The precipitation performance and kinetics of gibbsite from sodium aluminate solution with different sodium oxalate concentrations as well as the corresponding influence mechanism of oxalate during the seed precipitat...The precipitation performance and kinetics of gibbsite from sodium aluminate solution with different sodium oxalate concentrations as well as the corresponding influence mechanism of oxalate during the seed precipitation process were systematically investigated by physicochemical properties test,using SEM and Raman spectra.As the concentration of sodium oxalate increases,both the precipitation rate and particle size of gibbsite decrease.The presence of sodium oxalate not only increases the viscosity of sodium aluminate solution,but also promotes the transformation of Al(OH)4^? to Al2O(OH)6^2?.The overall reaction rate constant decreases and the apparent activation energy of gibbsite increases with the increasing sodium oxalate concentration,the rate controlling step of which is chemical reaction.The needle-like sodium oxalate precipitates on the gibbsite crystals and covers the active Al(OH)3 seed sites,which leads to the lower precipitation rate and the finer particle size of gibbsite during the seed precipitation process.展开更多
According to the existing problems of liquefaction models of saturated sand that were put forward under dynamic action,on the basis of Handin-Drnevich model,a new calculating model of the dynamic constitutive relation...According to the existing problems of liquefaction models of saturated sand that were put forward under dynamic action,on the basis of Handin-Drnevich model,a new calculating model of the dynamic constitutive relation of saturated sand was put forward.The model was based on the basic hypothesis of instantaneous limit balance according to the basic principle that the stress estate is the destroyed condition was not overstepped.The calculated method of increment nonlinear was referenced and combined with the excellence of the model of distributed particles.The process of vibrating liquefaction of saturated sand was divided into some areas.And the phenomena of shearing dilatation and unloading shrink of saturated sand were considered.On above basic a new calculating constitutive relation model was proposed.There are a few parameters in the model.The physical means of the parameters are very evident and quantized.They could be obtained from the dynamic triaxial test in door.The model was contrasted and validated with the results of the dynamic triaxial test in door.The comparison of the results of the dynamic triaxial test in door and the calculating results of the model indicates that all sorts of phenomenon appearing in the process of liquefaction of saturated sand could be more perfectly reflected by the model.Especially at the initial stage of development of pore water pressure and strain of saturated sand,the results of the dynamic triaxial test in door are consistent with the calculated results of the model very much.But there is some difference between the results at the anaphase of development of pore water pressure and strain.On the path of stress,the calculating and experimenting ultimate state surfaces are almost identical.展开更多
A new electro-hydraulic exciter that consists of rotary valve and micro-displacement double-functioned hydraulic cylinder was proposed to realize different kinds of waveforms.Calculated fluid dynamics(CFD) simulation ...A new electro-hydraulic exciter that consists of rotary valve and micro-displacement double-functioned hydraulic cylinder was proposed to realize different kinds of waveforms.Calculated fluid dynamics(CFD) simulation of rotary valve orifice reveals that orifice exists the two-throttle phenomenon.According to the finding,the revised flow area model was established.Vibration waveforms analysis was carried out by means of mathematic model and the related experiments were validated.Furthermore,as a new analysis indicator,saturation percentage was introduced first.The experimental results indicate that the revised flow area model is more accurate compared to the original one,and vibration waveforms can be optimized through suitable spool parameters and the revised cylinder structure.展开更多
Consider the design and implementation of an electro-hydraulic control system for a robotic excavator, namely the Lancaster University computerized and intelligent excavator (LUCIE). The excavator was developed to aut...Consider the design and implementation of an electro-hydraulic control system for a robotic excavator, namely the Lancaster University computerized and intelligent excavator (LUCIE). The excavator was developed to autonomously dig trenches without human intervention. One stumbling block is the achievement of adequate, accurate, quick and smooth movement under automatic control, which is difficult for traditional control algorithm, e.g. PI/PID. A gain scheduling design, based on the true digital proportional-integral-plus (PIP) control methodology, was utilized to regulate the nonlinear joint dynamics. Simulation and initial field tests both demonstrated the feasibility and robustness of proposed technique to the uncertainties of parameters, time delay and load disturbances, with the excavator arm directed along specified trajectories in a smooth, fast and accurate manner. The tracking error magnitudes for oblique straight line and horizontal straight line are less than 20 mm and 50 mm, respectively, while the velocity reaches 9 m/min.展开更多
Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and su...Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.展开更多
基金Projects(51774079,51674075)supported by the National Natural Science Foundation of ChinaProject(N182508026)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The precipitation performance and kinetics of gibbsite from sodium aluminate solution with different sodium oxalate concentrations as well as the corresponding influence mechanism of oxalate during the seed precipitation process were systematically investigated by physicochemical properties test,using SEM and Raman spectra.As the concentration of sodium oxalate increases,both the precipitation rate and particle size of gibbsite decrease.The presence of sodium oxalate not only increases the viscosity of sodium aluminate solution,but also promotes the transformation of Al(OH)4^? to Al2O(OH)6^2?.The overall reaction rate constant decreases and the apparent activation energy of gibbsite increases with the increasing sodium oxalate concentration,the rate controlling step of which is chemical reaction.The needle-like sodium oxalate precipitates on the gibbsite crystals and covers the active Al(OH)3 seed sites,which leads to the lower precipitation rate and the finer particle size of gibbsite during the seed precipitation process.
基金Project(59979001) supported by the National Natural Science Foundation of China
文摘According to the existing problems of liquefaction models of saturated sand that were put forward under dynamic action,on the basis of Handin-Drnevich model,a new calculating model of the dynamic constitutive relation of saturated sand was put forward.The model was based on the basic hypothesis of instantaneous limit balance according to the basic principle that the stress estate is the destroyed condition was not overstepped.The calculated method of increment nonlinear was referenced and combined with the excellence of the model of distributed particles.The process of vibrating liquefaction of saturated sand was divided into some areas.And the phenomena of shearing dilatation and unloading shrink of saturated sand were considered.On above basic a new calculating constitutive relation model was proposed.There are a few parameters in the model.The physical means of the parameters are very evident and quantized.They could be obtained from the dynamic triaxial test in door.The model was contrasted and validated with the results of the dynamic triaxial test in door.The comparison of the results of the dynamic triaxial test in door and the calculating results of the model indicates that all sorts of phenomenon appearing in the process of liquefaction of saturated sand could be more perfectly reflected by the model.Especially at the initial stage of development of pore water pressure and strain of saturated sand,the results of the dynamic triaxial test in door are consistent with the calculated results of the model very much.But there is some difference between the results at the anaphase of development of pore water pressure and strain.On the path of stress,the calculating and experimenting ultimate state surfaces are almost identical.
基金Project(51275499)supported by the National Natural Science Foundation of ChinaProject(2013CB035404)supported by the National Basic Research Program("973" Program)of ChinaProject(51221004)supported by the Science Fund for Creative Research Groups,National Natural Science Foundation of China
文摘A new electro-hydraulic exciter that consists of rotary valve and micro-displacement double-functioned hydraulic cylinder was proposed to realize different kinds of waveforms.Calculated fluid dynamics(CFD) simulation of rotary valve orifice reveals that orifice exists the two-throttle phenomenon.According to the finding,the revised flow area model was established.Vibration waveforms analysis was carried out by means of mathematic model and the related experiments were validated.Furthermore,as a new analysis indicator,saturation percentage was introduced first.The experimental results indicate that the revised flow area model is more accurate compared to the original one,and vibration waveforms can be optimized through suitable spool parameters and the revised cylinder structure.
基金Project(K5117827)supported by Scientific Research Foundation for the Returned Overseas Chinese ScholarsProject(08KJB510021)supported by the Natural Science Research Council of Jiangsu Province,China+1 种基金Project(Q3117918)supported by Scientific Research Foundation for Young Teachers of Soochow University,ChinaProject(60910001)supported by National Natural Science Foundation of China
文摘Consider the design and implementation of an electro-hydraulic control system for a robotic excavator, namely the Lancaster University computerized and intelligent excavator (LUCIE). The excavator was developed to autonomously dig trenches without human intervention. One stumbling block is the achievement of adequate, accurate, quick and smooth movement under automatic control, which is difficult for traditional control algorithm, e.g. PI/PID. A gain scheduling design, based on the true digital proportional-integral-plus (PIP) control methodology, was utilized to regulate the nonlinear joint dynamics. Simulation and initial field tests both demonstrated the feasibility and robustness of proposed technique to the uncertainties of parameters, time delay and load disturbances, with the excavator arm directed along specified trajectories in a smooth, fast and accurate manner. The tracking error magnitudes for oblique straight line and horizontal straight line are less than 20 mm and 50 mm, respectively, while the velocity reaches 9 m/min.
基金Project(2008ZX07105-002) supported by the Erhai Lake Project of National Science and Technology Major Project in the 11th Five years Plan of China
文摘Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.
