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AlCl_3(ZnCl_2,MgCl_2)对Sm_2O_3的氯化效果及电化学行为
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作者 薛云 杨雪 +4 位作者 颜永得 张密林 纪德彬 韩伟 李恩雨 《无机化学学报》 SCIE CAS CSCD 北大核心 2016年第4期575-582,共8页
研究了AlCl_3(ZnCl_2、MgCl_2)对Sm_2O_3的氯化效果以及Sm_2O_3在Li Cl-KCl-AlCl_3(ZnCl_2、MgCl_2)熔盐体系中的电化学行为。在Li Cl-KCl-Sm_2O_3熔盐中加入AlCl_3(ZnCl_2、MgCl_2)后,ICP测量结果表明,AlCl_3体系中Sm(Ⅲ)离子的浓度最... 研究了AlCl_3(ZnCl_2、MgCl_2)对Sm_2O_3的氯化效果以及Sm_2O_3在Li Cl-KCl-AlCl_3(ZnCl_2、MgCl_2)熔盐体系中的电化学行为。在Li Cl-KCl-Sm_2O_3熔盐中加入AlCl_3(ZnCl_2、MgCl_2)后,ICP测量结果表明,AlCl_3体系中Sm(Ⅲ)离子的浓度最高,并且在923 K时达到最大值;固相反应表明,AlCl_3氯化Sm_2O_3生成SmCl_3,而Sm_2O_3和ZnCl_2(MgCl_2)反应生成Sm OCl。电化学行为表明,AlCl_3体系中观察到了两种Al-Sm的合金峰,而ZnCl_2体系中只观察到Zn-Sm金属间化合物的形成峰,MgCl_2体系中没有形成合金。在-6.25 A·cm^(-2)下,W电极上恒电流电解2 h获得了Al-Li-Sm合金,经XRD分析,合金为Al_2Sm相。 展开更多
关键词 LiCl-KCl-Sm2O3熔盐 电化学行为 氯化效果 铝钐合金
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Analysis of inhibition of concrete steel-rebar corrosion by Na_2Cr_2O_7 concentrations:Implications for conflicting reports on inhibitor effectiveness 被引量:1
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作者 J.O.Okeniyi I.O.Oladele +4 位作者 I.J.Ambrose S.O.Okpala O.M.Omoniyi C.A.Loto A.P.I.Popoola 《Journal of Central South University》 SCIE EI CAS 2013年第12期3697-3714,共18页
Corrosion test data were measured using non-destructive electrochemical techniques and analysed for studying inhibition effectiveness by different concentrations of NazCr207 on the corrosion of concrete steel-rehar in... Corrosion test data were measured using non-destructive electrochemical techniques and analysed for studying inhibition effectiveness by different concentrations of NazCr207 on the corrosion of concrete steel-rehar in NaC1 and in H2SO4 media. For these, specifications of ASTM G16-95 R04 were combined with the normal and the Gumbel probability density functions as model analytical methods for addressing issues of conflicting reports of inhibitor effectiveness that had generated concerns. Results show that reinforced concrete samples admixed with concentrations having 4 g (0.012 7 tool), 8 g (0.025 4 mol) and 6 g (0.019 l tool) NaaCr207 exhibited, in that order, high inhibition effectiveness, with respective efficiency, r/, of (90.46±1.30)%, (88.41+2.24)% and (84.87±4.74)%, in the NaC1 medium. These exhibit good agreements within replicates and statistical methods for the samples. Also, optimal inhibition effectiveness model in the H2SO4 medium was exhibited by 8 g (0.025 4 mol) Na2Cr207 concentration having r/=(78.44±1.10)%. These bear implications for addressing conflicting test data in the study of effective inhibitors for mitigating steel-rebar corrosion in aggressive environments. 展开更多
关键词 corrosion inhibitor effectiveness saline/marine and industrial/microbial environments concrete steel-rebar normal andGumbel probability distribution functions Kolmogorov-Smirnov statistics tests of significance
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