期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
8-羟基喹啉动态有序介孔SiO_2涂层毛细管微萃取与ICP-MS在线联用分析天然水中铝的形态 被引量:3
1
作者 胡文凌 胡斌 郑菲 《分析科学学报》 CAS CSCD 北大核心 2009年第6期621-624,共4页
本文采用溶胶-凝胶方法合成SiO2溶胶,制备了8-羟基喹啉改性的有序介孔SiO2涂层毛细管,建立了毛细管微萃取-电感耦合等离子体质谱(CME—ICP—MS)在线联用技术分析铝形态的新方法。选择游离态铝和Al-柠檬酸络合物为不同铝形态的代表... 本文采用溶胶-凝胶方法合成SiO2溶胶,制备了8-羟基喹啉改性的有序介孔SiO2涂层毛细管,建立了毛细管微萃取-电感耦合等离子体质谱(CME—ICP—MS)在线联用技术分析铝形态的新方法。选择游离态铝和Al-柠檬酸络合物为不同铝形态的代表物,详细探讨了不同实验参数对铝形态分离的影响。结果表明:8-羟基喹啉改性的有序介孔SiO2涂层毛细管在pH为5.0~8.0的范围内可以有效地分离试样中的稳定态单核铝(柠檬酸铝)和非稳定态无机单核铝(游离态铝)。方法的富集倍数为10,检出限为0.34ng·mL^-1。该法应用于湖水、池塘水和长江水中铝的组形态分析,所得结果与8-羟基喹啉负载硅胶微柱分离所得结果吻合很好。 展开更多
关键词 8-羟基喹啉改性有序介SiO2涂层毛细管微萃取 形态分析 ICP—MS
在线阅读 下载PDF
混凝土的内部结构
2
作者 吴科如 《混凝土》 CAS 1981年第1期59-64,共6页
众所周知,材料的性质与其组成物质的成分、所处的环境条件及内部结构密切相关。对于处在相同环境条件下的某一特定材料,其性能主要取决于它的内部结构,此时,内部结构对材料性能的影响,如同物质的分子结构对物质性能的影响一样重要。材... 众所周知,材料的性质与其组成物质的成分、所处的环境条件及内部结构密切相关。对于处在相同环境条件下的某一特定材料,其性能主要取决于它的内部结构,此时,内部结构对材料性能的影响,如同物质的分子结构对物质性能的影响一样重要。材料的内部结构是通过发生于空间及时间的过程形成的,它可以借助各种工艺措施加以控制。因此,如果掌握了材料内部结构的形成过程及其性能的内在关系,就可以通过控制材料内部结构的形成,来获得指定性能的材料。这正是材料科学的根本任务。混凝土是将胶凝材料、水和粗。 展开更多
关键词 水泥浆体 集料 蒸发水 水灰比 骨料 水泥凝胶 无机非金属材料 混凝土 毛细管孔 内部结构
在线阅读 下载PDF
Influence of subsequent curing on water sorptivity and pore structure of steam-cured concrete 被引量:6
3
作者 贺智敏 龙广成 谢友均 《Journal of Central South University》 SCIE EI CAS 2012年第4期1155-1162,共8页
Steam-cured condition is found to cause larger porosity and worse properties of concrete compared with normal curing condition. For the sake of seeking effective measurements to eliminate this bad effect of steam-cure... Steam-cured condition is found to cause larger porosity and worse properties of concrete compared with normal curing condition. For the sake of seeking effective measurements to eliminate this bad effect of steam-cured condition on concrete, the water sorptivity and pore structure of steam-cured concretes exposed to different subsequent curing conditions were investigated after steam-curing treatment. The capillary absorption coefficient and porosity of the corresponding concretes were analyzed, and their mechanisms were also discussed. The results indicate that water sorptivity and pore structure of steam-cured concrete are greatly influenced by the curing condition used in subsequent ages. Exposure steam-cured concrete to air condition has an obviously bad effect on its properties and microstructures. Adopting subsequent curing of immersing steam-cured concrete into about 20℃ water after steam curing period can significantly decrease its capillary absorption coefficient and porosity. Steam-cured concrete with 7 d water curing has minimum capillary absorption coefficient and total porosity. Its water sorptivity is decreased by 23% compared with standard curing concrete and the porosity is 9.6% lower. Moreover, the corresponding gradient of water sorptivity and porosity of steam-cured concrete both decrease, thus mictostructure of concrete becomes more homogeneous. 展开更多
关键词 steam-cured concrete water sorptivity pore structure curing condition
在线阅读 下载PDF
Online dynamic measurement of saturation-capillary pressure relation in sandy medium under water level fluctuation 被引量:1
4
作者 李雁 周劲风 +1 位作者 徐军 KAMON M 《Journal of Central South University》 SCIE EI CAS 2010年第1期85-92,共8页
An online dynamic method based on electrical conductivity probe, tensiometer and datataker was presented to measure saturation-capillary pressure (S-p) relation in water-light nonaqueous phase liquid (LNAPL) two-p... An online dynamic method based on electrical conductivity probe, tensiometer and datataker was presented to measure saturation-capillary pressure (S-p) relation in water-light nonaqueous phase liquid (LNAPL) two-phase sandy medium under water level fluctuation. Three-electrode electrical conductivity probe (ECP) was used to measure water saturation. Hydrophobic tensiometer was obtained by spraying waterproof material to the ceramic cup of commercially available hydrophilic tensiometer. A couple of hydrophilic tensiometer and hydrophobic tensiometer were used to measure pore water pressure and pore LNAPL pressure of the sandy medium, respectively. All the signals from ECP and tensiometer were collected by a data taker connected with a computer. The results show that this method can finish the measurement of S-R relation of a complete drainage or imbibition process in less than 60 min. It is much more timesaving compared with 10-40 d of traditional methods. Two cycles of water level fluctuation were produced, and four saturation-capillary pressure relations including two stable residual LNAPL saturations of the sandy medium were obtained during in 350 h. The results show that this method has a good durable performance and feasibility in the porous medium with complicated multiphase flow. Although further studies are needed on the signal stability and accuracy drift of the ECP, this online dynamic method can be used successfully in the rapid characterization of a LNAPL migration in porous media. 展开更多
关键词 water level fluctuation saturation-capillary pressure (S-p) relation online dynamic measurement
在线阅读 下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部