In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides ...In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides in diesel were explored. Through studying the mechanism for oxidation of sulfides and the principle of solvent extraction,the kinetic equation of desulfurization via oxidative extraction were determined. By means of the evaluation of model parameters and curve fitting,the reaction order between organic sulfide and sulfone,the intrinsic oxidation rate constant of organic sulfide and sulfone,and the equilibrium constant between sulfone in model diesel and extractive solvent were determined. The experimental values of the desulfurization rate and the theoretical values of the corresponding model equation had closely demonstrated that the desulfurization reaction rate had high accuracy. And the reaction kinetics could provide an important basis for diesel desulfurization process in the future.展开更多
文摘In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides in diesel were explored. Through studying the mechanism for oxidation of sulfides and the principle of solvent extraction,the kinetic equation of desulfurization via oxidative extraction were determined. By means of the evaluation of model parameters and curve fitting,the reaction order between organic sulfide and sulfone,the intrinsic oxidation rate constant of organic sulfide and sulfone,and the equilibrium constant between sulfone in model diesel and extractive solvent were determined. The experimental values of the desulfurization rate and the theoretical values of the corresponding model equation had closely demonstrated that the desulfurization reaction rate had high accuracy. And the reaction kinetics could provide an important basis for diesel desulfurization process in the future.
