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高择优取向铜镀层的电化学形成及其表面形貌 被引量:50
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作者 辜敏 杨防祖 +2 位作者 黄令 姚士冰 周绍民 《物理化学学报》 SCIE CAS CSCD 北大核心 2002年第11期973-978,共6页
采用电化学方法在H2SO4-CuSO4电解液中获得高择优取向的Cu电沉积层.XRD结果表明,在1.0~6.0和15.0A·dm-2的电流密度下可分别获得(220)和(111)晶面高择优取向的Cu镀层.在同一电流密度下获得的Cu电沉积层织构度随镀层厚度增大而提高.... 采用电化学方法在H2SO4-CuSO4电解液中获得高择优取向的Cu电沉积层.XRD结果表明,在1.0~6.0和15.0A·dm-2的电流密度下可分别获得(220)和(111)晶面高择优取向的Cu镀层.在同一电流密度下获得的Cu电沉积层织构度随镀层厚度增大而提高.SEM结果表明,在4.0和15.0A·dm-2的电流密度下可分别获得(220)和(111)织构Cu沉积层,其表面形貌在(220)晶面取向时呈现为细长晶粒连结成的网状,在(111)取向时则呈六棱锥状.提出了可能的机理,认为电流密度变化引起的Cu镀层择优取向晶面的转化归因于电结晶晶面生长方向及生长速度竞争的结果. 展开更多
关键词 择优取向 铜镀层 电化学形成 电沉积 表面形貌 镀铜
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阴极直接制备铜氧化物-SiO_(2)复合薄膜及其电化学形成机理
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作者 辜敏 吴亚珍 《材料导报》 EI CAS CSCD 北大核心 2023年第5期27-32,共6页
以室温下制备出的n_(Cu)^(2+)∶n_(Cit)^(3-)=2∶1的透明稳定的Cu(Ⅱ)-Cit^(3-)-SiO_(2)复合溶胶为电解液,直接在氧化铟锡导电玻璃(ITO)阴极上电沉积得到铜氧化物-SiO_(2)复合薄膜。循环伏安(CV)和X射线衍射(XRD)结果表明,溶胶中Cu^(2+... 以室温下制备出的n_(Cu)^(2+)∶n_(Cit)^(3-)=2∶1的透明稳定的Cu(Ⅱ)-Cit^(3-)-SiO_(2)复合溶胶为电解液,直接在氧化铟锡导电玻璃(ITO)阴极上电沉积得到铜氧化物-SiO_(2)复合薄膜。循环伏安(CV)和X射线衍射(XRD)结果表明,溶胶中Cu^(2+)与吸附在电极上的SiO_(2)溶胶共电沉积形成Cu_(2)O-SiO_(2)凝胶薄膜,XRD和计时安培(CA)结果表明,薄膜中的SiO_(2)量随过电位升高而减少。X射线光电子能谱(XPS)、XRD和能量色散X射线(EDX)结果表明,高过电位下,SiO_(2)和Cu(Ⅱ)借助析氢生成的OH-共沉积,得到CuO/Cu_(2)O-SiO_(2)薄膜,这与扫描电子显微镜(SEM)图片显示的所得薄膜具有两种不同形貌的颗粒的结果一致。 展开更多
关键词 氧化亚铜-二氧化硅 氧化铜/氧化亚铜-二氧化硅 复合薄膜 复合溶胶 电化学形成
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Comparative study on microstructure and electrochemical corrosion resistance of Al7075 alloy prepared by laser additive manufacturing and forging technology 被引量:8
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作者 ZHANG Jin-liang YE Jie-liang +2 位作者 SONG Bo LI Rui-di SHI Yu-sheng 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第4期1058-1067,共10页
Al7075 alloy is a typical aviation aluminum with good mechanical properties and anodic oxidation effect.Laser engineered net shaping technology has unique advantages in the integrated forming of high-performance large... Al7075 alloy is a typical aviation aluminum with good mechanical properties and anodic oxidation effect.Laser engineered net shaping technology has unique advantages in the integrated forming of high-performance large aircraft structural parts.The manufacturing of 7075 aluminum alloy structural parts by laser engineered net shaping technology has become an important development direction in the future aerospace field.Electrochemical corrosion resistance of aluminum alloys is of vital importance to improve reliability and life-span of lightweight components.A comparative study on microstructure and anti-corrosion performance of Al7075 alloy prepared by laser additive manufacturing and forging technology was conducted.There are hole defects in LENS-fabricated Al7075 alloy with uniformly distributedηphase.No defects are observed in Al7075 forgings.The large S phase particles and small ellipsoidalηphase particles are found in Al matrix.The corrosion mechanisms were revealed according to the analysis of polarization curves and corrosion morphology.It was found that compared with that prepared by forgings,the additive manufactured samples have lower corrosion tendency and higher corrosion rate.Corrosion occurred preferentially at the hole defects.The incomplete passivation film at the defects leads to the formation of a local cell composed of the internal Al,corrosion solution and the surrounding passive film,which further aggravates the corrosion. 展开更多
关键词 Al7075 alloy laser engineered net shaping FORGING electrochemical corrosion resistance
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