Dinuclear copper complex with biradical, [Cu(hfac) 2] 2PhBNOM\[PhBNOM=2,5 bimethoxyl 1,4 bis(4,4,5,5 tetramethyllimidazoline 1 oxyl 3 oxide)phenyl, hfac=hexafluoroacetylacetonate], has been synthesized and characteriz...Dinuclear copper complex with biradical, [Cu(hfac) 2] 2PhBNOM\[PhBNOM=2,5 bimethoxyl 1,4 bis(4,4,5,5 tetramethyllimidazoline 1 oxyl 3 oxide)phenyl, hfac=hexafluoroacetylacetonate], has been synthesized and characterized. It crystallized in the monoclinic system; space group C2/c with a = \{1\^877 3(8)\} nm, b =1.359 8(5) nm, c =2.237 1(7) nm, β =97.24(3)°, Z =4, R = 0.096 1 , R w=0 094 4 .展开更多
文摘Dinuclear copper complex with biradical, [Cu(hfac) 2] 2PhBNOM\[PhBNOM=2,5 bimethoxyl 1,4 bis(4,4,5,5 tetramethyllimidazoline 1 oxyl 3 oxide)phenyl, hfac=hexafluoroacetylacetonate], has been synthesized and characterized. It crystallized in the monoclinic system; space group C2/c with a = \{1\^877 3(8)\} nm, b =1.359 8(5) nm, c =2.237 1(7) nm, β =97.24(3)°, Z =4, R = 0.096 1 , R w=0 094 4 .
