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水热介质对氢氧化镁晶体生长的影响 被引量:5
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作者 李秋菊 刘华彦 +3 位作者 卢晗锋 谢晶 郑敏珠 陈银飞 《浙江工业大学学报》 CAS 2007年第4期389-393,共5页
以含氯化镁废液和氨水直接沉淀制备的工业级氢氧化镁为原料,经过水热处理制备氢氧化镁阻燃剂,重点考察以纯水、氨水、氢氧化钠和碳酸钠为水热介质对氢氧化镁晶体生长的影响.采用了扫描电镜(SEM),X射线衍射分析(XRD),全自动氮物理吸附仪(... 以含氯化镁废液和氨水直接沉淀制备的工业级氢氧化镁为原料,经过水热处理制备氢氧化镁阻燃剂,重点考察以纯水、氨水、氢氧化钠和碳酸钠为水热介质对氢氧化镁晶体生长的影响.采用了扫描电镜(SEM),X射线衍射分析(XRD),全自动氮物理吸附仪(BET)和激光粒度仪等对水热改性的氢氧化镁进行表征分析,结果表明原料氢氧化镁经过水热处理后,在一定程度上都可以改善氢氧化镁晶体的形貌和团聚,其中以4.0 mol/L氢氧化钠溶液和1.0 mol/L碳酸钠溶液作为水热介质,改性后的Mg(OH)2最好.同时探讨不同水热介质下氢氧化镁晶体生长机理. 展开更多
关键词 水热介质 氢氧化镁 阻燃剂
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Coupled thermo-hydro-mechanical-migratory model for dual-porosity medium and numerical analysis 被引量:6
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作者 张玉军 杨朝帅 《Journal of Central South University》 SCIE EI CAS 2011年第4期1256-1262,共7页
A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the see... A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity. 展开更多
关键词 ubiquitous-joint rockmass dual-porosity medium thermo-hydro-mechanical-migratory coupling model numericalanalysis
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Hydrothermal synthesis and dielectric properties of lanthanum titanate ceramics
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作者 邓元 南策文 《Journal of Central South University of Technology》 2005年第3期251-254,共4页
Lanthanum titanate (La2/3 TiO3) powders were synthesized by hydrothermal method based on the reaction of TiO2, La(NO3)3 and KOH at 160℃ for 24 h followed by the treatment of acidification. The microstructure, mor... Lanthanum titanate (La2/3 TiO3) powders were synthesized by hydrothermal method based on the reaction of TiO2, La(NO3)3 and KOH at 160℃ for 24 h followed by the treatment of acidification. The microstructure, morphology and dielectric properties were investigated by using X-ray diffraction, scanning electron microscope, transmission electron microscope and impedance method. The results show that the La2/3TiO3 particles consist of nearly homogenous and lamellar grains. The particles can be sintered into porous ceramics above 1150℃. The dielectric properties of La2/3 TiO3 show that both the dielectric constant and the dielectric loss tangent decrease with the increase of frequency. 展开更多
关键词 lanthanum titanate dielectric properties hydrothermal synthesis
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