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离子选择电极法测定水热气体中的硼含量及硼的气态迁移能力研究 被引量:2
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作者 张生 陈根文 Seward T M 《岩矿测试》 CAS CSCD 北大核心 2016年第4期358-365,共8页
火山和成矿地质现象表明硼可以在含水流体和气体中运移,本文应用离子选择电极法测定水热气体中硼的溶解度,以揭示硼的气态迁移能力。使用氟硼酸盐选择电极,测定了经氟硼酸化的硼酸标准溶液和含硼气体凝结水的电位,当硼含量处于地质流体... 火山和成矿地质现象表明硼可以在含水流体和气体中运移,本文应用离子选择电极法测定水热气体中硼的溶解度,以揭示硼的气态迁移能力。使用氟硼酸盐选择电极,测定了经氟硼酸化的硼酸标准溶液和含硼气体凝结水的电位,当硼含量处于地质流体的主要范围内(0.52-524.50 mg/L)时,电极电位与硼浓度的对数呈现出灵敏度很高的能斯特线性关系,标准曲线具有很好的稳定性和重现性。本方法测定硼的检出限为0.13 mg/L,低于饮用水标准规定的硼含量限值,适用于测定水热气体中的硼含量。硼酸挥发实验显示,硼在150℃、0.37 MPa水蒸气中的含量可达0.65%-0.72%,与富硼火山喷气的硼含量相符,显示硼在高温水热条件下可在气相中显著迁移,且H3BO3气态分子是硼的主要迁移形式之一。矿床地质特征和实验表明,硼的气态迁移和电气石化与稀有金属型伟晶岩的形成和矿化以及某些热液-气成型Sn-W、Mo矿床和斑岩型Cu、Au矿床的形成密切相关。 展开更多
关键词 水热气体 气态迁移 离子选择电极法
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Numerical investigation of optimal geometry parameters for ejectors of premixed burner
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作者 刘凤国 张蕊 +2 位作者 刘文博 翟军 郑斌 《Journal of Central South University》 SCIE EI CAS 2014年第3期1011-1016,共6页
An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics (CFD) approach. A comprehen... An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics (CFD) approach. A comprehensive study was conducted to understand the effects of the geometrical parameters on the static pressure of air and methane, and mole fraction uniformity of methane at the outlet of ejector. The distribution chamber was applied to balance the pressure and improve the mixing process of methane and air in front of the fire hole. A distribution orifice plate with seven distribution orifices was introduced at the outlet of the ejector to improve the flow organization. It is found that the nozzle exit position of 5 mm and nozzle diameter d 〉1.3 mm should be used to improve the flow organization and realize the well premixed combustion for this designed ejector. 展开更多
关键词 EJECTOR computational fluid dynamics (CFD) bumer distribution orifice premixed combustion
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