The mechanism of leaching chalcopyrite by Acidithiobacillus ferrooxidans (,4. ferrooxidans) in agar-simulated extracellular polymeric substances (EPS) media was investigated. The results indicate that bacterial EP...The mechanism of leaching chalcopyrite by Acidithiobacillus ferrooxidans (,4. ferrooxidans) in agar-simulated extracellular polymeric substances (EPS) media was investigated. The results indicate that bacterial EPS can release H+ and concentrate Fe3+; Fe2+ is movable between agar-simulated EPS phase and bulk solution phase, but it is difficult for Fe3+ to move due to its hydroxylation and EPS complex action; A. ferrooxidans first prefer Fe2+ as energy to metabolize compared with chalcopyrite, and a suitable simulated EPS environment for bacterial living is at about pH 1.8; the iron precipitates and jarosites formed by a lot of biologically oxidized Fe3 cover the simulated EPS easily and form an impermeable deposit acting as a limited barrier of ion transport that attenuates the aggressiveness of the bioleaching attack. The EPS layer blocked by iron precipitates or jarosites is responsible for the chalcopyrite passivation.展开更多
Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local o...Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local or global uncertainty by honouring spatial correlation structures.The sequential Gaussian conditional simulation was used to assess uncertainty of grade estimates and illustrate simulated models in Sivas gold deposit,Turkey.In situ variability and risk quantification of the gold grade were assessed by probabilistic approach based on the sequential Gaussian simulations to yield a series of conditional maps characterized by equally probable spatial distribution of the gold grade for the study area.The simulation results were validated by a number of tests such as descriptive statistics,histogram,variogram and contour map reproductions.The case study demonstrates the efficiency of the method in assessing risk associated with geological and engineering variable such as the gold grade variability and distribution.The simulated models can be incorporated into exploration,exploitation and scheduling of the gold deposit.展开更多
基金Project(2010CB630900) supported by the National Basic Research Program of ChinaProject(50621063) supported by the National Nature Science Foundation of China
文摘The mechanism of leaching chalcopyrite by Acidithiobacillus ferrooxidans (,4. ferrooxidans) in agar-simulated extracellular polymeric substances (EPS) media was investigated. The results indicate that bacterial EPS can release H+ and concentrate Fe3+; Fe2+ is movable between agar-simulated EPS phase and bulk solution phase, but it is difficult for Fe3+ to move due to its hydroxylation and EPS complex action; A. ferrooxidans first prefer Fe2+ as energy to metabolize compared with chalcopyrite, and a suitable simulated EPS environment for bacterial living is at about pH 1.8; the iron precipitates and jarosites formed by a lot of biologically oxidized Fe3 cover the simulated EPS easily and form an impermeable deposit acting as a limited barrier of ion transport that attenuates the aggressiveness of the bioleaching attack. The EPS layer blocked by iron precipitates or jarosites is responsible for the chalcopyrite passivation.
文摘Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local or global uncertainty by honouring spatial correlation structures.The sequential Gaussian conditional simulation was used to assess uncertainty of grade estimates and illustrate simulated models in Sivas gold deposit,Turkey.In situ variability and risk quantification of the gold grade were assessed by probabilistic approach based on the sequential Gaussian simulations to yield a series of conditional maps characterized by equally probable spatial distribution of the gold grade for the study area.The simulation results were validated by a number of tests such as descriptive statistics,histogram,variogram and contour map reproductions.The case study demonstrates the efficiency of the method in assessing risk associated with geological and engineering variable such as the gold grade variability and distribution.The simulated models can be incorporated into exploration,exploitation and scheduling of the gold deposit.