Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging f...Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging from 278.15 K to 318.15 K.The solubility in each system was found to be positively correlated with temperature.Furthermore,solubility data were analyzed using four equations:the modified Apelblat equation,Van’t Hoff equation,λh equation and CNIBS/R-K equations,and they provided satisfactory results for both two systems.The average root-mean-square deviation(105RMSD)values for these models were less than 13.93.Calculations utilizing the Van’t Hoff equation and Gibbs equations facilitated the derivation of apparent thermodynamic properties of NTO dissolution in the two systems,including values for Gibbs free energy,enthalpy and entropy.The%ζ_(H)is larger than%ζ_(TS),and all the%ζ_(H)data are≥58.63%,indicating that the enthalpy make a greater contribution than entropy to theΔG_(soln)^(Θ).展开更多
The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,...The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,this new heating method presents an opportunity for the development of comprehensive facilities.The parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and temperature.In this paper,thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s evaluation.The results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44℃ to−0.44℃ and a heat flux discrepancy of less than 7.54%,which can meet the requirements of practical engineering applications,suggesting a foundation for the prefabricated radiant heating system.展开更多
In this paper,the springback of TC4 titanium alloy under hot stamping condition was studied by means of experiment and numerical analysis.Firstly,an analytical model was established to predict the V-shaped springback ...In this paper,the springback of TC4 titanium alloy under hot stamping condition was studied by means of experiment and numerical analysis.Firstly,an analytical model was established to predict the V-shaped springback angleΔαunder the stretch-bending conditions.The model took into account of blank holder force,friction,property of the material,thickness of the sheet and the neutral layer shift.Then,the influence of several process parameters on springback was studied by experiment and finite element simulation using a V-shaped stamping tool.In the hot stamping tests,the titanium alloy sheet fractured seriously at room temperature.The titanium alloy has good formability when the initial temperature of the sheet is 750–900°C.However,the springback angle of formed parts is large and decreases with increasing temperature.The springback angleΔαdecreased by 50%from 0.5°to 0.25°,and the angleΔβdecreased by 46.7%from 1.5°to 0.8°when the initial temperature of sheet increased from 750°C to 900°C.The springback angle of titanium alloy sheet increases gradually with the increase of the punch radius,because of the increase of elastic recovery,the complex distribution of stress,the length of forming region and the decreasing degree of stress.Compared with the simulation results,the analytical model can better predict the springback angleΔα.展开更多
文摘Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging from 278.15 K to 318.15 K.The solubility in each system was found to be positively correlated with temperature.Furthermore,solubility data were analyzed using four equations:the modified Apelblat equation,Van’t Hoff equation,λh equation and CNIBS/R-K equations,and they provided satisfactory results for both two systems.The average root-mean-square deviation(105RMSD)values for these models were less than 13.93.Calculations utilizing the Van’t Hoff equation and Gibbs equations facilitated the derivation of apparent thermodynamic properties of NTO dissolution in the two systems,including values for Gibbs free energy,enthalpy and entropy.The%ζ_(H)is larger than%ζ_(TS),and all the%ζ_(H)data are≥58.63%,indicating that the enthalpy make a greater contribution than entropy to theΔG_(soln)^(Θ).
基金Project(NB-2020-JG-07)supported by the Research and Engineering Application of Key Technologies for New Building Industrialization Project of China Northwest Architectural Design and Research Institute Co.,Ltd.Project(2023-CXTD-29)supported by the Key Scientific and Technological Innovation Team of Shaanxi Province,ChinaProject supported by the K.C.Wong Education Foundation。
文摘The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,this new heating method presents an opportunity for the development of comprehensive facilities.The parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and temperature.In this paper,thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s evaluation.The results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44℃ to−0.44℃ and a heat flux discrepancy of less than 7.54%,which can meet the requirements of practical engineering applications,suggesting a foundation for the prefabricated radiant heating system.
基金Projects(U1564202,51705018)supported by the National Natural Science Foundation of ChinaProject supported by the Beijing Laboratory of Modern Transportation Metal Materials and Processing Technology and the Beijing Key Laboratory of Metal Forming Lightweight,China。
文摘In this paper,the springback of TC4 titanium alloy under hot stamping condition was studied by means of experiment and numerical analysis.Firstly,an analytical model was established to predict the V-shaped springback angleΔαunder the stretch-bending conditions.The model took into account of blank holder force,friction,property of the material,thickness of the sheet and the neutral layer shift.Then,the influence of several process parameters on springback was studied by experiment and finite element simulation using a V-shaped stamping tool.In the hot stamping tests,the titanium alloy sheet fractured seriously at room temperature.The titanium alloy has good formability when the initial temperature of the sheet is 750–900°C.However,the springback angle of formed parts is large and decreases with increasing temperature.The springback angleΔαdecreased by 50%from 0.5°to 0.25°,and the angleΔβdecreased by 46.7%from 1.5°to 0.8°when the initial temperature of sheet increased from 750°C to 900°C.The springback angle of titanium alloy sheet increases gradually with the increase of the punch radius,because of the increase of elastic recovery,the complex distribution of stress,the length of forming region and the decreasing degree of stress.Compared with the simulation results,the analytical model can better predict the springback angleΔα.
