Using the mixture of cationic surfactant cetyltrimethylammonium bromide(CTAB) and six nonionic surfactants as templates, meso porous silica was synthesized. The d space of silica templated by CTAB is 3.5 nm. The d spa...Using the mixture of cationic surfactant cetyltrimethylammonium bromide(CTAB) and six nonionic surfactants as templates, meso porous silica was synthesized. The d space of silica templated by CTAB is 3.5 nm. The d spaces could be controlled by changing the ratio of nonionic to cationic surfactants and by increasing the length of nonpolar chain of nonionic surfactants in the mixed cationic nonionic surfactant templating systems. The pore dimension of silica in the mixed surfactants templating system is larger than that in CTAB system and a well ordered structure of pore array was maintained. [WT5HZ]展开更多
研究了十四烷基三甲基氯化铵(TTAC)和十二烷基苯磺酸钠(SDBS)混合表面活性剂水溶液双水相体系的性质,测定了分相区域并绘制了相图,以色氨酸为对象研究了双水相体系的萃取作用。实验结果表明,20~40℃,n(SDBS)∶n(TTAC)=(1.6∶1)^(1∶4)...研究了十四烷基三甲基氯化铵(TTAC)和十二烷基苯磺酸钠(SDBS)混合表面活性剂水溶液双水相体系的性质,测定了分相区域并绘制了相图,以色氨酸为对象研究了双水相体系的萃取作用。实验结果表明,20~40℃,n(SDBS)∶n(TTAC)=(1.6∶1)^(1∶4)可以形成双水相;TTAC过量区双水相上下相体积比随TTAC摩尔分数的增大而减小,加入正丁醇后分相速度加快,可在12 m in内分相,上下相体积比增大;电导率曲线与偏光显微镜图片表明,TTAC过量区双水相下相存在松散的液晶结构。该文报道工作的新颖性已为科学技术部西南信息中心查新中心2007年8月16日出具的第J 20071385号《科技查新报告》所证实。展开更多
Cloud point property was found in the aqueous mixtures of sodium dodecyl sulfate（SDS）and cetyl trimethyl ammonium bromide（CTAB）and the cloud point area in pseudo ternary plase diagram of SDS/CTAB/Na2SO4/H2O was st...Cloud point property was found in the aqueous mixtures of sodium dodecyl sulfate（SDS）and cetyl trimethyl ammonium bromide（CTAB）and the cloud point area in pseudo ternary plase diagram of SDS/CTAB/Na2SO4/H2O was studied.It was found that the cloud point area was the aqueous two-phase system area,in which the containing of SDS was more than that of CTAB.The cloud point area would enlarge when the temperature was high and the length of cationic surfactant carbochain had some effect on the position of cloud point area.展开更多
文摘Using the mixture of cationic surfactant cetyltrimethylammonium bromide(CTAB) and six nonionic surfactants as templates, meso porous silica was synthesized. The d space of silica templated by CTAB is 3.5 nm. The d spaces could be controlled by changing the ratio of nonionic to cationic surfactants and by increasing the length of nonpolar chain of nonionic surfactants in the mixed cationic nonionic surfactant templating systems. The pore dimension of silica in the mixed surfactants templating system is larger than that in CTAB system and a well ordered structure of pore array was maintained. [WT5HZ]
文摘研究了十四烷基三甲基氯化铵(TTAC)和十二烷基苯磺酸钠(SDBS)混合表面活性剂水溶液双水相体系的性质,测定了分相区域并绘制了相图,以色氨酸为对象研究了双水相体系的萃取作用。实验结果表明,20~40℃,n(SDBS)∶n(TTAC)=(1.6∶1)^(1∶4)可以形成双水相;TTAC过量区双水相上下相体积比随TTAC摩尔分数的增大而减小,加入正丁醇后分相速度加快,可在12 m in内分相,上下相体积比增大;电导率曲线与偏光显微镜图片表明,TTAC过量区双水相下相存在松散的液晶结构。该文报道工作的新颖性已为科学技术部西南信息中心查新中心2007年8月16日出具的第J 20071385号《科技查新报告》所证实。
文摘Cloud point property was found in the aqueous mixtures of sodium dodecyl sulfate（SDS）and cetyl trimethyl ammonium bromide（CTAB）and the cloud point area in pseudo ternary plase diagram of SDS/CTAB/Na2SO4/H2O was studied.It was found that the cloud point area was the aqueous two-phase system area,in which the containing of SDS was more than that of CTAB.The cloud point area would enlarge when the temperature was high and the length of cationic surfactant carbochain had some effect on the position of cloud point area.
