期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
β-C位引入供电子羟基增强季铵化聚砜膜的热碱稳定性
1
作者 李建卫 焉晓明 +4 位作者 阮雪华 郑文姬 贺高红 戴建 邓润连 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2016年第12期38-42,共5页
以氯甲基化的聚砜(CMPSf)为基材,与N-甲基二乙醇胺和N,N-二甲基乙醇胺反应,分别制备了β-C具有供电子羟基的N-甲基二乙醇胺季铵化聚砜膜(PSf-MDOH)和N,N-二甲基乙醇胺季铵化聚砜膜(PSf-DMOH)。在60℃、1 mol/L的KOH溶液中浸泡6 h后,β-... 以氯甲基化的聚砜(CMPSf)为基材,与N-甲基二乙醇胺和N,N-二甲基乙醇胺反应,分别制备了β-C具有供电子羟基的N-甲基二乙醇胺季铵化聚砜膜(PSf-MDOH)和N,N-二甲基乙醇胺季铵化聚砜膜(PSf-DMOH)。在60℃、1 mol/L的KOH溶液中浸泡6 h后,β-C具有供电子羟基的PSf-DMOH膜和PSf-MDOH膜的离子传导率略有下降,但仍保持了良好的膜尺寸稳定性,而β-C无羟基的三乙胺季铵化聚砜膜发生破碎,完全丧失膜形态,表明供电子羟基的引入显著提高了膜的热碱稳定性。同时,2种膜的性能比较发现,低离子交换容量(IEC)时,PSf-MDOH膜的离子传导率高于PSfDMOH膜,但随着IEC的升高,PSf-MDOH膜吸水率急剧增加,膜内有效离子浓度下降,离子传导率低于PSf-DMOH膜。 展开更多
关键词 N N-二甲基乙醇胺 N-甲基二乙醇胺 聚砜 离子传导率 热碱稳定性
在线阅读 下载PDF
Degradation behaviors,thermostability and mechanical properties of poly(ethylene terephthalate)/polylactic acid blends 被引量:1
2
作者 夏学莲 刘文涛 +4 位作者 唐新颖 史向阳 王丽娜 何素芹 朱诚身 《Journal of Central South University》 SCIE EI CAS 2014年第5期1725-1732,共8页
It is difficult for polyethylene terephthalate (PET) to degrade,which caused severe pollution.In this work,polylactic acid (PLA) was introduced to improve the degradation of PET.PET/PLA was synthesized by extrusio... It is difficult for polyethylene terephthalate (PET) to degrade,which caused severe pollution.In this work,polylactic acid (PLA) was introduced to improve the degradation of PET.PET/PLA was synthesized by extrusion blending.The thermal,crystalline and mechanical properties of blends were investigated with TGA,DSC,WAXD and universal testing machine.The degradation of the blends in soil,acid and alkaline buffer solutions was assessed,respectively.It was found that the introduction of a little PLA promoted crystallization of PET during injection molding process.The starting decomposition temperature lowered from 412.1 ℃ of pure PET to 330.4 ℃ at 50% PLA content,tensile and bending strength of blends gradually decreased with the PLA content increasing,while the degradation rate improved.Alkaline environment was most beneficial for blends to degrade.The degradation mechanism was discussed. 展开更多
关键词 DEGRADATION polyester: polylactic acid mechanical property
在线阅读 下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部