Recent advances in the preparation and application of perovskite-type oxides as bifunctional electrocatalysts for oxygen reaction and oxygen evolution reaction in rechargeable metal-air batteries are presented in this...Recent advances in the preparation and application of perovskite-type oxides as bifunctional electrocatalysts for oxygen reaction and oxygen evolution reaction in rechargeable metal-air batteries are presented in this review.Various fabrication methods of these oxides are introduced in detail,and their advantages and disadvantages are analyzed.Different preparation methods adopted have great influence on the morphologies and physicochemical properties of perovskite-type oxides.As a bifunctional electrocatalyst,perovskite-type oxides are widely used in rechargeable metal-air batteries.The relationship between the preparation methods and the performances of oxygen/air electrodes are summarized.This work is concentrated on the structural stability,the phase compositions,and catalytic performance of perovskite-type oxides in oxygen/air electrodes.The main problems existing in the practical application of perovskite-type oxides as bifunctional electrocatalysts are pointed out and possible research directions in the future are recommended.展开更多
Electro-catalysts Fe203 compounded by ZnO were prepared by a sol-gel method, which were titled as Fe203-ZnO. Electro-catalysts Fe203-ZnO loading on the bamboo charcoal was titled as Fe203-ZnO/C. The catalytic material...Electro-catalysts Fe203 compounded by ZnO were prepared by a sol-gel method, which were titled as Fe203-ZnO. Electro-catalysts Fe203-ZnO loading on the bamboo charcoal was titled as Fe203-ZnO/C. The catalytic materials were characterized by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The obtained catalysts were assembled to three-dimensional electrodes to degradation of chlorinated organic in paper wastewater. And the performance tests show that three-dimensional electrodes have high activities for degradation of chlorinated organic in paper wastewater. There are many factors affecting the electro-catalytic performances of the three-dimensional electrodes. And the orthogonal experiment results show that the optimum operating condition is as follows： the calcination time of the catalysts 2 h, the mass ratio of Fe to Zn 4：1, the voltage 12 V, the mass of the catalytic materials 6 g, the value of pH 9, and the treating time 2.5 h. Under these conditions, the optimum removal efficiency of chlorinated organics in paper wastewater is 47.58%.展开更多
A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, ...A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, mass fraction） and the basic density of the activation process were thoroughly investigated. The surface of catalysts was characterized by Boehm titration. The products were characterized by scanning electron microscopy （SEM）, X-ray diffractometry （XRD） and X-ray photoelectron spectroscopy （XPS）. The results show that catalysts with 2.5%-5.0% Fe2O3 after calcining at 500 ℃ have superior activity. The conversion rate of COS increases with increasing the relative density of basic capacity loaded onto activated carbon（AC）, and the activity follows the order： KOH〉Na2CO3 〉NaHCO3. Boehm titration data clearly show that the total acidity increases （from 0.06 to 0.48 mmol/g） and the basic groups decrease （from 0.78 to 0.56 mmol/g） after COS hydrolysis and H2S adsorption. The XPS results show that the product of HzS may be absorbed by the interaction with metal compounds and 02 to form sulfate （171.28 eV） and element sulfur （164.44 eV）, which lead to catalysts poisoning.展开更多
基金Projects(51504212,21573184,51703061)supported by the National Natural Science Foundation of ChinaProject(2018J01521)supported by the Natural Science Foundation of Fujian Province,ChinaProject(fma2017202)supported by the Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications(Xiamen University of Technology),China
文摘Recent advances in the preparation and application of perovskite-type oxides as bifunctional electrocatalysts for oxygen reaction and oxygen evolution reaction in rechargeable metal-air batteries are presented in this review.Various fabrication methods of these oxides are introduced in detail,and their advantages and disadvantages are analyzed.Different preparation methods adopted have great influence on the morphologies and physicochemical properties of perovskite-type oxides.As a bifunctional electrocatalyst,perovskite-type oxides are widely used in rechargeable metal-air batteries.The relationship between the preparation methods and the performances of oxygen/air electrodes are summarized.This work is concentrated on the structural stability,the phase compositions,and catalytic performance of perovskite-type oxides in oxygen/air electrodes.The main problems existing in the practical application of perovskite-type oxides as bifunctional electrocatalysts are pointed out and possible research directions in the future are recommended.
基金Projects(10JJ5002,11JJ5010,12JJ3013)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2011RS4069)supported by the Planned Science and Technology Program of Hunan Province,China
文摘Electro-catalysts Fe203 compounded by ZnO were prepared by a sol-gel method, which were titled as Fe203-ZnO. Electro-catalysts Fe203-ZnO loading on the bamboo charcoal was titled as Fe203-ZnO/C. The catalytic materials were characterized by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The obtained catalysts were assembled to three-dimensional electrodes to degradation of chlorinated organic in paper wastewater. And the performance tests show that three-dimensional electrodes have high activities for degradation of chlorinated organic in paper wastewater. There are many factors affecting the electro-catalytic performances of the three-dimensional electrodes. And the orthogonal experiment results show that the optimum operating condition is as follows： the calcination time of the catalysts 2 h, the mass ratio of Fe to Zn 4：1, the voltage 12 V, the mass of the catalytic materials 6 g, the value of pH 9, and the treating time 2.5 h. Under these conditions, the optimum removal efficiency of chlorinated organics in paper wastewater is 47.58%.
基金Project(50908110) supported by the National Natural Science Foundation of ChinaProject(2008AA062602) supported by the National High-Tech Research and Development Program of China+1 种基金Project(20090451431) supported by China Postdoctoral Science FoundationProject(2007PY01-10) supported by Young and Middle-aged Academic and Technical Back-up Personnel Program of Yunnan Province,China
文摘A novel type of metal oxide/activated carbon catalyst was prepared by sol-gel method for the hydrolysis of carbonyl sulfide （COS）. The influences of the calcination temperature, additive content （2.5%-10.0% Fe2O3, mass fraction） and the basic density of the activation process were thoroughly investigated. The surface of catalysts was characterized by Boehm titration. The products were characterized by scanning electron microscopy （SEM）, X-ray diffractometry （XRD） and X-ray photoelectron spectroscopy （XPS）. The results show that catalysts with 2.5%-5.0% Fe2O3 after calcining at 500 ℃ have superior activity. The conversion rate of COS increases with increasing the relative density of basic capacity loaded onto activated carbon（AC）, and the activity follows the order： KOH〉Na2CO3 〉NaHCO3. Boehm titration data clearly show that the total acidity increases （from 0.06 to 0.48 mmol/g） and the basic groups decrease （from 0.78 to 0.56 mmol/g） after COS hydrolysis and H2S adsorption. The XPS results show that the product of HzS may be absorbed by the interaction with metal compounds and 02 to form sulfate （171.28 eV） and element sulfur （164.44 eV）, which lead to catalysts poisoning.
