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用能量转移探测萘-蒽二元分子体系的构象变化
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作者 江华 许慧君 《物理化学学报》 SCIE CAS CSCD 北大核心 2001年第12期1092-1096,共5页
合成了一个带有末端取代的能量给体-萘和能量受体-蒽的开链冠醚(DSA).吸收光谱表明两个发色团之间在基态时没有相互作用 选择性激发萘观察到萘的荧光强度下降,同时伴随着蒽的发射增强,表明发生了从萘至蒽的单重态-单重态能... 合成了一个带有末端取代的能量给体-萘和能量受体-蒽的开链冠醚(DSA).吸收光谱表明两个发色团之间在基态时没有相互作用 选择性激发萘观察到萘的荧光强度下降,同时伴随着蒽的发射增强,表明发生了从萘至蒽的单重态-单重态能量转移.能量转移效率受溶剂极性的影响.可以认为在极性小的溶剂如苯中-OCH2CH2O-单元中的中心C—C键主要以反式存在,而在极性大的溶剂如乙腈中则以邻交叉式为主.因此,开链冠醚末端取代的萘和蒽之间的距离随着溶剂极性的增大,能量转移效率却随之降低.表明能量转移可以用于探测以柔性配体键连接的给体-受体体系在不同极性溶剂中的构象变化特性. 展开更多
关键词 能量转移 构变变化 溶剂 开链冠醚 极性 二元分子体系 聚乙二醇
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Mechanism of microwave assisted suspension magnetization roasting of oolitic hematite ore 被引量:8
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作者 ZHOU Wen-tao SUN Yong-sheng +2 位作者 HAN Yue-xin GAO Peng LI Yan-jun 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第2期420-432,共13页
Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roa... Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roasting technology was proposed to recover and utilize the ore.The results showed that under the conditions of microwave pretreatment temperature of 1050℃ for 2 min,a magnetic concentrate with an iron grade of 58.72%at a recovery of 89.32%was obtained by microwave suspension magnetization roasting and magnetic separation.Moreover,compared with the no microwave pretreatment case,the iron grade and recovery increased by 3.17%and 1.58%,respectively.Microwave pretreatment increased the saturation magnetization of the roasted products from 24.974 to 39.236(A∙m^(2))/kg and the saturation susceptibility from 0.179×10^(−3) m^(3)/kg to 0.283×10^(−3) m^(3)/kg.Microcracks were formed between the iron and gangue minerals,and they gradually extended to the core of oolite with the increase in the pretreatment time.The reducing gas diffused from outside to inside along the microcracks,which promoted the selective transformation of the weak magnetic hematite into the strong magnetic magnetite. 展开更多
关键词 oolitic hematite MICROWAVE suspension magnetization roasting phase and magnetic transformation microstructure evolution
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Effect of volume changes on complete deformation behavior of rocks
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作者 赵衡 曹文贵 +1 位作者 李翔 张玲 《Journal of Central South University》 SCIE EI CAS 2010年第2期394-399,共6页
For the purpose of describing the deformation characteristics of rocks,the effect of volume changes on mechanical properties of rocks should be taken into account with relation to the development of constitutive model... For the purpose of describing the deformation characteristics of rocks,the effect of volume changes on mechanical properties of rocks should be taken into account with relation to the development of constitutive model.Firstly,rocks are divided into three parts,i.e.,voids,a damaged part and an undamaged part in the course of loading.The void ratio was applied to describing the changes of voids or pores during the deformation process.Then,using statistical damage theory,a constitutive model was developed for rocks to describe their strain softening and hardening on the basis of investigating the relationship between the net stress and apparent stress,in which the influence of volume changes on rock behavior was correctly taken into account,such as the initial phase of compaction and the latter stage of dilation.Thirdly,a method of determining model parameters was also presented.Finally,this model was used to compare the theoretical results with those observed from experiments under conventional triaxial loading conditions. 展开更多
关键词 rock mechanics constitutive model statistical damage theory volume change void ratio
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