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钛酸铋钠基无铅压电材料的溶胶-凝胶自蔓燃制备工艺研究 被引量:3
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作者 杜娴 杜慧玲 +1 位作者 黄锦阳 史翔 《人工晶体学报》 EI CAS CSCD 北大核心 2011年第6期1504-1509,共6页
采用溶胶-凝胶自蔓燃法合成具有单一钙钛矿相的0.76Na0.5Bi0.5TiO3-0.24SrTiO3(简写为NBT-ST)的超细粉体。采用热重/差热、X射线粉末衍射、红外光谱等分析手段对自蔓燃工艺前后的粉体进行了分析表征,通过对合成工艺中溶胶pH值、水浴温... 采用溶胶-凝胶自蔓燃法合成具有单一钙钛矿相的0.76Na0.5Bi0.5TiO3-0.24SrTiO3(简写为NBT-ST)的超细粉体。采用热重/差热、X射线粉末衍射、红外光谱等分析手段对自蔓燃工艺前后的粉体进行了分析表征,通过对合成工艺中溶胶pH值、水浴温度、柠檬酸与硝酸根离子配比、热处理温度等参数的优化,获得了制备单一钙钛矿结构的NBT-ST无铅压电材料超细粉体的最优工艺参数:溶胶pH值为8、水浴温度为80℃、柠檬酸与硝酸根离子配比为1.25∶1,185℃左右凝胶发生自蔓燃,热处理温度为550℃,保温时间为1 h。 展开更多
关键词 钛酸铋钠 钛酸锶 钙钛矿相 溶胶-凝胶自蔓燃法
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自蔓燃工艺制备纳米TiO2降解制药废水的研究 被引量:4
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作者 李灵芝 李建渠 包国成 《化学研究与应用》 CAS CSCD 北大核心 2008年第4期465-468,共4页
Using TiOSO4 and iron as materials,a light catalyst with diameters varying between 40 to 70nm has been synthesized through the SAS process and is utilized to degrade a pharmaceutical wastewater.Under different conditi... Using TiOSO4 and iron as materials,a light catalyst with diameters varying between 40 to 70nm has been synthesized through the SAS process and is utilized to degrade a pharmaceutical wastewater.Under different conditions of combustion temperatures,sample pH values of sample,mole ratios of the mixed iron and stirring mode with aeration or supersonic wave as well as magnetic,the degradation effects on COD removal from the wastewater has been investigated.The nano-TiO2 has shown a higher catalytic activation at 600℃,and the removal rate of 80% or 72% is reached under conditions of pH of 4.5 and 3h of radiation with UV or sunshine respectively,while at pH of 2.0,the same treatment give 83% or 78% removal rate respectively.Under conditions of sunshine,600℃ and pH of 4.5,the nano-TiO2 mixed with iron of 0.8% get removal of 85%.The stirring mode has an influence on the COD removal,under the above conditions,stirring with aeration for 20min get a higher removal of 19% or 10% than that with supersonics wave or magnetic power,but after 40min,stirring with magnetic power get the highest removal rate. 展开更多
关键词 溶胶-凝胶自蔓燃法 TIO2 光催化 制药废水
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