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Pt/PolyCuTAPc/Nafion修饰电极及其应用的研究 被引量:5
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作者 罗敏 李辉 +2 位作者 曹旭妮 张凌越 金利通 《华东师范大学学报(自然科学版)》 CAS CSCD 北大核心 2000年第3期74-78,共5页
本文报道了用电化学聚合方法制备聚四氨基铜酞菁Pt/PolyCuTAPc/Nafion修饰铂微电极 ,并用该修饰电极制得了气氧传感器 ,研究了传感器的电化学行为并应用于气氧的测定。实验发现 ,该传感器对氧有很好的催化还原作用 ,对气体氧测定具有很... 本文报道了用电化学聚合方法制备聚四氨基铜酞菁Pt/PolyCuTAPc/Nafion修饰铂微电极 ,并用该修饰电极制得了气氧传感器 ,研究了传感器的电化学行为并应用于气氧的测定。实验发现 ,该传感器对氧有很好的催化还原作用 ,对气体氧测定具有很高的灵敏度、选择性及较好的抗污染能力 ,响应时间小于 5s ,平行测定 7次气氧浓度 ,相对标准偏差为 0 .36 %。 展开更多
关键词 四氨基铜酞菁 修饰电极 气氧测定 浓度
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Experiment study of optimization on prediction index gases of coal spontaneous combustion 被引量:5
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作者 NIU Hui-yong 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第9期2321-2328,共8页
The coal of Anyuan Mine has the characteristic of easy spontaneous combustion. Conventional method is difficult to predict it. Coal samples from this mine were tested in laboratory. The data obtained from laboratory d... The coal of Anyuan Mine has the characteristic of easy spontaneous combustion. Conventional method is difficult to predict it. Coal samples from this mine were tested in laboratory. The data obtained from laboratory determination were initialized for the value which was defined as "K". The ratio of each index gas and value of "K", and the ratio of combination index gases and value of "K", were analyzed simultaneously. The research results show that for this coal mine, if there is carbon monoxide in the gas sample, the phenomenon of oxidation and temperature rising for coal exists in this mine; if there is C_2H_4 in the gas sample, the temperature of coal perhaps exceeds 130 °C. If the coal temperature is between 35 °C and 130 °C, prediction and forecast for coal spontaneous combustion depend on the value of Φ(CO)/K mainly; if the temperature of coal is between 130 °C and 300 °C, prediction and forecast for coal spontaneous combustion depend on the value of Φ(C_2H_6)/Φ(C_2H_2) and Φ(C_2H_6)/K. The research results provide experimental basis for the prediction of coal spontaneous combustion in Anyuan coal mine, and have better guidance on safe production of this coal mine. 展开更多
关键词 COAL spontaneous combustion index gases PREDICTION INITIALIZATION
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