Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm...Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.展开更多
The water-inrush mechanism of strong water-guide collapse column in coal seam is studied based on the establishment of geological and mathematical models of "triangle" water-inrush mode. The geological backg...The water-inrush mechanism of strong water-guide collapse column in coal seam is studied based on the establishment of geological and mathematical models of "triangle" water-inrush mode. The geological background of Shuangliu mine is considered a prototype, similar simulation tests are adopted to analyze the water-inrush rules under this model, and the formation of water-guide channel and water-inrush process is investigated by examining the changes in rock resistivity. This work also uses the coupled cloud image derived from numerical simulation software to verify the results of simulation test. Results show that the numerical simulation of "triangle" water-inrush mode is consistent with the similar simulation. The "triangle" seepage area, which is located at the bottom of collapse columns and is connected to aquifer, is caused by the altered seepage direction and strengthened seepage actions after the overlapping of hydraulic transverse seepage in collapse column and hydraulic vertical seepage flow in aquifer. Under "triangle"water-inrush model, water-guide channel is formed by the communication between plastic failure zone of working face baseplate and"triangular" seepage area. Accordingly, the threatening water-inrush distance between working face and collapse column increases by 20 m compared with that of theoretical calculation.展开更多
In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, t...In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, the corresponding discretization and linearization methods were given. Due to the mass transfer between air-phase and water-phase, phase states of the model elements were constantly changing. Thus, parameters of the model were divided into primary ones and secondary ones, and the primary variables changing with phase states and the secondary variables can be obtained by their functional relationship with the primary variables. Additionally, the special definite condition of this numerical model was illustrated. Two examples were given to simulate the airflow in soil whether there was groundwater or not, and the effectiveness of the numerical model is verified by comparing the results of simulation with that of exoeriment.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52074130)the Engineering Research Center of Resource Utilization of Carbon-containing Waste with Carbon Neutrality,Ministry of Education。
文摘Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.
基金Projects(51374093,51104058)supported by the National Natural Science Foundation of ChinaProject(2013CB227903)supported by the National Basic Research Program of China
文摘The water-inrush mechanism of strong water-guide collapse column in coal seam is studied based on the establishment of geological and mathematical models of "triangle" water-inrush mode. The geological background of Shuangliu mine is considered a prototype, similar simulation tests are adopted to analyze the water-inrush rules under this model, and the formation of water-guide channel and water-inrush process is investigated by examining the changes in rock resistivity. This work also uses the coupled cloud image derived from numerical simulation software to verify the results of simulation test. Results show that the numerical simulation of "triangle" water-inrush mode is consistent with the similar simulation. The "triangle" seepage area, which is located at the bottom of collapse columns and is connected to aquifer, is caused by the altered seepage direction and strengthened seepage actions after the overlapping of hydraulic transverse seepage in collapse column and hydraulic vertical seepage flow in aquifer. Under "triangle"water-inrush model, water-guide channel is formed by the communication between plastic failure zone of working face baseplate and"triangular" seepage area. Accordingly, the threatening water-inrush distance between working face and collapse column increases by 20 m compared with that of theoretical calculation.
基金Project(Y5080022) supported by the Natural Science Foundation of Zhejiang Province,ChinaProject(RC1202) supported by Scientific and Technological Program of Water Resources Department of Zhejiang Province in 2012,ChinaProject(Y201224384) supported by Scientific Research Program of Education Department of Zhejiang Province in 2012,China
文摘In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, the corresponding discretization and linearization methods were given. Due to the mass transfer between air-phase and water-phase, phase states of the model elements were constantly changing. Thus, parameters of the model were divided into primary ones and secondary ones, and the primary variables changing with phase states and the secondary variables can be obtained by their functional relationship with the primary variables. Additionally, the special definite condition of this numerical model was illustrated. Two examples were given to simulate the airflow in soil whether there was groundwater or not, and the effectiveness of the numerical model is verified by comparing the results of simulation with that of exoeriment.
