The influence of sulfur content in raw materials on oxidized pellets was studied. The results show that most sulfur exists in the form of elementary sulfur in pyrite cinder, and over 95% sulfur is removed in producing...The influence of sulfur content in raw materials on oxidized pellets was studied. The results show that most sulfur exists in the form of elementary sulfur in pyrite cinder, and over 95% sulfur is removed in producing pyrite cinder oxidized pellets. The compressive strength of fired pellets drops from 3 186 N to 2 405 N when the ratio of pyrite cinder increases from 40% to 70% under the conditions of preheating at 900℃ for 9 min and firing at 1 230 ℃ for 15 min. The porosity and microstructures of fired pellets prove that the higher ratio of pyrite cinder is given, and the more holes and cracks are achieved, leading to the better reducibility index （RI） and reduction swelling index （RSI）, and the lower compressive strength of fired pellets and the worse reduction degradation index （RDI）.展开更多
The main objective of this paper focuses on the changes that occur in the strength and microstructural properties of sodium silicate activated fly ash based geopolymer due to varying the sulfate salt and water content...The main objective of this paper focuses on the changes that occur in the strength and microstructural properties of sodium silicate activated fly ash based geopolymer due to varying the sulfate salt and water content.A series of tests including X-ray diffraction,Fourier transform infrared spectroscopy,scanning electron microscopy,physical adsorption and unconfined compressive strength were used to investigate this effect.The results indicate that the higher water content has an adverse effect on the alkali activation and microstructural properties of geopolymer,so the optimum mass ratio of sodium sulfate in alkali-activated geopolymer under different water-to-binder ratios shows a“peak shifting”phenomenon,i.e.,the higher the water-to-binder ratio,the higher the optimum mass ratio.Lower presence of sodium sulfate has no significant effect on the alkali-activated geopolymer systems;higher addition of sodium sulfate,however,could cause the symmetrical stretching vibration of Si—O and the symmetrical stretching vibration of Si—O—Si and Al—O—Si,and promote the formation of N-A-S-H gels.Furthermore,the cement effect of the gel and sodium sulfate aggregate could improve the integrity of pore structure obviously.The maximum strength of geopolymer curing at ambient temperature was 52 MPa.This study obtains the rule that the strength properties of alkali-activated geopolymers vary with the water-to-binder ratio and sodium sulfate content.The feasibility of geopolymer co-activated by sodium sulfate and sodium silicate was investigated,and reference for engineering application of alkali-activated geopolymer in salt-bearing areas was provided.展开更多
To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration （MSW1） fly ash were studied by measuring the chemica...To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration （MSW1） fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of Such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.展开更多
基金Project(2007k02) supported by the Technology Fund of the Land and Resources Department of Hunan Province, China
文摘The influence of sulfur content in raw materials on oxidized pellets was studied. The results show that most sulfur exists in the form of elementary sulfur in pyrite cinder, and over 95% sulfur is removed in producing pyrite cinder oxidized pellets. The compressive strength of fired pellets drops from 3 186 N to 2 405 N when the ratio of pyrite cinder increases from 40% to 70% under the conditions of preheating at 900℃ for 9 min and firing at 1 230 ℃ for 15 min. The porosity and microstructures of fired pellets prove that the higher ratio of pyrite cinder is given, and the more holes and cracks are achieved, leading to the better reducibility index （RI） and reduction swelling index （RSI）, and the lower compressive strength of fired pellets and the worse reduction degradation index （RDI）.
基金Project(51878322)supported by the National Natural Science Foundation of ChinaProject(18YF1FA112)supported by Key Research and Development Program of Gansu Province,China。
文摘The main objective of this paper focuses on the changes that occur in the strength and microstructural properties of sodium silicate activated fly ash based geopolymer due to varying the sulfate salt and water content.A series of tests including X-ray diffraction,Fourier transform infrared spectroscopy,scanning electron microscopy,physical adsorption and unconfined compressive strength were used to investigate this effect.The results indicate that the higher water content has an adverse effect on the alkali activation and microstructural properties of geopolymer,so the optimum mass ratio of sodium sulfate in alkali-activated geopolymer under different water-to-binder ratios shows a“peak shifting”phenomenon,i.e.,the higher the water-to-binder ratio,the higher the optimum mass ratio.Lower presence of sodium sulfate has no significant effect on the alkali-activated geopolymer systems;higher addition of sodium sulfate,however,could cause the symmetrical stretching vibration of Si—O and the symmetrical stretching vibration of Si—O—Si and Al—O—Si,and promote the formation of N-A-S-H gels.Furthermore,the cement effect of the gel and sodium sulfate aggregate could improve the integrity of pore structure obviously.The maximum strength of geopolymer curing at ambient temperature was 52 MPa.This study obtains the rule that the strength properties of alkali-activated geopolymers vary with the water-to-binder ratio and sodium sulfate content.The feasibility of geopolymer co-activated by sodium sulfate and sodium silicate was investigated,and reference for engineering application of alkali-activated geopolymer in salt-bearing areas was provided.
基金Project(50808184) supported by the National Natural Science Foundation of China
文摘To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration （MSW1） fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of Such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.
