Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indica...Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indicating high crystalline and phase purity.The SEM and TEM images reveal that diameter of the spherical-like Na2FePO4F/C particles ranges from 50 to 300 nm,and HRTEM image shows that the surface of Na2FePO4F/C composite is uniformly coated by carbon layer with a average thickness of about 3.6 nm.The carbon coating constrains the growth of the particles and effectively reduces the agglomeration of nanoparticles.Using lithium metal as anode,the composite delivers a discharge capacities of 102.8,96.4 and 90.3 mA·h/g at rates of 0.5C,1C and 2C,respectively.After 100 cycles at 0.5C,a discharge capacity of 98.9 mA·h/g is maintained with capacity retention of 96.2%.The Li+diffusion coefficient(D)of Na2FePO4F/C composite is calculated as 1.71×10^–9 cm^2/s.This study reveals that the simple solid state reaction could be a practical and effective synthetic route for the industrial production of Na2FePO4F/C material.展开更多
To solve the problem of information fusion in the strapdown inertial navigation system(SINS)/celestial navigation system(CNS)/global positioning system(GPS) integrated navigation system described by the nonlinear/non-...To solve the problem of information fusion in the strapdown inertial navigation system(SINS)/celestial navigation system(CNS)/global positioning system(GPS) integrated navigation system described by the nonlinear/non-Gaussian error models,a new algorithm called the federated unscented particle filtering(FUPF) algorithm was introduced.In this algorithm,the unscented particle filter(UPF) served as the local filter,the federated filter was used to fuse outputs of all local filters,and the global filter result was obtained.Because the algorithm was not confined to the assumption of Gaussian noise,it was of great significance to integrated navigation systems described by the non-Gaussian noise.The proposed algorithm was tested in a vehicle's maneuvering trajectory,which included six flight phases:climbing,level flight,left turning,level flight,right turning and level flight.Simulation results are presented to demonstrate the improved performance of the FUPF over conventional federated unscented Kalman filter(FUKF).For instance,the mean of position-error decreases from(0.640×10-6 rad,0.667×10-6 rad,4.25 m) of FUKF to(0.403×10-6 rad,0.251×10-6 rad,1.36 m) of FUPF.In comparison of the FUKF,the FUPF performs more accurate in the SINS/CNS/GPS system described by the nonlinear/non-Gaussian error models.展开更多
基金Projects(51472211,51502256)supported by the National Natural Science Foundation of ChinaProjects(2016GK4005,2016GK4030)supported by the Strategic New Industry of Hunan Province,ChinaProject(13C925)supported by the Research Foundation of Education Bureau of Hunan Province,China
文摘Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indicating high crystalline and phase purity.The SEM and TEM images reveal that diameter of the spherical-like Na2FePO4F/C particles ranges from 50 to 300 nm,and HRTEM image shows that the surface of Na2FePO4F/C composite is uniformly coated by carbon layer with a average thickness of about 3.6 nm.The carbon coating constrains the growth of the particles and effectively reduces the agglomeration of nanoparticles.Using lithium metal as anode,the composite delivers a discharge capacities of 102.8,96.4 and 90.3 mA·h/g at rates of 0.5C,1C and 2C,respectively.After 100 cycles at 0.5C,a discharge capacity of 98.9 mA·h/g is maintained with capacity retention of 96.2%.The Li+diffusion coefficient(D)of Na2FePO4F/C composite is calculated as 1.71×10^–9 cm^2/s.This study reveals that the simple solid state reaction could be a practical and effective synthetic route for the industrial production of Na2FePO4F/C material.
基金Project(60535010) supported by the National Nature Science Foundation of China
文摘To solve the problem of information fusion in the strapdown inertial navigation system(SINS)/celestial navigation system(CNS)/global positioning system(GPS) integrated navigation system described by the nonlinear/non-Gaussian error models,a new algorithm called the federated unscented particle filtering(FUPF) algorithm was introduced.In this algorithm,the unscented particle filter(UPF) served as the local filter,the federated filter was used to fuse outputs of all local filters,and the global filter result was obtained.Because the algorithm was not confined to the assumption of Gaussian noise,it was of great significance to integrated navigation systems described by the non-Gaussian noise.The proposed algorithm was tested in a vehicle's maneuvering trajectory,which included six flight phases:climbing,level flight,left turning,level flight,right turning and level flight.Simulation results are presented to demonstrate the improved performance of the FUPF over conventional federated unscented Kalman filter(FUKF).For instance,the mean of position-error decreases from(0.640×10-6 rad,0.667×10-6 rad,4.25 m) of FUKF to(0.403×10-6 rad,0.251×10-6 rad,1.36 m) of FUPF.In comparison of the FUKF,the FUPF performs more accurate in the SINS/CNS/GPS system described by the nonlinear/non-Gaussian error models.
