[RuCl2（TPPTS）2]2 was used as a catalyst for the isomerization of 1-hexene in water/organic biphasic system. The effects of reaction temperature and the concentrations of CTAB 、 TPPTS 、 catalyst on the conversion w...[RuCl2（TPPTS）2]2 was used as a catalyst for the isomerization of 1-hexene in water/organic biphasic system. The effects of reaction temperature and the concentrations of CTAB 、 TPPTS 、 catalyst on the conversion were studied. The temperature and the addition of surfactant（CTAB） can enhance conversion and selectivity of reaction. Under the conditions of 200 ℃、 0.38 MPa、 [Ru]0.06 mol/L、 t=4h, the conversion of 1-hexene is 87.0% .Selectivity of 2-hexene and 3-hexene is 31.7% and 57.0%.展开更多
文摘[RuCl2（TPPTS）2]2 was used as a catalyst for the isomerization of 1-hexene in water/organic biphasic system. The effects of reaction temperature and the concentrations of CTAB 、 TPPTS 、 catalyst on the conversion were studied. The temperature and the addition of surfactant（CTAB） can enhance conversion and selectivity of reaction. Under the conditions of 200 ℃、 0.38 MPa、 [Ru]0.06 mol/L、 t=4h, the conversion of 1-hexene is 87.0% .Selectivity of 2-hexene and 3-hexene is 31.7% and 57.0%.
