Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and t...Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and the reduction conditions of Ag(NH_3)_2^+ were also investigated. The powders prepared were characterized by differential thermal analysis (DTA), X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and energy spectrum analysis. The results show that pH value of the solution is a key parameter in the formation of Sn(OH)_4 precipitate and the reduction reaction of Ag(NH_3)_2^+ can release H+ ions, which results in synchronous precipitation of Sn(OH)_6~2- as Sn(OH)_4. The reduction of Ag(NH_3)_2^+ and precipitation of Na_2SnO_3 occur simultaneously and the coprecipitation of silver and tin oxide is reached by the hydrothermal method. The silver-tin oxide composite powders have mainly flake shape of about 0.3 μm in thickness and there exists homogeneous distribution of tin oxide and silver in the powder synthesized.展开更多
Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two diffe...Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two different modes including filmwise (FWC) and dropwise (DWC) condensation.DWC occurring on hydrophobic and superhydrophobic surfaces has a much higher heat transfer capacity than FWC.Therefore,wide investigations have been done to produce DWC in recent years.Superhydrophobic surfaces have micro/nano structures with low surface energy.In this study,a two-step electrodeposition process is used to produce micro/nano structures on copper specimens.The surface energy of specimens is reduced by a self-assembled monolayer using ethanol and 1-octadecanethiol solution.The results show that there is an optimum condition for electrodeposition parameters.For example,a surface prepared by 2000 s step time has 5 times greater heat transfer than FWC while a surface with 4000 s step time has nearly the same heat transfer as FWC.The surfaces of the fabricated specimens are examined using XRD and SEM analyses.The SEM analyses of the surfaces show that there are some micro-structures on the surfaces and the surface porosities are reduced by increasing the second step electrodeposition time.展开更多
In view of the limitations of solid metal heat sink in the heat dissipation of high power light emitting diode （LED）, a kind of miniaturized phase change heat sink is developed for high power LED packaging. First, t...In view of the limitations of solid metal heat sink in the heat dissipation of high power light emitting diode （LED）, a kind of miniaturized phase change heat sink is developed for high power LED packaging. First, the fabrication process of miniaturized phase change heat sink is investigated, upon which all parts of the heat sink are fabricated including main-body and end-cover of the heat sink, the formation of three-dimensional boiling structures at the evaporation end, the sintering of the wick, and the encapsulation of high power LED phase change heat sink. Subsequently, with the assistance of the developed testing system, heat transfer performance of the heat sink is tested under the condition of natural convection, upon which the influence of thermal load and working medium on the heat transfer performance is investigated. Finally, the heat transfer performance of the developed miniaturized phase change heat sink is compared with that of metal solid heat sink. Results show that the developed miniaturized phase change heat sink presents much better heat transfer performance over traditional metal solid heat sink, and is suitable for the packaging of high power LED.展开更多
基金Project(2001BA901A09)supported by the Key Program of Science and Technology Action of West China Development
文摘Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and the reduction conditions of Ag(NH_3)_2^+ were also investigated. The powders prepared were characterized by differential thermal analysis (DTA), X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and energy spectrum analysis. The results show that pH value of the solution is a key parameter in the formation of Sn(OH)_4 precipitate and the reduction reaction of Ag(NH_3)_2^+ can release H+ ions, which results in synchronous precipitation of Sn(OH)_6~2- as Sn(OH)_4. The reduction of Ag(NH_3)_2^+ and precipitation of Na_2SnO_3 occur simultaneously and the coprecipitation of silver and tin oxide is reached by the hydrothermal method. The silver-tin oxide composite powders have mainly flake shape of about 0.3 μm in thickness and there exists homogeneous distribution of tin oxide and silver in the powder synthesized.
文摘Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two different modes including filmwise (FWC) and dropwise (DWC) condensation.DWC occurring on hydrophobic and superhydrophobic surfaces has a much higher heat transfer capacity than FWC.Therefore,wide investigations have been done to produce DWC in recent years.Superhydrophobic surfaces have micro/nano structures with low surface energy.In this study,a two-step electrodeposition process is used to produce micro/nano structures on copper specimens.The surface energy of specimens is reduced by a self-assembled monolayer using ethanol and 1-octadecanethiol solution.The results show that there is an optimum condition for electrodeposition parameters.For example,a surface prepared by 2000 s step time has 5 times greater heat transfer than FWC while a surface with 4000 s step time has nearly the same heat transfer as FWC.The surfaces of the fabricated specimens are examined using XRD and SEM analyses.The SEM analyses of the surfaces show that there are some micro-structures on the surfaces and the surface porosities are reduced by increasing the second step electrodeposition time.
基金Projects(51575115,51775122)supported by the National Natural Science Foundation of China
文摘In view of the limitations of solid metal heat sink in the heat dissipation of high power light emitting diode （LED）, a kind of miniaturized phase change heat sink is developed for high power LED packaging. First, the fabrication process of miniaturized phase change heat sink is investigated, upon which all parts of the heat sink are fabricated including main-body and end-cover of the heat sink, the formation of three-dimensional boiling structures at the evaporation end, the sintering of the wick, and the encapsulation of high power LED phase change heat sink. Subsequently, with the assistance of the developed testing system, heat transfer performance of the heat sink is tested under the condition of natural convection, upon which the influence of thermal load and working medium on the heat transfer performance is investigated. Finally, the heat transfer performance of the developed miniaturized phase change heat sink is compared with that of metal solid heat sink. Results show that the developed miniaturized phase change heat sink presents much better heat transfer performance over traditional metal solid heat sink, and is suitable for the packaging of high power LED.
