Mg phases for M=Co as well as MnNi and Mg phases for M=Mn.Based upon the measurements of the automatic Sieverts apparatus and the automatic galvanostatic system,the impacts engendered by M(M=Cu,Co,Mn)substitution on the gaseous and electrochemical hydrogen storage kinetics of the alloys appear to be evident.The gaseous hydriding kinetics of the alloys first rises and then declines with the growing of M(M=Cu,Co,Mn)content.Particularly,the M(M= Mn)substitution results in a sharp drop in the hydriding kinetics when x=4.The M(M=Cu,Co,Mn)substitution ameliorates the dehydriding kinetics dramatically in the order(M=Co)>(M=Mn)>(M=Cu).The electrochemical kinetics of the alloys visibly grows with M content rising for(M=Cu,Co),while it first increases and then declines for(M=Mn).
