The activated carbon wound supercapacitors with TEABF4/propylene carbonate （PC） and TEABF4/acetonitrile （AN） electrolytes were prepared. The effects of the electrolyte and temperature on the capacitance behavior w...The activated carbon wound supercapacitors with TEABF4/propylene carbonate （PC） and TEABF4/acetonitrile （AN） electrolytes were prepared. The effects of the electrolyte and temperature on the capacitance behavior were investigated by cyclic voltammetry （CV） and constant current charge-discharge. Compared with the PC-based supercapacitor, the AN-based supercapacitor has higher capacitance and lower equivalent serial resistance （RES） at discharge currents ranging from 5 to 1 000 mA and 25 ℃. Moreover, temperature effects are more prominent for PC-based supercapacitor than for AN-based supereapacitor. When the measurement temperature ranges from 60 ℃to -40 ℃ the capacitance changes from 5.1 to 2.5 F and RES changes from 135 to 876 mΩ for the PC-based supercapacior, while the AN-based supercapacitor shows less change in capacitance and RES. Thus AN-based supercapacitor exhibits excellent power characteristics and temperature property.展开更多
基金Project(20803095)supported by the National Natural Science Foundation of ChinaProject(2008AA03Z207)supported by the National High Technology Research and Development Program of China
文摘The activated carbon wound supercapacitors with TEABF4/propylene carbonate （PC） and TEABF4/acetonitrile （AN） electrolytes were prepared. The effects of the electrolyte and temperature on the capacitance behavior were investigated by cyclic voltammetry （CV） and constant current charge-discharge. Compared with the PC-based supercapacitor, the AN-based supercapacitor has higher capacitance and lower equivalent serial resistance （RES） at discharge currents ranging from 5 to 1 000 mA and 25 ℃. Moreover, temperature effects are more prominent for PC-based supercapacitor than for AN-based supereapacitor. When the measurement temperature ranges from 60 ℃to -40 ℃ the capacitance changes from 5.1 to 2.5 F and RES changes from 135 to 876 mΩ for the PC-based supercapacior, while the AN-based supercapacitor shows less change in capacitance and RES. Thus AN-based supercapacitor exhibits excellent power characteristics and temperature property.
