Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected ...Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected with water molecules by hydrogen bonding, while the non-polar group showed that hydrophobic property and water molecules around it were repelled away. The adsorption of water molecules on single frother molecule suggests that the complexes of α-terpineol-7H2O, MIBC-7H2O and DF200-13H2O reach their stable structure. The hydration shell affects both the polar head group and the non-polar group. The liquid film drainage rate of DF200 is the lowest, while α-terpineol and MIBC are almost the same. The adsorption layer of frother molecules adsorbed at the gas-liquid interface reveals that the α-terpineol molecules are more neatly arranged and better distributed. The DF200 molecules are arranged much more loosely than MIBC molecules. These results suggest that the α-terpineol molecule layer could better block the diffusion of gas through the liquid film than DF200 and MIBC. The simulation results indicate that the foam stability of α-terpineol is the best, followed by DF200 and MIBC.展开更多
In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy ...In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy c means(FCM) algorithm. Through the attributes of size and shape pattern spectrum,the optimal morphological structuring element was determined.According to the optimal parameters,some image noises were removed with an improved area opening and closing by reconstruction operation,which consist of image regional markers,and the bubbles were finely separated from each other by watershed transform.The experimental results show that the structural element can be determined adaptively by shape and size pattern spectrum,and the froth image is segmented accurately.Compared with other froth image segmentation method,the proposed method achieves much high accuracy,based on which,the bubble size and shape features are extracted effectively.展开更多
基金Projects(51574092,51874106)supported by the National Natural Science Foundation,ChinaProject supported by Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase),China
文摘Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected with water molecules by hydrogen bonding, while the non-polar group showed that hydrophobic property and water molecules around it were repelled away. The adsorption of water molecules on single frother molecule suggests that the complexes of α-terpineol-7H2O, MIBC-7H2O and DF200-13H2O reach their stable structure. The hydration shell affects both the polar head group and the non-polar group. The liquid film drainage rate of DF200 is the lowest, while α-terpineol and MIBC are almost the same. The adsorption layer of frother molecules adsorbed at the gas-liquid interface reveals that the α-terpineol molecules are more neatly arranged and better distributed. The DF200 molecules are arranged much more loosely than MIBC molecules. These results suggest that the α-terpineol molecule layer could better block the diffusion of gas through the liquid film than DF200 and MIBC. The simulation results indicate that the foam stability of α-terpineol is the best, followed by DF200 and MIBC.
基金Projects(60634020,60874069) supported by the National Natural Science Foundation of ChinaProject(2009AA04Z137) supported by the National High-Tech Research and Development Program of China
文摘In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy c means(FCM) algorithm. Through the attributes of size and shape pattern spectrum,the optimal morphological structuring element was determined.According to the optimal parameters,some image noises were removed with an improved area opening and closing by reconstruction operation,which consist of image regional markers,and the bubbles were finely separated from each other by watershed transform.The experimental results show that the structural element can be determined adaptively by shape and size pattern spectrum,and the froth image is segmented accurately.Compared with other froth image segmentation method,the proposed method achieves much high accuracy,based on which,the bubble size and shape features are extracted effectively.
