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催化剂添加量和温度对催化氮化制备低碳MgO-C耐火材料显微结构演变的影响
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作者 陈洋 李增祎 +6 位作者 吴智 邓承继 娄晓明 李勇庆 谭嘉琳 丁军 余超 《材料导报》 北大核心 2025年第8期72-76,共5页
为了探明硝酸铁添加量和氮化温度对催化制备低碳MgO-C耐火材料中陶瓷相形貌演变的影响,以电熔镁砂、鳞片石墨、硅粉、酚醛树脂和硝酸铁为主要原料,通过高温氮化制备低碳MgO-C耐火材料。结果表明:与不添加催化剂的材料(1400℃)相比,硝酸... 为了探明硝酸铁添加量和氮化温度对催化制备低碳MgO-C耐火材料中陶瓷相形貌演变的影响,以电熔镁砂、鳞片石墨、硅粉、酚醛树脂和硝酸铁为主要原料,通过高温氮化制备低碳MgO-C耐火材料。结果表明:与不添加催化剂的材料(1400℃)相比,硝酸铁的添加促进了SiC、β-Si_(3)N_(4)和α-Si_(3)N_(4)新相的生成,晶须状Mg_(2)SiO_(4)消失,Mg_(2)SiO_(4)主要以尺寸更大的片状形貌存在;当硝酸铁添加量为1%时,生成许多大尺寸的片状Mg_(2)SiO_(4)和较多小晶粒尺寸的柱状β-Si_(3)N_(4)。在含3%硝酸铁的材料中,氮化温度由1 400℃升高至1 500℃会导致试样内部产生大量气体而逸出,降低了片状Mg_(2)SiO_(4)和柱状β-Si_(3)N_(4)的生成量,并使Mg_(2)SiO_(4)以尖端带液滴的蠕虫状形貌存在。 展开更多
关键词 低碳MgO-C耐火材料 显微结构演变 陶瓷相 催化氮化
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燃烧合成C/MgAl_(2)O_(4)复合粉及其显微结构演变
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作者 吕李华 丁冬海 肖国庆 《耐火材料》 CAS 北大核心 2021年第5期405-409,共5页
为解决纳米碳在应用过程中难分散、易氧化、成本高等问题,以草酸镁(MgC_(2)O_(4))、过氧化镁、Al_(2)O_(3)粉和Al粉为原料,燃烧合成碳/镁铝尖晶石(C/MgAl_(2)O_(4))复合粉。结果表明,当MgC 2O 4的最大掺量是33.34%(w)时,C/MgAl_(2)O_(4... 为解决纳米碳在应用过程中难分散、易氧化、成本高等问题,以草酸镁(MgC_(2)O_(4))、过氧化镁、Al_(2)O_(3)粉和Al粉为原料,燃烧合成碳/镁铝尖晶石(C/MgAl_(2)O_(4))复合粉。结果表明,当MgC 2O 4的最大掺量是33.34%(w)时,C/MgAl_(2)O_(4)复合粉中碳含量为1.17%(w),碳夹杂于尖晶石晶粒间。复合粉中镁铝尖晶石具有粒状及棒状两种形貌。粒状镁铝尖晶石由MgO与Al_(2)O_(3)相互扩散形成,棒状镁铝尖晶石由Mg蒸气与原料Al_(2)O_(3)以气-固生长机制主导形成。 展开更多
关键词 C/MgAl_(2)O_(4)复合粉 燃烧合成法 燃烧波淬熄技术 显微结构演变
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水氧腐蚀环境对2D C/SiC热扩散性能的作用机制研究
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作者 王芙愿 杨晓辉 +1 位作者 王毅 白龙腾 《火箭推进》 CAS 2017年第4期23-28,共6页
通过对不同温度条件下,水氧腐蚀前后2D C/SiC复合材料热扩散性能的演变规律,研究了环境损伤对C/SiC复合材料热扩散性能的作用机制。在水蒸气和氧气混合环境下,C/SiC复合材料内部气孔率增加,同时在材料表面有氧化物形成。材料内部出现的... 通过对不同温度条件下,水氧腐蚀前后2D C/SiC复合材料热扩散性能的演变规律,研究了环境损伤对C/SiC复合材料热扩散性能的作用机制。在水蒸气和氧气混合环境下,C/SiC复合材料内部气孔率增加,同时在材料表面有氧化物形成。材料内部出现的气孔,阻断了热流在材料内部的传输,使得热扩散性能呈现出直线下降的趋势。氧化物的形成,在一定程度上封填裂纹,有助于热量的传输,能够在一定程度上改善材料热扩散性能。 展开更多
关键词 C/SIC 热扩散 环境腐蚀 显微结构演变
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Influence of minor Sc additions on grain refinement and microstructure characteristics of a high Zn-containing Al-Zn-Mg-Cu-Zr alloy 被引量:4
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作者 WEN Kai LI Xi-wu +5 位作者 XIONG Bai-qing LIU Hong-lei WANG Ying-jun LI Zhi-hui ZHANG Yong-an LI Ya-nan 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第3期780-794,共15页
In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cas... In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed. 展开更多
关键词 Al-Zn-Mg-Cu-Zr alloy high zinc content microstructure Sc addition grain refinement phase evolution
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Deformation behavior and microstructural evolution of Al-Zn-Cu-Mg-Sc-Zr alloy during high temperature compression 被引量:2
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作者 李文斌 潘清林 +3 位作者 刘俊生 梁文杰 何运斌 刘晓艳 《Journal of Central South University》 SCIE EI CAS 2009年第4期530-534,共5页
The deformation behavior of a new Al-Zn-Cu-Mg-Sc-Zr alloy was investigated with compression tests in temperature range of 380?470 ℃ and strain rate range of 0.001-10 s-1 using Gleeble 1500 system, and the associated ... The deformation behavior of a new Al-Zn-Cu-Mg-Sc-Zr alloy was investigated with compression tests in temperature range of 380?470 ℃ and strain rate range of 0.001-10 s-1 using Gleeble 1500 system, and the associated microstructural evolutions were studied by metallographic microscopy and transmission electron microscopy. The results show that true stress—strain curves exhibit a peak stress, followed by a dynamic flow softening at low strains (ε<0.05). The stress decreases with increasing deformation temperature and decreasing strain rate, which can be represented by a Zener-Hollomon exponential equation with the activation energy for deformation of 157.9 kJ/mol. The substructure in the deformed specimens consists of few fine precipitates with equaixed polygonized subgrains in the elongated grains and developed serrations at the grain boundaries. The dynamic flow softening is attributed mainly to dynamic recovery and dynamic recrystallization. 展开更多
关键词 Al-Zn-Cu-Mg-Sc-Zr alloy hot deformation flow softening microstructural evolution activation energy
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