In this paper,the content and density of adsorbed water in fine-grained soil are determined.According to the test results,the calculation method of compaction degree of the solid-phase and void ration of soil is impro...In this paper,the content and density of adsorbed water in fine-grained soil are determined.According to the test results,the calculation method of compaction degree of the solid-phase and void ration of soil is improved.Four kinds of fine-grained soils from different regions in China were selected,and the adsorbed water content and density of four kinds of fine-grained soils were determined by thermogravimetry and volumetric flask method.Furthermore,SEM and XRD experiments were used to analyze the differences in the ability of each soil sample to absorb water.In order to study the compression characteristics of adsorbed water,four saturated soil samples were tested by consolidation method.The results show that the desorption temperature range of the adsorbed water and its density were equal to 100−115℃and 1.30 g/cm^(3),respectively.Adsorbed water plays a positive role in keeping the compressibility of fine-grained soil at a low rate when it has high water content.Besides,adsorbed water can be a stable parameter and is difficult to discharge during the operation period of subgrade.The settlement of fine-grained soil embankment is predicted by engineering example,and compared with the result of conventional calculation method.The results show that it is more close to the field monitoring results by using the improved void ratio of soil as the parameter.展开更多
In order to decrease the solubility of PbSO4 and enhance lead recovery from PbSO4 bearing wastes, CO was employed as a reductant to transform PbSO4 into Pb S. Reaction system was established and reductive thermodynami...In order to decrease the solubility of PbSO4 and enhance lead recovery from PbSO4 bearing wastes, CO was employed as a reductant to transform PbSO4 into Pb S. Reaction system was established and reductive thermodynamics of PbSO4 was calculated by software HSC 5.0. The effects of gas concentration, reaction temperature, time and mass of sample on reduction of PbSO4 were examined by thermogravimetry(TG) and XRD. Roasting tests further verify the conclusions of thermodynamic and TG analyses. The results show that increasing temperature in the reasonable range and CO content are favorable for the formation of Pb S. The reduction process is controlled by chemical reaction and calculation value of the activation energy is 47.88 k J/mol.展开更多
基金Project(51978085)supported by the National Natural Science Foundation of ChinaProject(K2019G045)supported by the Science and Technology Research and Development Plan of China National Railway Group Co.,Ltd.Project(201808430102)supported by the China Scholarship Council。
文摘In this paper,the content and density of adsorbed water in fine-grained soil are determined.According to the test results,the calculation method of compaction degree of the solid-phase and void ration of soil is improved.Four kinds of fine-grained soils from different regions in China were selected,and the adsorbed water content and density of four kinds of fine-grained soils were determined by thermogravimetry and volumetric flask method.Furthermore,SEM and XRD experiments were used to analyze the differences in the ability of each soil sample to absorb water.In order to study the compression characteristics of adsorbed water,four saturated soil samples were tested by consolidation method.The results show that the desorption temperature range of the adsorbed water and its density were equal to 100−115℃and 1.30 g/cm^(3),respectively.Adsorbed water plays a positive role in keeping the compressibility of fine-grained soil at a low rate when it has high water content.Besides,adsorbed water can be a stable parameter and is difficult to discharge during the operation period of subgrade.The settlement of fine-grained soil embankment is predicted by engineering example,and compared with the result of conventional calculation method.The results show that it is more close to the field monitoring results by using the improved void ratio of soil as the parameter.
基金Project(51204210)supported by the National Natural Science Foundation of ChinaProject(2011AA061001)supported by the National High Technology Research and Development Program of ChinaProject(2012BAC12B04)supported by the National Science and Technology Pillar Program during the Twelfth Five-Year Plan of China
文摘In order to decrease the solubility of PbSO4 and enhance lead recovery from PbSO4 bearing wastes, CO was employed as a reductant to transform PbSO4 into Pb S. Reaction system was established and reductive thermodynamics of PbSO4 was calculated by software HSC 5.0. The effects of gas concentration, reaction temperature, time and mass of sample on reduction of PbSO4 were examined by thermogravimetry(TG) and XRD. Roasting tests further verify the conclusions of thermodynamic and TG analyses. The results show that increasing temperature in the reasonable range and CO content are favorable for the formation of Pb S. The reduction process is controlled by chemical reaction and calculation value of the activation energy is 47.88 k J/mol.
