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{[PMo_(12)O_(40)]^(3-)-Pt/PAMAM}_n多层复合膜的制备及对甲醇的电催化氧化活性 被引量:1
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作者 罗明洪 林深 《化学研究与应用》 CAS CSCD 北大核心 2015年第11期1698-1704,共7页
用电化学扫描法制备了{[PMo12O40]3--Pt/PAMAM}n多层复合膜,通过X射线光电子能谱(XPS)、循环伏安测定(CV)和原子力显微镜(AFM)对样品的化学组成和膜的均匀性进行了表征。测试和分析结果表明[PMo12O40]3--Pt和PAMAM通过静电相互作用形成... 用电化学扫描法制备了{[PMo12O40]3--Pt/PAMAM}n多层复合膜,通过X射线光电子能谱(XPS)、循环伏安测定(CV)和原子力显微镜(AFM)对样品的化学组成和膜的均匀性进行了表征。测试和分析结果表明[PMo12O40]3--Pt和PAMAM通过静电相互作用形成了交替多层复合膜,且膜的增长均匀,[PMo12O40]3-和Pt粒子均匀分布在间隔剂PAMAM上。采用三电极体系的循环伏安电化学分析方法研究了样品在酸性溶液中对甲醇的电催化氧化活性,结果表明,与Pt/GCE催化剂相比,{[PMo12O40]3--Pt/PAMAM}n/GCE呈现出较高的电催化氧化活性和好的稳定性。 展开更多
关键词 多金属氧酸盐 聚酰胺-胺载体 电化学扫描法 甲醇氧化 电催化
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Photocatalytic activity of bauxite-tailings supported nano-TiO_2
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作者 卢清华 胡岳华 王梦 《Journal of Central South University》 SCIE EI CAS 2010年第4期755-759,共5页
TiO2/bauxite-tailings (TiO2/BTs) composites were prepared via a chemical liquid deposition method and characterized by X-ray diffractometry (XRD), scanning electronic microscopy (SEM) and N2 adsorption analysis.... TiO2/bauxite-tailings (TiO2/BTs) composites were prepared via a chemical liquid deposition method and characterized by X-ray diffractometry (XRD), scanning electronic microscopy (SEM) and N2 adsorption analysis. The photocatalytic performance of TiO2/BTs composites was evaluated with UV-Vis spectrophotometer following the changes of phenol concentration under different illumination time. Effects of the calcination temperature, the pH and the cycles on the photocatalytic activity of TiO2/BTs composites were investigated. The composites calcined at 500 and 600 ℃ exhibit the best photocatalytic performance, and the phenol degradation ratios reacting for 40 and 160 rain reach 35% and 78% respectively under the same conditions, higher than those of 29% and 76% of the Degussa P25(TiO2). The ability of TiO2/BTs500 (BTs500 represents bauxite-tailings calcined at 500 ℃) composites to degrade phenol increases with decreasing pH. 展开更多
关键词 TIO2 bauxite-tailings PHENOL photocatalytic activity
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