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波长色散X射线荧光光谱法分析铝箔中9种元素 被引量:2
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作者 薛秋红 丁仕兵 陶琳 《理化检验(化学分册)》 CAS CSCD 北大核心 2015年第1期114-116,共3页
铝及铝合金中化学成分的测定常用滴定法、分光光度法、原子吸收光谱法[1]、电感耦合等离子体原子发射光谱法(ICP-AES)[2-4]和电感耦合等离子体质谱法(ICP-MS)[5]等方法,这些分析方法准确度高,但样品前处理过程繁琐。对于固体金属材料,... 铝及铝合金中化学成分的测定常用滴定法、分光光度法、原子吸收光谱法[1]、电感耦合等离子体原子发射光谱法(ICP-AES)[2-4]和电感耦合等离子体质谱法(ICP-MS)[5]等方法,这些分析方法准确度高,但样品前处理过程繁琐。对于固体金属材料,若侧重考虑分析速度因素的影响,首选的是火花源原子发射光谱法[6-8],但直接使用火花源原子发射光谱对厚度从0.005~0. 展开更多
关键词 原子发射光谱法 波长色散 原子吸收光谱法 金属材料 分光光度法 荧光光谱法 化学成分 仪器工作条件 铝及铝合金 方法准确度
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离子色谱法测定大气中硫酸盐转化速率的研究 被引量:2
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作者 郭银玉 潘伟林 朱文荣 《中国环境监测》 CAS CSSCI CSCD 北大核心 1989年第4期41-43,共3页
本文研究了经碳酸钾溶液浸渍过玻璃纤维膜曝露于大气中使气态硫化合物,如SO_2转化为硫酸盐,采用离子色谱法测定。通过对本方法准确度及精密度检验、回收率在96.2%~99.9%之间变异系数1.29%,证实本方法准确稳定,并具有检出限低、快速... 本文研究了经碳酸钾溶液浸渍过玻璃纤维膜曝露于大气中使气态硫化合物,如SO_2转化为硫酸盐,采用离子色谱法测定。通过对本方法准确度及精密度检验、回收率在96.2%~99.9%之间变异系数1.29%,证实本方法准确稳定,并具有检出限低、快速、简便等优点。 展开更多
关键词 离子色谱法 转化速率 玻璃纤维膜 碳酸钾溶液 硫化合物 变异系数 离子色谱仪 测定步骤 淋洗液 方法准确度
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气相色谱法分析恶霉灵 被引量:2
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作者 姜淑秀 《农药科学与管理》 CAS 1989年第4期14-15,共2页
恶霉灵是土壤杀真菌剂和植物生长促进剂。原药和制剂中的有效成分分析采用气相色谱法。选择适宜的溶剂将样品进行溶解或萃取,用填充玻璃柱进行分离,加内标物校正,方法准确度和精密度均符合定量要求。
关键词 定量要求 恶霉灵 植物生长促进剂 气相色谱法分析 内标物 杀真菌剂 方法准确度 刻度离心管 玻璃柱 摇匀
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Comparison of GUF and Monte Carlo methods to evaluate task-specific uncertainty in laser tracker measurement 被引量:1
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作者 杨景照 李国喜 +2 位作者 吴宝中 龚京忠 王杰 《Journal of Central South University》 SCIE EI CAS 2014年第10期3793-3804,共12页
Measurement uncertainty plays an important role in laser tracking measurement analyses. In the present work, the guides to the expression of uncertainty in measurement(GUM) uncertainty framework(GUF) and its supplemen... Measurement uncertainty plays an important role in laser tracking measurement analyses. In the present work, the guides to the expression of uncertainty in measurement(GUM) uncertainty framework(GUF) and its supplement, the Monte Carlo method, were used to estimate the uncertainty of task-specific laser tracker measurements. First, the sources of error in laser tracker measurement were analyzed in detail, including instruments, measuring network fusion, measurement strategies, measurement process factors(such as the operator), measurement environment, and task-specific data processing. Second, the GUM and Monte Carlo methods and their application to laser tracker measurement were presented. Finally, a case study involving the uncertainty estimation of a cylindricity measurement process using the GUF and Monte Carlo methods was illustrated. The expanded uncertainty results(at 95% confidence levels) obtained with the Monte Carlo method are 0.069 mm(least-squares criterion) and 0.062 mm(minimum zone criterion), respectively, while with the GUM uncertainty framework, none but the result of least-squares criterion can be got, which is 0.071 mm. Thus, the GUM uncertainty framework slightly underestimates the overall uncertainty by 10%. The results demonstrate that the two methods have different characteristics in task-specific uncertainty evaluations of laser tracker measurements. The results indicate that the Monte Carlo method is a practical tool for applying the principle of propagation of distributions and does not depend on the assumptions and limitations required by the law of propagation of uncertainties(GUF). These features of the Monte Carlo method reduce the risk of an unreliable measurement of uncertainty estimation, particularly in cases of complicated measurement models, without the need to evaluate partial derivatives. In addition, the impact of sampling strategy and evaluation method on the uncertainty of the measurement results can also be taken into account with Monte Carlo method, which plays a guiding role in measurement planning. 展开更多
关键词 task-specific uncertainty laser tracker measurement uncertainty evaluation Monte Carlo method uncertainy framework(GUF)
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