An ordered array of Ni submicrotubes with up to 35 ìm in length has been successfully prepared by electrodeposition in the pores of alumina membrane modified with methyl-?-diethylenetriaminopropyl-dimethoxysilane...An ordered array of Ni submicrotubes with up to 35 ìm in length has been successfully prepared by electrodeposition in the pores of alumina membrane modified with methyl-?-diethylenetriaminopropyl-dimethoxysilane as pore-wall-modifying agent. Furthermore, using the array of Ni submicrotubes with an alumina membrane support as a "second-order-template", the concentric composite structure of Co wires filling Ni submicrotubes was prepared by electrodeposition method. Magnetization measurements on the array of the Ni submicrotubes and the concentric composite structure of Co wires filling Ni submicrotubes revealed different uniaxial magnetic anisotropy.展开更多
The monodisperse silica particles self-assembled colloidal crystals were used as templates to synthesize pH value and temperature responsive ordered macorporous hydrogels. The ordered structure arranged by the uniform...The monodisperse silica particles self-assembled colloidal crystals were used as templates to synthesize pH value and temperature responsive ordered macorporous hydrogels. The ordered structure arranged by the uniform pores and the pore-pore interconnectivity through the window channel is confirmed by SEM characterization. UV-Vis-near IR absorption experiment result reveals that the wavelength at the stop band peak is tunable within the whole visible spectrum via simply altering some parameters such as pH value and light incidence angle. This finding allows to design frequency-tunable photonic band gap materials.展开更多
A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecan...A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecane and decatungstate polyanions.HR-TEM image ahowded that the decatungstate polyanions"packed"around the l,10-diaminodecane moledules.XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown).Atdlplate mechanosm was pro-posed to explain its formation prodess.It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework.the cationic diaminodecane molecules "bond"decatungstate polyanions on esch end via supermolecular interation and thus form bolarform struc-ture units.These units pack together and ahexagonal phasa is constructed.展开更多
文摘An ordered array of Ni submicrotubes with up to 35 ìm in length has been successfully prepared by electrodeposition in the pores of alumina membrane modified with methyl-?-diethylenetriaminopropyl-dimethoxysilane as pore-wall-modifying agent. Furthermore, using the array of Ni submicrotubes with an alumina membrane support as a "second-order-template", the concentric composite structure of Co wires filling Ni submicrotubes was prepared by electrodeposition method. Magnetization measurements on the array of the Ni submicrotubes and the concentric composite structure of Co wires filling Ni submicrotubes revealed different uniaxial magnetic anisotropy.
文摘The monodisperse silica particles self-assembled colloidal crystals were used as templates to synthesize pH value and temperature responsive ordered macorporous hydrogels. The ordered structure arranged by the uniform pores and the pore-pore interconnectivity through the window channel is confirmed by SEM characterization. UV-Vis-near IR absorption experiment result reveals that the wavelength at the stop band peak is tunable within the whole visible spectrum via simply altering some parameters such as pH value and light incidence angle. This finding allows to design frequency-tunable photonic band gap materials.
文摘A novel Microporous decatungstate was synthesized by using cationic l,10-diaminode-cane as template under mile chemical donditions,This material was construdted from hoghly ordered hexahonal array of 1,10-diaminodecane and decatungstate polyanions.HR-TEM image ahowded that the decatungstate polyanions"packed"around the l,10-diaminodecane moledules.XRD pattern confirmed its hexagonal array(a=b=1.718nm,cunaknown).Atdlplate mechanosm was pro-posed to explain its formation prodess.It is evidenced that l,10-diaminodecane molecules play a crucial role in templating the inorganic framework.the cationic diaminodecane molecules "bond"decatungstate polyanions on esch end via supermolecular interation and thus form bolarform struc-ture units.These units pack together and ahexagonal phasa is constructed.
