司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法...司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法对司家营BIF的成矿物质来源和形成背景提出了有效制约,同时对司家营BIF的锆石U-Pb年龄数据进行补充。锆石U-Pb年代学显示,司家营BIF形成于2537~2531 Ma。地球化学数据显示司家营BIF矿石主要由TFe_(2)O_(3)和SiO_(2)组成,具有较低的Al_(2)O_(3)和TiO_(2)含量,富集Fe重同位素(δ^(56)Fe=0.341‰~0.525‰);稀土元素配分模式呈现轻稀土亏损、重稀土富集的特征,具有明显的Eu、Y、La正异常,Y/Ho值较高(Y/Ho=34.96~45.84)。这些特征表明司家营BIF是基本无碎屑物质参与的化学沉积岩,稀土元素来源于高温热液和海水的混合溶液,铁质来源于海相热液流体。司家营BIF缺乏真正的Ce负异常和Fe同位素组成均为正值指示其形成于缺氧环境。综合对比世界上其他地区太古宙BIF的Fe同位素特征,笔者等认为新太古代时期地球海洋含氧量逐步上升,此时海洋总体属于缺氧环境,但部分地区氧气含量较高。展开更多
A serics of simulating experiments on the mechanism of formation of banded ironsilica formations have been made using a suite of self-designed glasswares to model the hypergene circulation of surface water.The simulat...A serics of simulating experiments on the mechanism of formation of banded ironsilica formations have been made using a suite of self-designed glasswares to model the hypergene circulation of surface water.The simulating process involved two stages;In the first stage weathering-leaching of basalts by strongly acidic meteoric water formed in the volcanic period of early Proeambrian,resulting in amorphous silica precipitates and strongly acidic ore solutions(pH,1.25),and in the second stage weathering-leaching of basalts by rainwater satupated with CO2 gas free fromcontamination of volcanie gases in the intermission of volcanic activity.Under such conditions the pH value of the seawater would increase.When the pH value rose to 1.25-3.00,ferric hydroxide and amorphous silica would be alternatively precipitated due to periodic heating of the upper solutions and continueous addition of pH-high basalt leaching solutions.This is a possible explanation for the mechanism of formation of banded iron-silica formations.展开更多
文摘司家营条带状含铁建造(Banded iron formation,BIF)型铁矿床是冀东地区规模最大的铁矿床,前人对其进行了大量的年代学、岩石学和元素地球化学工作,但目前尚未对其进行Fe同位素研究。笔者等通过Fe同位素和主微量、稀土元素相结合的方法对司家营BIF的成矿物质来源和形成背景提出了有效制约,同时对司家营BIF的锆石U-Pb年龄数据进行补充。锆石U-Pb年代学显示,司家营BIF形成于2537~2531 Ma。地球化学数据显示司家营BIF矿石主要由TFe_(2)O_(3)和SiO_(2)组成,具有较低的Al_(2)O_(3)和TiO_(2)含量,富集Fe重同位素(δ^(56)Fe=0.341‰~0.525‰);稀土元素配分模式呈现轻稀土亏损、重稀土富集的特征,具有明显的Eu、Y、La正异常,Y/Ho值较高(Y/Ho=34.96~45.84)。这些特征表明司家营BIF是基本无碎屑物质参与的化学沉积岩,稀土元素来源于高温热液和海水的混合溶液,铁质来源于海相热液流体。司家营BIF缺乏真正的Ce负异常和Fe同位素组成均为正值指示其形成于缺氧环境。综合对比世界上其他地区太古宙BIF的Fe同位素特征,笔者等认为新太古代时期地球海洋含氧量逐步上升,此时海洋总体属于缺氧环境,但部分地区氧气含量较高。
文摘A serics of simulating experiments on the mechanism of formation of banded ironsilica formations have been made using a suite of self-designed glasswares to model the hypergene circulation of surface water.The simulating process involved two stages;In the first stage weathering-leaching of basalts by strongly acidic meteoric water formed in the volcanic period of early Proeambrian,resulting in amorphous silica precipitates and strongly acidic ore solutions(pH,1.25),and in the second stage weathering-leaching of basalts by rainwater satupated with CO2 gas free fromcontamination of volcanie gases in the intermission of volcanic activity.Under such conditions the pH value of the seawater would increase.When the pH value rose to 1.25-3.00,ferric hydroxide and amorphous silica would be alternatively precipitated due to periodic heating of the upper solutions and continueous addition of pH-high basalt leaching solutions.This is a possible explanation for the mechanism of formation of banded iron-silica formations.
