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基于强化粗粒中灰煤泥浮选回收与分离效果的调控机制研究 被引量:1
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作者 许光前 王焕忠 +1 位作者 耿大将 李伟明 《煤炭工程》 北大核心 2024年第11期202-210,共9页
基于细粒煤泥分质回收与合理化利用目的,为强化中灰煤泥浮选回收与分离效果,实现细粒煤泥“低灰精煤、中灰煤泥和高灰泥矸”三产品分选,选取浮选精煤和中灰煤泥两种试样,通过浮选试验考查了不同分选参数下的浮选效果,研究了浮选精煤与... 基于细粒煤泥分质回收与合理化利用目的,为强化中灰煤泥浮选回收与分离效果,实现细粒煤泥“低灰精煤、中灰煤泥和高灰泥矸”三产品分选,选取浮选精煤和中灰煤泥两种试样,通过浮选试验考查了不同分选参数下的浮选效果,研究了浮选精煤与中灰煤泥浮选行为差异,并借助原子力显微镜测定了液膜薄化过程中强/弱疏水性基板与气泡间的相互作用。研究表明:浮选精煤的接触角为109.25°,较中灰煤泥高28.62°;浮选精煤中含有较多的烷基和氨基等阳离子型基团,中灰煤泥含有较多的羧基和羟基等含氧官能团。增加柴油和仲辛醇用量、提高浮选搅拌转速都有助于提升浮选精煤和中灰煤泥的回收效果;增加充气量能提升浮选精煤回收效果,但中灰煤泥回收效果有所降低。浮选精煤的浮选速率明显高于中灰煤泥,在相同浮选条件下浮选精煤优先浮出。对于强化中灰煤泥回收,分选参数影响次序为搅拌转速>矿浆浓度>充气量>起泡剂>捕收剂。强化粗粒中灰煤泥分选回收时,应采用“高药剂用量、强搅拌转速、低充气量、高矿浆浓度、延长浮选时间”分选条件;对于分离浮选精煤与中灰煤泥,应采用“低药剂用量、低搅拌转速、高充气量、低矿浆浓度、降浮选时间”分选条件。强/弱疏水性基板与气泡间的临界液膜厚度理论值分别为39 nm和16 nm,在吸引性分离压作用下气泡突破液膜与基板发生黏附。当液膜厚度薄化至疏水力作用程时,总分离压力开始转向吸引,膜薄化驱动压力急剧升高,液膜在疏水力的作用下发生破裂。 展开更多
关键词 浮选精煤 煤泥 浮选回收 分离效果
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聚羧酸系水煤浆分散剂对高灰煤泥成浆性的研究 被引量:5
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作者 孟献梁 王红林 +6 位作者 吴国光 苗真勇 褚睿智 刘亚菲 王敬 王艳丽 张中彩 《煤炭科学技术》 CAS 北大核心 2013年第10期121-124,共4页
针对煤泥制浆中灰分对分散剂分散效果的不利影响,设计并合成了耐盐型聚羧酸分散剂,通过红外分析、表面电位测定和制浆试验考察了该分散剂的性能。研究表明:聚羧酸分散剂与煤样结构相似,具有很好的匹配性;分散剂与煤颗粒结合后,煤粒表面... 针对煤泥制浆中灰分对分散剂分散效果的不利影响,设计并合成了耐盐型聚羧酸分散剂,通过红外分析、表面电位测定和制浆试验考察了该分散剂的性能。研究表明:聚羧酸分散剂与煤样结构相似,具有很好的匹配性;分散剂与煤颗粒结合后,煤粒表面的电位明显降低,电负性显著提高;聚羧酸系分散剂的相对分子质量处于110 000~170 000时,制浆效果最佳、最为稳定;与木系和萘系分散剂相比,利用聚羧酸系分散剂制备的水煤浆浆体质量分数达61%左右,且浆体表现出良好的流动性稳定性,分散效果最好。 展开更多
关键词 煤泥 聚羧酸分散剂 水煤浆 成浆性 ZETA电位
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贵州高灰细粒煤泥浮选研究 被引量:2
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作者 石开仪 孔德顺 +1 位作者 龙剑 陈鹏 《煤炭工程》 北大核心 2016年第10期120-123,共4页
以贵州西部汪家寨选煤厂入浮煤泥为研究对象,进行了粒度分析、小浮沉试验、分步释放试验和药剂制度探索等试验。结果发现,该厂煤泥中-0.045mm粒级的占43.30%,灰分达47.97%,此外,由小浮沉试验结果绘制的可选性曲线看出,灰分曲线较为陡峭... 以贵州西部汪家寨选煤厂入浮煤泥为研究对象,进行了粒度分析、小浮沉试验、分步释放试验和药剂制度探索等试验。结果发现,该厂煤泥中-0.045mm粒级的占43.30%,灰分达47.97%,此外,由小浮沉试验结果绘制的可选性曲线看出,灰分曲线较为陡峭,可以判断该厂煤泥为高灰细粒难选煤泥。通过对捕收剂(柴油、正十二烷)、起泡剂(二号油、仲辛醇、MIBC)种类和用量的探索发现,当矿浆浓度选择110g/L,捕收剂选择正十二烷(270g/t),起泡剂选择MIBC(6g/t)时,精煤产率为38.91%,灰分为11.14%,尾煤灰分为45.53%。 展开更多
关键词 煤泥 细粒煤泥 浮选 MIBC
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高灰煤泥的制浆及流化床燃烧
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作者 王晓黎 《中国煤炭》 1999年第5期40-41,共2页
选煤厂实现煤泥内回收后,回收的这些煤泥大多很难找到销售市场和适当的处理方法。煤泥具有粒度细、微粒含量多,持水性强、灰分较高、热值较低且不易运输的特点,目前主要作劣质燃料就地利用。煤泥浆燃烧技术是利用选煤厂生产的煤泥,... 选煤厂实现煤泥内回收后,回收的这些煤泥大多很难找到销售市场和适当的处理方法。煤泥具有粒度细、微粒含量多,持水性强、灰分较高、热值较低且不易运输的特点,目前主要作劣质燃料就地利用。煤泥浆燃烧技术是利用选煤厂生产的煤泥,经过合理的调整灰分、水分和粒度后,... 展开更多
关键词 煤泥 煤泥 制浆 流化床燃烧
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煤泥无废排放综合利用模式 被引量:23
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作者 黄光许 谌伦建 申义青 《洁净煤技术》 CAS 北大核心 2005年第2期59-62,14,共5页
对国内煤泥综合利用进行了综述,并就煤泥燃烧产物———煤泥灰与粉煤灰的理化特性进行了对比分析,认为粉煤灰的许多利用途径可以为煤泥灰综合利用所借鉴,提出了符合循环经济要求的煤泥无废排放综合利用构想。
关键词 煤泥 煤泥灰 综合利用
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Influence of ultra-fine fly ash on hydration shrinkage of cement paste 被引量:15
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作者 高英力 周士琼 《Journal of Central South University of Technology》 EI 2005年第5期596-600,共5页
Hydration shrinkage generated by cement hydration is the cause of autogenous shrinkage of high strength concrete. It may result in the volume change and even cracking of mortar and concrete. According to the data anal... Hydration shrinkage generated by cement hydration is the cause of autogenous shrinkage of high strength concrete. It may result in the volume change and even cracking of mortar and concrete. According to the data analysis in a series of experimental studies, the influence of ultra-fine fly ash on the hydration shrinkage of composite cementitious materials was investigated. It is found that ultra-fine fly ash can reduce the hydration shrinkage of cement paste effectively, and the more the ultra-fine fly ash, the less the hydration shrinkage. Compared with cement paste without the ultra-fine fly ash, the shrinkage ratio of cement paste reduces from 23.4% to 39.7% when the ultra-fine fly ash replaces cement from 20% to 50%. Moreover, the microscopic mechanism of the ultra-fine fly ash restraining the hydration shrinkage was also studied by scanning electron microscopy, X-ray diffraction and hydrated equations. The results show that the hydration shrinkage can be restrained to a certain degree because the ultra-fine fly ash does not participate in the hydration at the early stage and the secondary hydration products are different at the later stage. 展开更多
关键词 ultra-fine fly ash cement paste hydration shrinkage MECHANISM
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Cemented backfill technology based on phosphorous gypsum 被引量:5
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作者 王新民 赵彬 张钦礼 《Journal of Central South University》 SCIE EI CAS 2009年第2期285-291,共7页
Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive ... Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive mined-out gobs, enormous ore body under roadway and low recovery ratio of Yongshaba Mine, Kaiyang Phosphor Mine Group, Guizhou Province, China. An appropriate backfill system and craflwork were designed, using shattering milling method to crush gypsum, double-axles mixing and strong activation mixing way to mix slurry, cemented slurry and mullock backfill alternately process. The results show that gypsum is fit for backfilling afterwards by adding fly ash, though it is not an ideal aggregate for fine granule and coagulate retardation. The suggested dosage (the mass ratio of cement to fly ash to gypsum) is 1:1:6-1:1:8 with mass fraction of solid materials 60%-63%. Slurry is transported in suspend state with non-plastic strength, and then in concretion state after backfilling. The application to mine shows the technology is feasible, and gypsum utilization ratio is up to 100%. Transportation and backfill effect is very good for paste-like slurry and drenching cemented slurry into mullock, and the compressive strength and recovery ratio are 2.0 MPa and 82.6%, respectively, with the maximum subsidence of surface only 1.307 mm. Furthermore, the investment of system is about 7 × 10^6 yuan (RMB), only 1/10 of that of traditional paste backfill system. 展开更多
关键词 phosphorous gypsum self-flowing transportation cemented backfill cemented mechanism backfill system and craftwork
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Consolidation analysis of composite foundation with partially penetrated cement fly-ash gravel(CFG) piles under changing permeable boundary conditions 被引量:3
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作者 邹新军 赵增明 徐洞斌 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第10期4019-4026,共8页
Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the ... Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure. 展开更多
关键词 composite ground CFG piles permeability double-layered foundation consolidation degree
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Lateral displacement of silty clay under cement-fly ash-gravel pile-supported embankments: Analytical consideration and field evidence 被引量:5
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作者 张崇磊 蒋关鲁 +1 位作者 刘先峰 王智猛 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第4期1477-1489,共13页
Based on back analysis of lateral displacements measured in situ by using the analytical solution, a useful method for estimating stress concentration ratio of geosynthetic-reinforced and pile-supported(GRPS) embankme... Based on back analysis of lateral displacements measured in situ by using the analytical solution, a useful method for estimating stress concentration ratio of geosynthetic-reinforced and pile-supported(GRPS) embankments was proposed. In order to validate the proposed method, a full-scale high-speed railway embankment(HSRE) with four instrumented subsections over medium compressibility silty clay was constructed in three stages. The soil profile, construction procedure and monitoring of settlements and lateral displacements of the four test sections were described. The field deformation analysis results show that 1) the combined reinforcement of CFG piles and geosynthetic layer perform well in terms of reducing lateral displacements; 2) the development of lateral displacements lags behind the increase of fill load, which can be attributed to the vertical load transfer mechanism of the pile foundation; and 3) pile length has a dominant effect on the stress distribution proportion between piles and surrounding soils. The comparison between predicted and experimental results suggests that the proposed analytical solution and the back analysis-based method are capable of reasonably estimating the lateral deformation and the stress concentration ratio, respectively, if the appropriate soil elastic modulus is chosen. 展开更多
关键词 piled-supported embankment silty clay lateral displacement field test stress concentration ratio
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Chloride diffusivity in flexural cracked Portland cement concrete and fly ash concrete beams 被引量:1
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作者 陆春华 崔钊玮 +1 位作者 刘荣桂 刘奇东 《Journal of Central South University》 SCIE EI CAS 2014年第9期3682-3691,共10页
In order to examine the effect of load-induced transverse cracks on the chloride penetration in flexural concrete beams, two different concretes, Portland cement concrete(PCC) and fly ash concrete(FAC), were tested wi... In order to examine the effect of load-induced transverse cracks on the chloride penetration in flexural concrete beams, two different concretes, Portland cement concrete(PCC) and fly ash concrete(FAC), were tested with various crack widths. Total 14 reinforced concrete(RC) beams, ten of which were self-anchored in a three-point bending mode, were immersed into a 5% NaCl solution with the condition of dry-wet cycles. Then, the free chloride ion contents were determined by rapid chloride testing(RCT) method. Based on the proposed analytical models of chloride penetration in sound and cracked concrete subjected to dry-wet cycles, the apparent chloride diffusion coefficient and chloride diffusivity of concrete were discussed. It can be found that the performance of chloride diffusivity in both concretes will be improved with the increase of crack width, and that the influence of convection action will also be augmented. Based on the two samples obtained in sound concrete after 15 and 30 cycles, the time-exponent, m, for chloride diffusion coefficient was determined to be 0.58, 0.42, 0.62 and 0.77 for PCC1, PCC2, FAC1 and FAC2 specimens, respectively. Finally, two influencing factors of fly ash content and crack width on chloride diffusivity were obtained by regression analysis of test data, and it can be seen that factors kf and kw can be expressed with quadratic polynomial functions of fly ash content, f, and crack width, w, respectively. 展开更多
关键词 flexural cracked concrete fly ash chloride dry-wet cycle equivalent chloride diffusion coefficient
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