期刊文献+
共找到8篇文章
< 1 >
每页显示 20 50 100
机械力化学/晶化法合成纳米水滑石 被引量:5
1
作者 谭琦 印万忠 +1 位作者 刘磊 李小黎 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2012年第4期576-579,587,共5页
以水镁石、Al(OH)3和Na2CO3为原料,采用机械力化学/晶化法合成纳米水滑石,研究了干磨时间、球磨转速和球料质量比对水滑石晶体结构的影响,并采用XRD和FE-SEM等手段对水滑石的晶体结构和表观形貌进行表征.结果表明,干磨时间、球磨转速和... 以水镁石、Al(OH)3和Na2CO3为原料,采用机械力化学/晶化法合成纳米水滑石,研究了干磨时间、球磨转速和球料质量比对水滑石晶体结构的影响,并采用XRD和FE-SEM等手段对水滑石的晶体结构和表观形貌进行表征.结果表明,干磨时间、球磨转速和球料质量比的增加均有利于纳米水滑石的形成,但当超过适宜实验参数,继续增加时就会有杂相生成;在干磨时间为6 h,湿磨时间为2 h,球磨转速为250 r/min,球料质量比为50的条件下得到的纳米水滑石晶型完整单一,具有规则的六边形结构,平均晶粒粒径约为40nm. 展开更多
关键词 水镁石 机械学/ 合成 纳米水滑石 体结构
在线阅读 下载PDF
机械诱发非晶Finemet合金的纳米晶化
2
作者 陆伟 严彪 +1 位作者 杨磊 黄文旵 《同济大学学报(自然科学版)》 EI CAS CSCD 北大核心 2006年第3期393-396,共4页
利用X射线衍射(XRD)研究了高能球磨条件下非晶Fe73.5Cu1NB3Si13.5b9合金的机械诱发纳米晶化过程,并根据化学成分偏聚、局域高压、局域高温以及Johnson-Mehl-Avrami(JMA)晶化动力学模型解释了纳米晶化的过程和机制.研究结果表明:非晶Fe73... 利用X射线衍射(XRD)研究了高能球磨条件下非晶Fe73.5Cu1NB3Si13.5b9合金的机械诱发纳米晶化过程,并根据化学成分偏聚、局域高压、局域高温以及Johnson-Mehl-Avrami(JMA)晶化动力学模型解释了纳米晶化的过程和机制.研究结果表明:非晶Fe73.5Cu1Nb3Si13.5B9合金机械诱发纳米晶化的产物为复杂的α-Fe固溶体和稳定的Fe2B金属间化合物,α-Fe固溶体相晶粒尺寸为2.0-6.5nm,其纳米晶化过程和晶化产物是由化学成分富集、碰撞引起的局域高压和局域高温共同作用的结果;机械诱发纳米晶化过程中的Avrami指数n=1.59,动力学反应速率常数k=0.1287h^-1,表明机械诱发纳米晶化过程中形核机制为均匀形核,晶粒生长机制为从小尺寸晶核开始的三维生长. 展开更多
关键词 Finemet合金 机械诱发 纳米 动力学
在线阅读 下载PDF
高能球磨处理非晶合金Fe_(78)Si_9B_(13)的晶化特点 被引量:1
3
作者 晁月盛 窦志坚 +2 位作者 耿岩 董心权 程力智 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 1998年第5期551-553,共3页
对非晶合金进行了高能振动球磨处理,用穆斯堡尔谱学结合X光衍射等技术研究了球磨后试样的晶化结构.结果表明,经一定时间球磨,试样发生了晶化,析出基体金属相αFe(Si),但其对应的超精细磁场值相对较低.
关键词 态合金 机械晶化 超精细磁场 球磨
在线阅读 下载PDF
高能球磨诱发Fe78Si13B9非晶合金纳米晶化的研究 被引量:3
4
作者 严彪 陈伯渠 +1 位作者 陆伟 杨磊 《同济大学学报(自然科学版)》 EI CAS CSCD 北大核心 2008年第5期636-639,共4页
利用X射线衍射和透射电子显微镜研究了高能球磨条件下Fm8Si13B9非晶合金的机械诱发纳米晶化过程中的结构变化和晶化动力学,利用Scherer公式计算了晶化的α—Fe颗粒的平均直径D,在球磨3h之后开始形成α-Fe相晶粒,D为2~10nm.晶化动... 利用X射线衍射和透射电子显微镜研究了高能球磨条件下Fm8Si13B9非晶合金的机械诱发纳米晶化过程中的结构变化和晶化动力学,利用Scherer公式计算了晶化的α—Fe颗粒的平均直径D,在球磨3h之后开始形成α-Fe相晶粒,D为2~10nm.晶化动力学通过X射线衍射数据给出的晶化体积分数来分析.由经典的Johnson-Mehl-Avrami(JMA)模型得到Avrami指数n=1.53,表明机械诱发纳米晶化过程中其形核机制为均匀形核,晶粒生长机制为从小尺寸晶核开始的三维生长. 展开更多
关键词 合金 机械诱发纳米 动力学
在线阅读 下载PDF
Kinetics for static recrystallization after hot working of 0.38C-0.99Cr-0.16Mo steel 被引量:2
5
作者 李雄 张鸿冰 +2 位作者 阮雪榆 罗中华 张艳 《Journal of Central South University of Technology》 2004年第4期353-357,共5页
The restoration mechanisms for static recrystallization of work-hardened austenite were investigated by using double-pass compression tests performed on medium-carbon steel containing chromium and molybdenum. The soft... The restoration mechanisms for static recrystallization of work-hardened austenite were investigated by using double-pass compression tests performed on medium-carbon steel containing chromium and molybdenum. The softening fraction was defined by 2% offset method. The results show that Avrami exponent of about 0.21 is insensitive to deformation temperature, indicating that the action of steel grade should be considered. The time of 50% recrystallization (t0.5) decreases noteworthily with the increase of deformation temperature. Apparent activation energy for static recrystallization of 195 kJ/mol, which is close to that of vanadium microalloyed steel, is obtained by calculating. The increasing trend of the driving force for recrystallization is opposite to that of the deformation temperature, which is attributed to the number of operative slip system increasing as temperature increasing. 展开更多
关键词 hot working STEEL softening fraction RECRYSTALLIZATION restoration mechanism work-hardened
在线阅读 下载PDF
Microstructure and mechanical properties of Al-5.8Mg-Mn-Sc-Zr alloy after annealing treatment 被引量:1
6
作者 陈琴 潘清林 +3 位作者 王迎 张志野 周坚 刘畅 《Journal of Central South University》 SCIE EI CAS 2012年第7期1785-1790,共6页
An A1-5.8Mg-0.4Mn-0.35(Sc+Zr) (mass fraction, %) alloy sheet was prepared using water chilling copper mould ingot metallurgy processing which was protected by active flux. The influence of stabilizing annealing o... An A1-5.8Mg-0.4Mn-0.35(Sc+Zr) (mass fraction, %) alloy sheet was prepared using water chilling copper mould ingot metallurgy processing which was protected by active flux. The influence of stabilizing annealing on mechanical properties and microstructure of the cold rolling sheet was studied. The results show that the strength and hardness of the alloy decrease, while the elongation increases with increasing the stabilizing annealing temperature. With the increase of stabilizing annealing time, the strength and hardness of the alloy drop slightly but its ductility exhibits no change. Partial recovery and recrystallization orderly occur with the increase of annealing temperature during stabilizing treatment. Only different degrees of recovery occur in the alloys annealed below 400 ℃ for 1 h. Partial recrystallization occurs after annealed at 450 ℃ for 1 h. By annealing at 300 ℃ for 1 h, the alloy can obtain the optimum application values of δb, δ0.2 and δ, which are 436 MPa, 327 MPa and 16.7%, respectively. 展开更多
关键词 A1-Mg-Mn-Sc-Zr alloy stabilizing treatment A13(Sc Zr) particle microstructure mechanical property
在线阅读 下载PDF
Structural evolution and stability of mechanically alloyed Fe-Ni nanocrystalline
7
作者 陈资 刘奇正 +1 位作者 孟庆平 戎咏华 《Journal of Central South University of Technology》 EI 2005年第4期389-392,共4页
The structural evolution and stability of Fe100-xNix(x= 10, 20, 35, 50) alloys prepared by mechanical alloying were investigated through X-ray diffraction analysis and transmission electron microscopy. The intrinsic... The structural evolution and stability of Fe100-xNix(x= 10, 20, 35, 50) alloys prepared by mechanical alloying were investigated through X-ray diffraction analysis and transmission electron microscopy. The intrinsic conditions of preparation determining phase stability in nanocrystalline were clarified. After being milled for 120 h, the powders of Fego Ni10 and Fe80 Ni20 consist of a single α(bcc) phase, Fe30 Ni30 powders are a single γ(fcc), and for Fe65 Ni35 powders there is co-existence of α and γ phases. The as-milled Fe80 Ni20 powders annealed at 680℃ exhibits the stability of high-temperature γ phase at room temperature, which is consistent with the theoretical prediction. 展开更多
关键词 mechanical alloying t Fe-Ni nanocrystalline structural evolutiont phase stability martensitic transformation
在线阅读 下载PDF
Effect of Mo on mechanical properties of modified ultrahigh carbon steels after heat-treatment
8
作者 李磊 胡彬 +2 位作者 刘生根 刘华山 郑峰 《Journal of Central South University》 SCIE EI CAS 2014年第5期1683-1688,共6页
Abstract: Microstructure and mechanical properties of modified ultrahigh carbon (1.6%C) steels with different Mo additions (0, 0.3%, 0.5%, and 0.8%, mass fraction) were studied in their as-cast and quenched then ... Abstract: Microstructure and mechanical properties of modified ultrahigh carbon (1.6%C) steels with different Mo additions (0, 0.3%, 0.5%, and 0.8%, mass fraction) were studied in their as-cast and quenched then tempered conditions by optical microscopy, scanning electronic microscopy, X-ray diffraction and hardness and toughness tests, respectively. The results show that the continuous eutectic carbide network structure has been broken down and changed to partial isolated and finer particles embedded in matrix of as-cast alloy by modification. Carbides in both quenched and tempered specimens have been refined effectively after the addition of Mo. Specimen containing 0.5% Mo shows the finest microstructures with carbides dispersed homogeneously in martensite matrix and demonstrates highest impact toughness of 18.4 J/cm2 and hardness of 50 HRC. 展开更多
关键词 ultrahigh carbon steel MOLYBDENUM MICROSTRUCTURE impact toughness HARDNESS
在线阅读 下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部