A novel compound Ni(phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains {V2O6}n2n- chains interconnected by nickel(II) complexes via oxygen...A novel compound Ni(phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains {V2O6}n2n- chains interconnected by nickel(II) complexes via oxygen atoms. The crystallographic data measured by single-crystal X-ray diffraction analysis are as follows: C12H10N2NiO7V2, Mr=454.81, monoclinic, space group P21 / c, a=0.784 6(3), b=2.103 6(8), c=0.942 3(4) nm, β=112.872(5)°, V=1.433 0(10) nm3, Z=4, Dc=2.104 Mg·m-3, μ(Mo Kα)=2.615 mm-1, F(000)=904, T=298(2) K, 4 480 reflections collected, 2 470 independent (Rint=0.032 2), the final R=0.058 4 and wR2=0.145 7 for 2 303 observed reflections with I>2σ(I). CCDC: 192520.展开更多
Organicinorganic hybridbis(diethylammonium)tetrachlorocuprate was synthesized by solid state synthesis at lowheating temperature.Thermochromism and the probability on solid state reactiom of the hybrid were inve...Organicinorganic hybridbis(diethylammonium)tetrachlorocuprate was synthesized by solid state synthesis at lowheating temperature.Thermochromism and the probability on solid state reactiom of the hybrid were investigated by IR,DSC,XRD,and(in situ)UVvisible spectra.Solid state synthesis has much higher yield (908%) than solution method (491%) and almost need not any solvent during reaction process.展开更多
文摘A novel compound Ni(phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensional compound, which contains {V2O6}n2n- chains interconnected by nickel(II) complexes via oxygen atoms. The crystallographic data measured by single-crystal X-ray diffraction analysis are as follows: C12H10N2NiO7V2, Mr=454.81, monoclinic, space group P21 / c, a=0.784 6(3), b=2.103 6(8), c=0.942 3(4) nm, β=112.872(5)°, V=1.433 0(10) nm3, Z=4, Dc=2.104 Mg·m-3, μ(Mo Kα)=2.615 mm-1, F(000)=904, T=298(2) K, 4 480 reflections collected, 2 470 independent (Rint=0.032 2), the final R=0.058 4 and wR2=0.145 7 for 2 303 observed reflections with I>2σ(I). CCDC: 192520.
文摘Organicinorganic hybridbis(diethylammonium)tetrachlorocuprate was synthesized by solid state synthesis at lowheating temperature.Thermochromism and the probability on solid state reactiom of the hybrid were investigated by IR,DSC,XRD,and(in situ)UVvisible spectra.Solid state synthesis has much higher yield (908%) than solution method (491%) and almost need not any solvent during reaction process.
