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Pt/Ce_xZr_(1-x)O_2/γ-Al_2O_3整体式催化剂上的氢气燃烧性能研究 被引量:5
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作者 宫振华 张存满 +2 位作者 肖方暐 高鑫 马建新 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2008年第5期1-5,10,共6页
研究了添加CexZr1-xO2对Pt/γ-Al2O3/堇青石整体式催化剂氢气催化燃烧性能的影响。结果表明,CexZr1-xO2的添加明显提高了催化剂的活性,并且随着Ce/Zr比的增大,催化剂活性逐渐增强。XRD结果显示,随着Ce/Zr比的增大,CexZr1-xO2立方相固溶... 研究了添加CexZr1-xO2对Pt/γ-Al2O3/堇青石整体式催化剂氢气催化燃烧性能的影响。结果表明,CexZr1-xO2的添加明显提高了催化剂的活性,并且随着Ce/Zr比的增大,催化剂活性逐渐增强。XRD结果显示,随着Ce/Zr比的增大,CexZr1-xO2立方相固溶体的衍射峰越来越明显,这表明Ce/Zr比的增大有利于CexZr1-xO2立方相固溶体的形成。N2吸附-脱附测试结果表明,添加10%质量分数的CexZr1-xO2对γ-Al2O3的比表面积影响不大,而使其孔径和孔容明显减小。当氢气浓度较低时,空速和湿度对氢气的转化率影响较大;而当氢气浓度较高时,空速和湿度对氢气的转化率影响不大。 展开更多
关键词 氢气催化燃烧 Pt/γ-Al2O3/堇青石催化 整体式催化 CexZr1-xO2 操作参数
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不同载体Pt基整体式催化剂对氢气低温反应性能的影响 被引量:3
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作者 周颖 唐爱坤 +1 位作者 倪强 李冲 《江苏大学学报(自然科学版)》 CAS 北大核心 2023年第2期207-212,220,共7页
以H型分子筛-5(hydrogen zeolite sieve molecular-5,HZSM-5)和氧化物(Al_(2)O_(3)、TiO_(2)和SiO_(2))涂层为载体、堇青石蜂窝陶瓷为基体、贵金属铂(Pt)为活性组分,制备了Pt/载体/堇青石整体式催化剂.利用XRD、SEM、TEM和XPS等表征手段... 以H型分子筛-5(hydrogen zeolite sieve molecular-5,HZSM-5)和氧化物(Al_(2)O_(3)、TiO_(2)和SiO_(2))涂层为载体、堇青石蜂窝陶瓷为基体、贵金属铂(Pt)为活性组分,制备了Pt/载体/堇青石整体式催化剂.利用XRD、SEM、TEM和XPS等表征手段,对催化剂的结构与性质进行了分析.探讨了在氢气体积分数为2.5%的环境中,不同载体、不同Pt负载量对氢气低温催化燃烧反应性能的影响.研究结果表明:以HZSM-5为载体的整体式催化剂性能最优,这与催化剂活性层黏结性良好、Pt在该载体上的分布良好及其粒径均匀有关;以SiO_(2)为载体的催化剂性能最差,测试显示这种载体上Pt 0种类含量最少,且Pt负载不牢;Pt负载量为0.01 g·L^(-1)时,Pt/HZSM-5/堇青石整体式催化剂的催化活性较好;Pt负载量为0.05 g·L^(-1)及以上时,整体式催化剂均能在室温下快速起燃,并实现氢气转化率为100%. 展开更多
关键词 整体式催化 堇青石 负载量 氢气低温催化燃烧 H型分子筛-5
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Effects analysis on catalytic combustion characteristic of hydrogen/air in micro turbine engine by fuzzy grey relation method 被引量:4
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作者 E Jia-qiang WU Jiang-hua +3 位作者 LIU Teng CHEN Jing-wei DENG Yuan-wang PENG Qing-guo 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第8期2214-2223,共10页
In order to enhance catalytic combustion efficiency, a premixed hydrogen /air combustion model of the micro turbine engine is established under different excess air ratio, inlet velocity and heat transfer coefficient.... In order to enhance catalytic combustion efficiency, a premixed hydrogen /air combustion model of the micro turbine engine is established under different excess air ratio, inlet velocity and heat transfer coefficient. And effects of inlet velocity, excess air coefficient and heat transfer coefficient on the catalytic combustion efficiency of the hydrogen have been analyzed by the FLUENT with CHEMKIN reaction mechanisms and the fuzzy grey relation theory. It is showed that inlet velocity has a more intuitive influence on the catalytic combustion efficiency of the hydrogen. A higher efficiency can be obtained with a lower inlet velocity. The optimum excess air coefficient is in the range of 0.94 to 1.0, the catalytic combustion efficiency of the hydrogen will be declined if the excess air coefficient exceeded 1.0. The effect of heat transfer coefficient on the catalytic combustion efficiency of the hydrogen mainly embodies in the case of the excess air coefficient exceeded 1.0, however, the effect will be declined if the heat transfer coefficient exceeded 4.0. The fuzzy grey relation degrees of the inlet velocity, heat transfer coefficient and excess air coefficient on the catalytic combustion efficiency of the hydrogen are 0.640945, 0.633214 and 0.547892 respectively. 展开更多
关键词 micro turbine engine catalytic combustion HYDROGEN fuzzy grey relation theory
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