As a solution to the breaking of pipeline under high axial force,carbon fiber composite pipe with low density and high intensity is applied to deep-sea mining transporting system.Based on the fact that the transportin...As a solution to the breaking of pipeline under high axial force,carbon fiber composite pipe with low density and high intensity is applied to deep-sea mining transporting system.Based on the fact that the transporting pipe is under the forces of gravity,inner liquid,buoyancy as well as hydrodynamic force,geometric nonlinear finite element theory has been applied to analyzing the transporting system.Conclusions can be drawn as follows.Under the interaction of waves and currents,node forces FX and FZ acted by the transporting pipe on the mining vehicle are less than 2 kN,which indicates that waves and currents have little influence on the spatial shape of the transporting pipe and the mining vehicle movement.On the other hand,the horizontal force acting on the mining ship could be as large as 106 830 N,which has great influence on the mining system.展开更多
The surface states of pyrite(Fe S2) were theoretically investigated using first principle calculation based on the density functional theory(DFT). The results indicate that both the(200) and(311) surfaces of pyrite un...The surface states of pyrite(Fe S2) were theoretically investigated using first principle calculation based on the density functional theory(DFT). The results indicate that both the(200) and(311) surfaces of pyrite undergo significant surface atom relaxation after geometry optimization, which results in a considerable distortion of the surface region. In the normal direction, i.e., perpendicular to the surface, S atoms in the first surface layer move outward from the bulk, while Fe atoms move toward the bulk, forming an S-rich surface. The surface relaxation processes are driven by electrostatic interaction, which is evidenced by a relative decrease in the surface energy after surface relaxation. Such a relaxation process is visually interpreted through the qualitative analysis of molecular mechanics. Atomic force microscopy(AFM) analysis reveals that only sulfur atom is visible on the pyrite surface. This result is consistent with the DFT data. Such S-rich surface has important influence on the flotation properties of pyrite.展开更多
Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding perf...Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding performance. The interaction mechanism between CMC and iron ore particles was analyzed through Zeta potential measurements, adsorption measurements and infrared spectra. The results show that the interaction is chemical adsorption-oriented and the CMC's adsorption performance is related to the properties of CMC as well as the type of iron oxides. CMC has a greater affinity to Fe2O3 than Fe3O4, and CMC with higher relative molecular mass shows a higher adsorption isotherm. Pelletization of practical iron ore concentrates added with CMC further illustrates that CMC with higher relative molecular mass or DS exhibits a better binding performance, which is consistent with the results of adsorption tests.展开更多
基金Project(50975290) supported by the National Natural Science Foundation of ChinaProject(2011QNZT057) supported by the Basic Operational Cost of Special Research Funding of Central Universities in ChinaProject(11JJ5028) supported by Hunan Provincial Natural Science Foundation,China
文摘As a solution to the breaking of pipeline under high axial force,carbon fiber composite pipe with low density and high intensity is applied to deep-sea mining transporting system.Based on the fact that the transporting pipe is under the forces of gravity,inner liquid,buoyancy as well as hydrodynamic force,geometric nonlinear finite element theory has been applied to analyzing the transporting system.Conclusions can be drawn as follows.Under the interaction of waves and currents,node forces FX and FZ acted by the transporting pipe on the mining vehicle are less than 2 kN,which indicates that waves and currents have little influence on the spatial shape of the transporting pipe and the mining vehicle movement.On the other hand,the horizontal force acting on the mining ship could be as large as 106 830 N,which has great influence on the mining system.
基金Project(51464029)supported by the National Natural Science Foundation of ChinaProject(2014M562343)supported by China Postdoctoral Science FoundationProject(KKSY201421110)supported by the Scholar Development Project of Yunnan Province,China
文摘The surface states of pyrite(Fe S2) were theoretically investigated using first principle calculation based on the density functional theory(DFT). The results indicate that both the(200) and(311) surfaces of pyrite undergo significant surface atom relaxation after geometry optimization, which results in a considerable distortion of the surface region. In the normal direction, i.e., perpendicular to the surface, S atoms in the first surface layer move outward from the bulk, while Fe atoms move toward the bulk, forming an S-rich surface. The surface relaxation processes are driven by electrostatic interaction, which is evidenced by a relative decrease in the surface energy after surface relaxation. Such a relaxation process is visually interpreted through the qualitative analysis of molecular mechanics. Atomic force microscopy(AFM) analysis reveals that only sulfur atom is visible on the pyrite surface. This result is consistent with the DFT data. Such S-rich surface has important influence on the flotation properties of pyrite.
基金Project(2012zzts101)supported by the Fundamental Research Funds for the Central Universities,China
文摘Carboxylmethyl cellulose(CMC) has become a commercial organic binder in agglomeration of iron ore concentrates. The relative molecular mass and degree of substitution(DS) of CMC have a large impact on its binding performance. The interaction mechanism between CMC and iron ore particles was analyzed through Zeta potential measurements, adsorption measurements and infrared spectra. The results show that the interaction is chemical adsorption-oriented and the CMC's adsorption performance is related to the properties of CMC as well as the type of iron oxides. CMC has a greater affinity to Fe2O3 than Fe3O4, and CMC with higher relative molecular mass shows a higher adsorption isotherm. Pelletization of practical iron ore concentrates added with CMC further illustrates that CMC with higher relative molecular mass or DS exhibits a better binding performance, which is consistent with the results of adsorption tests.
