Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may ...Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may exacerbate these limitations.To address these issues,this study introduced a novel cement-stabilized permeable recycled aggregate material.A total of 162 beam specimens prepared with nine different levels of cement-aggregate ratio were tested to evaluate their permeability,bending load,and bending fatigue life.The experimental results indicate that increasing the content of recycled aggregates led to a reduction in both permeability and bending load.Additionally,the inclusion of recycled aggregates diminished the energy dissipation capacity of the specimens.These findings were used to establish a robust relationship between the initial damage in cement-stabilized permeable recycled aggregate material specimens and their fatigue life,and to propose a predictive model for their fatigue performance.Further,a method for assessing fatigue damage based on the evolution of fatigue-induced strain and energy dissipation was developed.The findings of this study provide valuable insights into the mechanical behavior and fatigue performance of cement-stabilized permeable recycled aggregate materials,offering guidance for the design of low-carbon-emission,permeable,and durable roadways incorporating recycled aggregates.展开更多
The mechanism of stability of Co-doped spinel λ-MnO_2 that is referred to as spinel Li_xMn_2O_4 (x=0) was studied by using the first-principle calculation method. The total energy and formation enthalpy can be decrea...The mechanism of stability of Co-doped spinel λ-MnO_2 that is referred to as spinel Li_xMn_2O_4 (x=0) was studied by using the first-principle calculation method. The total energy and formation enthalpy can be decreased remarkably due to the Co substation, resulting in a more stable structure of λ-Mn_xCr_(2-x)O_4. The bond order and DOS analysis were given in detail to explain the nature of stability improvement. The calculated results show that as the content of Co dopant increases, the bond order of Mn—O becomes larger and the peak of density of states around Fermi level shifts toward lower energy. The charge density distribution illustrates that the Mn—O bonding is ionic and partially covalent, and the covalent Mn-O bonding becomes stronger with the increase of Co dopant content. The results confirm that the Codoping will enhance the stability of λ-MnO_2 and hence improve the electrochemistry performance of Li_xMn_2O_4.展开更多
The reinforcement and stabilization of loess soil are duscussed by using fibers as the reinforcement and cement as the stabilization materials.To study the strength characteristics of loess soil reinforced by modified...The reinforcement and stabilization of loess soil are duscussed by using fibers as the reinforcement and cement as the stabilization materials.To study the strength characteristics of loess soil reinforced by modified polypropylene(MPP) fiber and cement,samples were prepared with six different fiber contents,three different cement contents,three different curing periods and three kinds of fiber length.The samples were tested under submergence and non-submergence conditions for the unconfined compressive strength(UCS),the splitting tensile strength and the compressive resilient modulus.The results indicated that combined reinforcement by PP fiber and cement could significantly improve the early strength of loess to 3.65–5.99 MPa in three days.With an increase in cement content,the specimens exhibited brittle fracture.However,the addition of fibers gradually modified the mode of fracture from brittle to ductile to plastic.The optimal dosage of fiber to reinforce loess was in the range of 0.3%–0.45% and the optimum fiber length was 12 mm,for which the unconfined compressive strength and tensile strength reached their maxima.Based on the analysis of failure properties,cement-reinforced loess specimens were susceptible to brittle damage under pressure,and the effect of modified polypropylene fiber as the connecting "bridge" could help the specimens achieve a satisfactory level of ductility when under pressure.展开更多
A novel technology of in-situ coating Al2O3 on the surface of H4TiO4 was developed to prevent the aggregation of nano-TiO2 powders and improve the dispersibility and thermal stability in the way of forming a uniform c...A novel technology of in-situ coating Al2O3 on the surface of H4TiO4 was developed to prevent the aggregation of nano-TiO2 powders and improve the dispersibility and thermal stability in the way of forming a uniform coating layer. The heterogeneous nucleation was conducted to prepare the precursor of nano-TiO2 and then Al2O3 was coated on the surface of precursor. The effects of Al2O3 in-situ coating on the properties of nano-TiO2 were investigated. The results show that H4 TiO4 can be dispersed well under alkaline condition （pH 8. 5） and the heterogeneous nucleation can be controlled easily. The optimized uniform coating layer is obtained by adding 5 % （mass fraction ） and 10% of Al2O3 and the aggregation of nano-TiO2 powders is effectively inhibited and the dispersibility is obviously improved. The crystal sizes of TiO2 powders are 12.3, 11.4 and 8. 7 nm after coating 0, 5% and 10% of Al2O3 respectively. Al2O3 on the surface of particulates in amorphous phase could increase the thermal stability of nano-partieles after calcined at 550℃.展开更多
Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electro...Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electrochemical properties of the composites were investigated. The samples were characterized by thermogravimetry and differential thermal analysis （TG/DTA）, X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, cyclic voltammetry （CV）, electrochemical impedance spectroscopy （EIS） and charge/discharge measurements. With increasing the graphite content, the reversible capacity of the Co3O4/graphite composites decreases, while cycling stability improves dramatically, and the addition of graphite obviously decreases the average potential of lithium intercalation/deintercalation. The reversible capacity of the composites with 50% graphite rises from 583 to 725 mA-h/g as the calcination temperature increases from 300 to 500 ℃, and the Co304/graphite composites synthesized at 400 ℃ show the best cycling stability without capacity loss in the initial 20 cycles. peaks, corresponding to the lithium intercalaction/deintercalation for The CV profile of the composite presents two couples of redox graphite and Co3O4, respectively. EIS studies indicate that the electrochemical impedance decreases with increasing the graphite content.展开更多
针对液压支架在井下承受冲击、腐蚀等恶劣环境条件,造成塑性变形、疲劳、立柱失效的问题,对液压支架关键元部件材料进行性能分析,提出材料质量一致性、机械及抗腐蚀性能,以及加工工艺对液压支架可靠性和寿命的影响;通过TMCP(Thermo-Mech...针对液压支架在井下承受冲击、腐蚀等恶劣环境条件,造成塑性变形、疲劳、立柱失效的问题,对液压支架关键元部件材料进行性能分析,提出材料质量一致性、机械及抗腐蚀性能,以及加工工艺对液压支架可靠性和寿命的影响;通过TMCP(Thermo-Mechanical Control Process)技术提升材料质量稳定性,采用激光熔覆和不锈钢包覆技术提高立柱表面耐腐蚀性,采用刮削滚光工艺提高零件加工精度和效率。材料性能及加工工艺的升级将有效提升产品品质,大幅提高我国装备制造水平,提升产品的市场竞争力。展开更多
基金Project(2024JJ2073)supported by the Science Fund for Distinguished Young Scholars of Hunan Province,ChinaProjects(2023YFC3807205,2019YFC1904704)+4 种基金supported by the National Key R&D Program of ChinaProject(52178443)supported by the National Natural Science Foundation of ChinaProject(2024ZZTS0109)supported by Fundamental Research Funds for the Central Universities of Central South University,China。
文摘Permeable roads generally exhibit inferior mechanical properties and shorter service life than traditional dense-graded/impermeable roads.Furthermore,the incorporation of recycled aggregates in their construction may exacerbate these limitations.To address these issues,this study introduced a novel cement-stabilized permeable recycled aggregate material.A total of 162 beam specimens prepared with nine different levels of cement-aggregate ratio were tested to evaluate their permeability,bending load,and bending fatigue life.The experimental results indicate that increasing the content of recycled aggregates led to a reduction in both permeability and bending load.Additionally,the inclusion of recycled aggregates diminished the energy dissipation capacity of the specimens.These findings were used to establish a robust relationship between the initial damage in cement-stabilized permeable recycled aggregate material specimens and their fatigue life,and to propose a predictive model for their fatigue performance.Further,a method for assessing fatigue damage based on the evolution of fatigue-induced strain and energy dissipation was developed.The findings of this study provide valuable insights into the mechanical behavior and fatigue performance of cement-stabilized permeable recycled aggregate materials,offering guidance for the design of low-carbon-emission,permeable,and durable roadways incorporating recycled aggregates.
基金Project(20376086) supported by National Natural Science Foundation of China
文摘The mechanism of stability of Co-doped spinel λ-MnO_2 that is referred to as spinel Li_xMn_2O_4 (x=0) was studied by using the first-principle calculation method. The total energy and formation enthalpy can be decreased remarkably due to the Co substation, resulting in a more stable structure of λ-Mn_xCr_(2-x)O_4. The bond order and DOS analysis were given in detail to explain the nature of stability improvement. The calculated results show that as the content of Co dopant increases, the bond order of Mn—O becomes larger and the peak of density of states around Fermi level shifts toward lower energy. The charge density distribution illustrates that the Mn—O bonding is ionic and partially covalent, and the covalent Mn-O bonding becomes stronger with the increase of Co dopant content. The results confirm that the Codoping will enhance the stability of λ-MnO_2 and hence improve the electrochemistry performance of Li_xMn_2O_4.
基金Project(050101)supported by Horizontal Research Foundation of PLA Air Force Engineering University,ChinaProject(51478462)supported by the National Natural Science Foundation of China
文摘The reinforcement and stabilization of loess soil are duscussed by using fibers as the reinforcement and cement as the stabilization materials.To study the strength characteristics of loess soil reinforced by modified polypropylene(MPP) fiber and cement,samples were prepared with six different fiber contents,three different cement contents,three different curing periods and three kinds of fiber length.The samples were tested under submergence and non-submergence conditions for the unconfined compressive strength(UCS),the splitting tensile strength and the compressive resilient modulus.The results indicated that combined reinforcement by PP fiber and cement could significantly improve the early strength of loess to 3.65–5.99 MPa in three days.With an increase in cement content,the specimens exhibited brittle fracture.However,the addition of fibers gradually modified the mode of fracture from brittle to ductile to plastic.The optimal dosage of fiber to reinforce loess was in the range of 0.3%–0.45% and the optimum fiber length was 12 mm,for which the unconfined compressive strength and tensile strength reached their maxima.Based on the analysis of failure properties,cement-reinforced loess specimens were susceptible to brittle damage under pressure,and the effect of modified polypropylene fiber as the connecting "bridge" could help the specimens achieve a satisfactory level of ductility when under pressure.
文摘A novel technology of in-situ coating Al2O3 on the surface of H4TiO4 was developed to prevent the aggregation of nano-TiO2 powders and improve the dispersibility and thermal stability in the way of forming a uniform coating layer. The heterogeneous nucleation was conducted to prepare the precursor of nano-TiO2 and then Al2O3 was coated on the surface of precursor. The effects of Al2O3 in-situ coating on the properties of nano-TiO2 were investigated. The results show that H4 TiO4 can be dispersed well under alkaline condition （pH 8. 5） and the heterogeneous nucleation can be controlled easily. The optimized uniform coating layer is obtained by adding 5 % （mass fraction ） and 10% of Al2O3 and the aggregation of nano-TiO2 powders is effectively inhibited and the dispersibility is obviously improved. The crystal sizes of TiO2 powders are 12.3, 11.4 and 8. 7 nm after coating 0, 5% and 10% of Al2O3 respectively. Al2O3 on the surface of particulates in amorphous phase could increase the thermal stability of nano-partieles after calcined at 550℃.
基金Project(2007CB613607) supported by the National Basic Research Program of China Projects(2009FJ1002, 2009CK3062) supported by the Science and Technology Program of Hunan Province, China
文摘Co3O4/graphite composites were synthesized by precipitation of cobalt oxalate on the surface of graphite and pyrolysis of the precipitate, and the effects of graphite content and calcination temperature on the electrochemical properties of the composites were investigated. The samples were characterized by thermogravimetry and differential thermal analysis （TG/DTA）, X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, cyclic voltammetry （CV）, electrochemical impedance spectroscopy （EIS） and charge/discharge measurements. With increasing the graphite content, the reversible capacity of the Co3O4/graphite composites decreases, while cycling stability improves dramatically, and the addition of graphite obviously decreases the average potential of lithium intercalation/deintercalation. The reversible capacity of the composites with 50% graphite rises from 583 to 725 mA-h/g as the calcination temperature increases from 300 to 500 ℃, and the Co304/graphite composites synthesized at 400 ℃ show the best cycling stability without capacity loss in the initial 20 cycles. peaks, corresponding to the lithium intercalaction/deintercalation for The CV profile of the composite presents two couples of redox graphite and Co3O4, respectively. EIS studies indicate that the electrochemical impedance decreases with increasing the graphite content.
文摘针对液压支架在井下承受冲击、腐蚀等恶劣环境条件,造成塑性变形、疲劳、立柱失效的问题,对液压支架关键元部件材料进行性能分析,提出材料质量一致性、机械及抗腐蚀性能,以及加工工艺对液压支架可靠性和寿命的影响;通过TMCP(Thermo-Mechanical Control Process)技术提升材料质量稳定性,采用激光熔覆和不锈钢包覆技术提高立柱表面耐腐蚀性,采用刮削滚光工艺提高零件加工精度和效率。材料性能及加工工艺的升级将有效提升产品品质,大幅提高我国装备制造水平,提升产品的市场竞争力。
