The control of the clutch engagement for an automatic mechanical transmission in the process of a tracklayer getting to start is studied. The dynamic model of power transmission and automatic clutch system is develope...The control of the clutch engagement for an automatic mechanical transmission in the process of a tracklayer getting to start is studied. The dynamic model of power transmission and automatic clutch system is developed. Using tools of Simulink, the transient characteristics during the vehicle starting, including the jerk and the clutch slip time, are provided here. Based on the analyses of the simulation results and driver’s experiences, a fuzzy controller is designed to control the clutch engagement. Simulation results verify its value.展开更多
The mathematical model of 4He quantum interferometer gyroscope is presented. The model includes the driven equation, the current equation and the position equation. Therefore, it can sufficiently describe the gyro- sc...The mathematical model of 4He quantum interferometer gyroscope is presented. The model includes the driven equation, the current equation and the position equation. Therefore, it can sufficiently describe the gyro- scope system. The driven equation shows the thermally driven gyroscope can work for a long time but the pres- sure driven one cannot. From the current equation, the superfluid currents passing through the weak link contain the AC currents which show the rotation flux, and other currents caused by drive. As shown in the position equa- tion, the displacement of diaphragm is the only detectable parameter in the gyroscope system. The model is tested by the simulations based on experimental parameters, and can be used to research performance of the gyroscope and analyse the gyroscope error.展开更多
To investigate the vibration principle in machining thin-walled components, a dynamic model for end milling of flexible structures is built based on considering the variations in the dynamic chip thickness and the dif...To investigate the vibration principle in machining thin-walled components, a dynamic model for end milling of flexible structures is built based on considering the variations in the dynamic chip thickness and the differences between up-milling and down-milling. Two milling experiments verify the model. Experimental results show that the model can predict the milling force and displacements simultaneously in the dynamic milling process.展开更多
In order to investigate the dynamic behavior of non-conservative systems,the Lie symmetries and conserved quantities of fractional Birkhoffian dynamics based on quasi-fractional dynamics model are proposed and studied...In order to investigate the dynamic behavior of non-conservative systems,the Lie symmetries and conserved quantities of fractional Birkhoffian dynamics based on quasi-fractional dynamics model are proposed and studied.The quasi-fractional dynamics model here refers to the variational problem based on the definition of RiemannLiouville fractional integral(RLFI),the variational problem based on the definition of extended exponentially fractional integral(EEFI),and the variational problem based on the definition of fractional integral extended by periodic laws(FIEPL).First,the fractional Pfaff-Birkhoff principles based on quasi-fractional dynamics models are established,and the corresponding Birkhoff’s equations and the determining equations of Lie symmetry are obtained.Second,for fractional Birkhoffian systems based on quasi-fractional models,the conditions and forms of conserved quantities are given,and Lie symmetry theorems are proved.The Pfaff-Birkhoff principles,Birkhoff’s equations and Lie symmetry theorems of quasi-fractional Birkhoffian systems and classical Birkhoffian systems are special cases of this article.Finally,some examples are given.展开更多
The South China Sea contains tremendous oil and gas resources in deepwater areas. However, one of the keys for deepwater exploration, the investigation of deepwater floating platforms, is very inadequate. In this pape...The South China Sea contains tremendous oil and gas resources in deepwater areas. However, one of the keys for deepwater exploration, the investigation of deepwater floating platforms, is very inadequate. In this paper, the authors studied and compared the hydrodynamics and global motion behaviors of typical deepwater platforms in the South China Sea environment. The hydrodynamic models of three main types of floating platforms, e.g. the Semi-submersible, tension leg platform （TLP）, and Truss Spar, which could potentially be utilized in the South China Sea, were established by using the 3-D potential theory. Additionally, some important considerations which significantly influence the hydrodynamics were given. The RAOs in frequency domains as well as global motions in time domains under time-varying wind, random waves, and current in 100-y, 10-y, and 1-y return period environment conditions were predicted, compared, and analyzed. The results indicate that the heave and especially the pitch motion of the TLP are favorable. The heave response of the Truss Spar is perfect and comparable with that of the TLP when the peak period of random waves is low. However, the pitch motion of Truss Spar is extraordinarily lar^er than that of Semi-submersible and TLP.展开更多
In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflec...In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflect actual situations and facilitate their computation and analyses.Given the importance of model building, further processing methods about traditional seismic interpretation results from Landmark should be studied and the processed result can then be directly used in numerical simulation computations.Through this data conversion procedure, Landmark and FLAC(the international general stress software) are seamlessly connected.Thus, the format conversion between the two systems and the pre-and post-processing in simulation computation is realized.A practical application indicates that this method has many advantages such as simple operation, high accuracy of the element subdivision and high speed, which may definitely satisfy the actual needs of floor grid cutting.展开更多
This study modeled the effects of structural and dimensional manipulations on hydrodynamic behavior of a bench vertical current classifier. Computational fluid dynamics （CFD） approach was used as modeling method, an...This study modeled the effects of structural and dimensional manipulations on hydrodynamic behavior of a bench vertical current classifier. Computational fluid dynamics （CFD） approach was used as modeling method, and turbulent intensity and fluid velocity were applied as system responses to predict the over- flow cut size variations. These investigations showed that cut size would decrease by increasing diameter and height of the separation column and cone section depth, due to the decrease of turbulent intensity and fluid velocity. As the size of discharge gate increases, the overflow cut-size would decrease due to freely fluid stream out of the column. The overflow cut-size was significantly increased in downward fed classifier compared to that fed by upward fluid stream. In addition, reforming the shape of angular overflow outlet＇s weir into the curved form prevented stream inside returning and consequently unselec- tire cut-size decreasing.展开更多
Given the actual working of a fully mechanized plough at a mining face, we have proposed a formula for running constraints between powered supports and a coal plough under assumed geological conditions of the coal fac...Given the actual working of a fully mechanized plough at a mining face, we have proposed a formula for running constraints between powered supports and a coal plough under assumed geological conditions of the coal face and, on this basis, established an automatic control model of powered supports for the coal plough face. We introduced the working principle of the powered support control system of the plough at the mining face. We established three advanced characteristics of this control system： response speed, reliability and easy maintenance of the system. As well, we briefly introduced, the principal function of primary and subordinate controllers and the realization of the communication system by a Single Bus. Ten controllers were constructed and tested in our laboratorium. The results show that the control model is practical and meets actual conditions. It provides a theoretical basis for designing a comouter control system for a oowered support system of a plough at a mining face.展开更多
In this paper, Noblesse's New Slender-Ship Wave-Making Theory was investigated numerically. Detailed expressions of zeroth and lst order wave resistance have been derived and calculation programs have also been co...In this paper, Noblesse's New Slender-Ship Wave-Making Theory was investigated numerically. Detailed expressions of zeroth and lst order wave resistance have been derived and calculation programs have also been compiled. In the single and double integral terms of Green function, the kernel function of wave resistance expression, special function expansion method and Chebyshev polynomials approach have been adopted respectively, which greatly simplify the calculation and increase the convergence speed.展开更多
An innovative hydrodynamic theory and numerical model were developed to help improve the efficiency, accuracy, and convergence of the numerical prediction of wave drift forces on two side-by-side deepwater floating bo...An innovative hydrodynamic theory and numerical model were developed to help improve the efficiency, accuracy, and convergence of the numerical prediction of wave drift forces on two side-by-side deepwater floating bodies. The wave drift forces were expressed by the double integration of source strength and the corresponding Green function on the body surface, which is consistent with the far field formula based on momentum conservation and sharing the advantage of near field calculations providing the drift force on each body. Numerical results were validated through comparing the general far field model and pressure integral model, as well as the middle field model developed usin^z the software HydroStar.展开更多
A mathematical model based on an electrorheological (ER) shock absorber with the mixed-mode is presented. Its application to the parametric design of an electrorheological fluid shock absorber with the simulation calc...A mathematical model based on an electrorheological (ER) shock absorber with the mixed-mode is presented. Its application to the parametric design of an electrorheological fluid shock absorber with the simulation calculation performed by program MATLAB demonstrates that the model can predict the behavior of ER shock absorbers satisfactorily, shorten the design period of an electrorheological shock absorber, and reduce the cost in the prototype manufacturing. The strength analysis based on a three-dimensional finite element model for the electrorheological shock absorber confirm that the structure design of the ER shock absorber is reasonable, and the stress distribution is uniform.展开更多
This study examines the hydrodynamic performance of multiple-row vertical slotted breakwaters. We developed a mathematical model based on an eigenfunction expansion method and a least squares technique for Stokes seco...This study examines the hydrodynamic performance of multiple-row vertical slotted breakwaters. We developed a mathematical model based on an eigenfunction expansion method and a least squares technique for Stokes second-order waves. The numerical results obtained for limiting cases of double-row and triple-row walls are in good agreement with results of previous studies and experimental results. Comparisons with experimental measurements of the reflection, transmission, and dissipation coefficients （CR, Cr, and CE） for double-row walls show that the proposed mathematical model adequately reproduces most of the important features. We found that for double-row walls, the CR increases with increasing wave number, kd, and with a decreasing permeable wall part, din. The Cr follows the opposite trend. The CE slowly increases with an increasing kd for lower kd values, reaches a maximum, and then decreases again. In addition, an increasing porosity of dm would significantly decrease the CR while increasing the Cr. At lower values of kd, a decreasing porosity increases the CE, but for high values of kd, a decreasing porosity reduces the Ce. The numerical results indicate that, for triple-row walls, the effect of the arrangement of the chamber widths on hydrodynamic characteristics is not significant, except when kd〈0.5 Double-row slotted breakwaters may exhibit a good wave-absorbing performance at kd〉0.5, where by the horizontal wave force may be smaller than that of a single wall. On the other hand, the difference between double-row and triple-row vertical slotted breakwaters is marginal.展开更多
In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides ...In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides in diesel were explored. Through studying the mechanism for oxidation of sulfides and the principle of solvent extraction,the kinetic equation of desulfurization via oxidative extraction were determined. By means of the evaluation of model parameters and curve fitting,the reaction order between organic sulfide and sulfone,the intrinsic oxidation rate constant of organic sulfide and sulfone,and the equilibrium constant between sulfone in model diesel and extractive solvent were determined. The experimental values of the desulfurization rate and the theoretical values of the corresponding model equation had closely demonstrated that the desulfurization reaction rate had high accuracy. And the reaction kinetics could provide an important basis for diesel desulfurization process in the future.展开更多
Oxidation of coke deposited on spent catalytic cracking catalysts was compared with that of coal and coal char via the non-isothermal oxidation means, i.e. the thermal-gravimetric analysis （TGA） and the differential...Oxidation of coke deposited on spent catalytic cracking catalysts was compared with that of coal and coal char via the non-isothermal oxidation means, i.e. the thermal-gravimetric analysis （TGA） and the differential thermal analysis （DTA）. Oxidation kinetic parameters were further investigated by model-fitting methods. The test results showed that the oxidation of spent catalysts was a quite mild process, while coal and coal char experienced sharp weight loss during oxidation. The temperature for commencement and termination of oxidation increased in the following order： coal〈coal char〈spent catalysts, and the oxidation of the three tested materials displayed a self-catalytic nature, with their largest oxidation rate appearing at a weight percent of 24.96%, 34.21% and 57.93%, respectively. The oxidation of spent catalysts obeyed a random nucleation model for the first-order reaction, with Ea=206.13 kJ/mol and lgA=10.10, and the oxidation of coal could be a diffusion-controlled reaction mechanism, with Ea=161.61 kJ/mol and lgA=7.74, while the oxidation of coal char also obeyed a random nucleation model for the first-order reaction, with Ea= 149.36 k J/mol and lgA=7.89.展开更多
Before any rock engineering project,mechanical parameters of rocks such as uniaxial compressive strength and young modulus of intact rock get measured using laboratory or in-situ tests,but in some situations preparing...Before any rock engineering project,mechanical parameters of rocks such as uniaxial compressive strength and young modulus of intact rock get measured using laboratory or in-situ tests,but in some situations preparing the required specimens is impossible.By this time,several models have been established to evaluate UCS and E from rock substantial properties.Artificial neural networks are powerful tools which are employed to establish predictive models and results have shown the priority of this technique compared to classic statistical techniques.In this paper,ANN and multivariate statistical models considering rock textural characteristics have been established to estimate UCS of rock and to validate the responses of the established models,they were compared with laboratory results.For this purpose a data set for 44 samples of sandstone was prepared and for each sample some textural characteristics such as void,mineral content and grain size as well as UCS were determined.To select the best predictors as inputs of the UCS models,this data set was subjected to statistical analyses comprising basic descriptive statistics,bivariate correlation,curve fitting and principal component analyses.Results of such analyses have shown that void,ferroan calcitic cement,argillaceous cement and mica percentage have the most effect on USC.Two predictive models for UCS were developed using these variables by ANN and linear multivariate regression.Results have shown that by using simple textural characteristics such as mineral content,cement type and void,strength of studied sandstone can be estimated with acceptable accuracy.ANN and multivariate statistical UCS models,revealed responses with 0.87 and 0.76 regressions,respectively which proves higher potential of ANN model for predicting UCS compared to classic statistical models.展开更多
By taking the surface chemical reactions as the rate-controlling step, a possible reaction mechanism for ethylene epoxidation to synthesize ethylene oxide over the A-type silver catalyst was developed, while it was as...By taking the surface chemical reactions as the rate-controlling step, a possible reaction mechanism for ethylene epoxidation to synthesize ethylene oxide over the A-type silver catalyst was developed, while it was assumed that the epoxidation reaction would take place between ethylene and the un-dissociated adsorbed oxygen O2 a on the solo active sites, while the deep oxidation would occur between ethylene and the dissociated adsorbed oxygen Oa on the adjacent multi-active sites. In order to describe the effect of 1,2-C2H4Cl2(EDC) inhibitor on the ethylene epoxidation process, the reversible reactions between EDC and vinyl chloride(VC) on the active sites of silver catalyst was introduced. According to the assumed mechanism, the hyperbolic macro-kinetic model of ethylene epoxidation over the A-type silver catalyst was established, and the macrokinetic experiments were carried out in an internal-recycle gradientless reactor operating at a pressure of 2.1 MPa and a temperature in the range of 217.8—249.0 ℃, with the gas composition(molar fraction) consisting of 15.82%—34.65% C2H4, 2.55%—7.80% O2, 0.88%—6.15% CO2, 0.15—2.61 μmol/mol of 1,2-C2H4Cl2 and 0.14—1.28 μmol/mol of C2H3 Cl. By means of the Simplex Optimal Method, the parameters of the macrokinetic models were estimated. Statistical test showed that the macrokinetic models developed for the A-type silver catalyst agree well with the experimental results.展开更多
文摘The control of the clutch engagement for an automatic mechanical transmission in the process of a tracklayer getting to start is studied. The dynamic model of power transmission and automatic clutch system is developed. Using tools of Simulink, the transient characteristics during the vehicle starting, including the jerk and the clutch slip time, are provided here. Based on the analyses of the simulation results and driver’s experiences, a fuzzy controller is designed to control the clutch engagement. Simulation results verify its value.
基金Supported by the National Natural Science Foundation of China(61074162)the Ph.D.Program Foundation of Ministry of Education of China(200802870011)~~
文摘The mathematical model of 4He quantum interferometer gyroscope is presented. The model includes the driven equation, the current equation and the position equation. Therefore, it can sufficiently describe the gyro- scope system. The driven equation shows the thermally driven gyroscope can work for a long time but the pres- sure driven one cannot. From the current equation, the superfluid currents passing through the weak link contain the AC currents which show the rotation flux, and other currents caused by drive. As shown in the position equa- tion, the displacement of diaphragm is the only detectable parameter in the gyroscope system. The model is tested by the simulations based on experimental parameters, and can be used to research performance of the gyroscope and analyse the gyroscope error.
文摘To investigate the vibration principle in machining thin-walled components, a dynamic model for end milling of flexible structures is built based on considering the variations in the dynamic chip thickness and the differences between up-milling and down-milling. Two milling experiments verify the model. Experimental results show that the model can predict the milling force and displacements simultaneously in the dynamic milling process.
基金supported by the National Natural Science Foundation of China (Nos.11972241,11572212 and 11272227)the Natural Science Foundation of Jiangsu Province(No. BK20191454)。
文摘In order to investigate the dynamic behavior of non-conservative systems,the Lie symmetries and conserved quantities of fractional Birkhoffian dynamics based on quasi-fractional dynamics model are proposed and studied.The quasi-fractional dynamics model here refers to the variational problem based on the definition of RiemannLiouville fractional integral(RLFI),the variational problem based on the definition of extended exponentially fractional integral(EEFI),and the variational problem based on the definition of fractional integral extended by periodic laws(FIEPL).First,the fractional Pfaff-Birkhoff principles based on quasi-fractional dynamics models are established,and the corresponding Birkhoff’s equations and the determining equations of Lie symmetry are obtained.Second,for fractional Birkhoffian systems based on quasi-fractional models,the conditions and forms of conserved quantities are given,and Lie symmetry theorems are proved.The Pfaff-Birkhoff principles,Birkhoff’s equations and Lie symmetry theorems of quasi-fractional Birkhoffian systems and classical Birkhoffian systems are special cases of this article.Finally,some examples are given.
基金Supported by the National Sci-Tech Major Special Item(No.2008ZX05056-03)
文摘The South China Sea contains tremendous oil and gas resources in deepwater areas. However, one of the keys for deepwater exploration, the investigation of deepwater floating platforms, is very inadequate. In this paper, the authors studied and compared the hydrodynamics and global motion behaviors of typical deepwater platforms in the South China Sea environment. The hydrodynamic models of three main types of floating platforms, e.g. the Semi-submersible, tension leg platform （TLP）, and Truss Spar, which could potentially be utilized in the South China Sea, were established by using the 3-D potential theory. Additionally, some important considerations which significantly influence the hydrodynamics were given. The RAOs in frequency domains as well as global motions in time domains under time-varying wind, random waves, and current in 100-y, 10-y, and 1-y return period environment conditions were predicted, compared, and analyzed. The results indicate that the heave and especially the pitch motion of the TLP are favorable. The heave response of the Truss Spar is perfect and comparable with that of the TLP when the peak period of random waves is low. However, the pitch motion of Truss Spar is extraordinarily lar^er than that of Semi-submersible and TLP.
基金Projects 50221402, 50490271 and 50025413 supported by the National Natural Science Foundation of Chinathe National Basic Research Program of China (2009CB219603, 2009 CB724601, 2006CB202209 and 2005CB221500)+1 种基金the Key Project of the Ministry of Education (306002)the Program for Changjiang Scholars and Innovative Research Teams in Universities of MOE (IRT0408)
文摘In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflect actual situations and facilitate their computation and analyses.Given the importance of model building, further processing methods about traditional seismic interpretation results from Landmark should be studied and the processed result can then be directly used in numerical simulation computations.Through this data conversion procedure, Landmark and FLAC(the international general stress software) are seamlessly connected.Thus, the format conversion between the two systems and the pre-and post-processing in simulation computation is realized.A practical application indicates that this method has many advantages such as simple operation, high accuracy of the element subdivision and high speed, which may definitely satisfy the actual needs of floor grid cutting.
基金financially supported by INVENTIVE~ Mineral Processing Research Center of Iran
文摘This study modeled the effects of structural and dimensional manipulations on hydrodynamic behavior of a bench vertical current classifier. Computational fluid dynamics （CFD） approach was used as modeling method, and turbulent intensity and fluid velocity were applied as system responses to predict the over- flow cut size variations. These investigations showed that cut size would decrease by increasing diameter and height of the separation column and cone section depth, due to the decrease of turbulent intensity and fluid velocity. As the size of discharge gate increases, the overflow cut-size would decrease due to freely fluid stream out of the column. The overflow cut-size was significantly increased in downward fed classifier compared to that fed by upward fluid stream. In addition, reforming the shape of angular overflow outlet＇s weir into the curved form prevented stream inside returning and consequently unselec- tire cut-size decreasing.
基金Project 104030 supported by the Ministry of Education of the People’s Republic of China
文摘Given the actual working of a fully mechanized plough at a mining face, we have proposed a formula for running constraints between powered supports and a coal plough under assumed geological conditions of the coal face and, on this basis, established an automatic control model of powered supports for the coal plough face. We introduced the working principle of the powered support control system of the plough at the mining face. We established three advanced characteristics of this control system： response speed, reliability and easy maintenance of the system. As well, we briefly introduced, the principal function of primary and subordinate controllers and the realization of the communication system by a Single Bus. Ten controllers were constructed and tested in our laboratorium. The results show that the control model is practical and meets actual conditions. It provides a theoretical basis for designing a comouter control system for a oowered support system of a plough at a mining face.
文摘In this paper, Noblesse's New Slender-Ship Wave-Making Theory was investigated numerically. Detailed expressions of zeroth and lst order wave resistance have been derived and calculation programs have also been compiled. In the single and double integral terms of Green function, the kernel function of wave resistance expression, special function expansion method and Chebyshev polynomials approach have been adopted respectively, which greatly simplify the calculation and increase the convergence speed.
基金Supported by National Natural Science Foundation of China (51079032)
文摘An innovative hydrodynamic theory and numerical model were developed to help improve the efficiency, accuracy, and convergence of the numerical prediction of wave drift forces on two side-by-side deepwater floating bodies. The wave drift forces were expressed by the double integration of source strength and the corresponding Green function on the body surface, which is consistent with the far field formula based on momentum conservation and sharing the advantage of near field calculations providing the drift force on each body. Numerical results were validated through comparing the general far field model and pressure integral model, as well as the middle field model developed usin^z the software HydroStar.
基金the National Natural Science Foundation of China (No: 51035030) and the Applied and Basic Research Foundation of Chongqing University
文摘A mathematical model based on an electrorheological (ER) shock absorber with the mixed-mode is presented. Its application to the parametric design of an electrorheological fluid shock absorber with the simulation calculation performed by program MATLAB demonstrates that the model can predict the behavior of ER shock absorbers satisfactorily, shorten the design period of an electrorheological shock absorber, and reduce the cost in the prototype manufacturing. The strength analysis based on a three-dimensional finite element model for the electrorheological shock absorber confirm that the structure design of the ER shock absorber is reasonable, and the stress distribution is uniform.
文摘This study examines the hydrodynamic performance of multiple-row vertical slotted breakwaters. We developed a mathematical model based on an eigenfunction expansion method and a least squares technique for Stokes second-order waves. The numerical results obtained for limiting cases of double-row and triple-row walls are in good agreement with results of previous studies and experimental results. Comparisons with experimental measurements of the reflection, transmission, and dissipation coefficients （CR, Cr, and CE） for double-row walls show that the proposed mathematical model adequately reproduces most of the important features. We found that for double-row walls, the CR increases with increasing wave number, kd, and with a decreasing permeable wall part, din. The Cr follows the opposite trend. The CE slowly increases with an increasing kd for lower kd values, reaches a maximum, and then decreases again. In addition, an increasing porosity of dm would significantly decrease the CR while increasing the Cr. At lower values of kd, a decreasing porosity increases the CE, but for high values of kd, a decreasing porosity reduces the Ce. The numerical results indicate that, for triple-row walls, the effect of the arrangement of the chamber widths on hydrodynamic characteristics is not significant, except when kd〈0.5 Double-row slotted breakwaters may exhibit a good wave-absorbing performance at kd〉0.5, where by the horizontal wave force may be smaller than that of a single wall. On the other hand, the difference between double-row and triple-row vertical slotted breakwaters is marginal.
文摘In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides in diesel were explored. Through studying the mechanism for oxidation of sulfides and the principle of solvent extraction,the kinetic equation of desulfurization via oxidative extraction were determined. By means of the evaluation of model parameters and curve fitting,the reaction order between organic sulfide and sulfone,the intrinsic oxidation rate constant of organic sulfide and sulfone,and the equilibrium constant between sulfone in model diesel and extractive solvent were determined. The experimental values of the desulfurization rate and the theoretical values of the corresponding model equation had closely demonstrated that the desulfurization reaction rate had high accuracy. And the reaction kinetics could provide an important basis for diesel desulfurization process in the future.
文摘Oxidation of coke deposited on spent catalytic cracking catalysts was compared with that of coal and coal char via the non-isothermal oxidation means, i.e. the thermal-gravimetric analysis （TGA） and the differential thermal analysis （DTA）. Oxidation kinetic parameters were further investigated by model-fitting methods. The test results showed that the oxidation of spent catalysts was a quite mild process, while coal and coal char experienced sharp weight loss during oxidation. The temperature for commencement and termination of oxidation increased in the following order： coal〈coal char〈spent catalysts, and the oxidation of the three tested materials displayed a self-catalytic nature, with their largest oxidation rate appearing at a weight percent of 24.96%, 34.21% and 57.93%, respectively. The oxidation of spent catalysts obeyed a random nucleation model for the first-order reaction, with Ea=206.13 kJ/mol and lgA=10.10, and the oxidation of coal could be a diffusion-controlled reaction mechanism, with Ea=161.61 kJ/mol and lgA=7.74, while the oxidation of coal char also obeyed a random nucleation model for the first-order reaction, with Ea= 149.36 k J/mol and lgA=7.89.
文摘Before any rock engineering project,mechanical parameters of rocks such as uniaxial compressive strength and young modulus of intact rock get measured using laboratory or in-situ tests,but in some situations preparing the required specimens is impossible.By this time,several models have been established to evaluate UCS and E from rock substantial properties.Artificial neural networks are powerful tools which are employed to establish predictive models and results have shown the priority of this technique compared to classic statistical techniques.In this paper,ANN and multivariate statistical models considering rock textural characteristics have been established to estimate UCS of rock and to validate the responses of the established models,they were compared with laboratory results.For this purpose a data set for 44 samples of sandstone was prepared and for each sample some textural characteristics such as void,mineral content and grain size as well as UCS were determined.To select the best predictors as inputs of the UCS models,this data set was subjected to statistical analyses comprising basic descriptive statistics,bivariate correlation,curve fitting and principal component analyses.Results of such analyses have shown that void,ferroan calcitic cement,argillaceous cement and mica percentage have the most effect on USC.Two predictive models for UCS were developed using these variables by ANN and linear multivariate regression.Results have shown that by using simple textural characteristics such as mineral content,cement type and void,strength of studied sandstone can be estimated with acceptable accuracy.ANN and multivariate statistical UCS models,revealed responses with 0.87 and 0.76 regressions,respectively which proves higher potential of ANN model for predicting UCS compared to classic statistical models.
文摘By taking the surface chemical reactions as the rate-controlling step, a possible reaction mechanism for ethylene epoxidation to synthesize ethylene oxide over the A-type silver catalyst was developed, while it was assumed that the epoxidation reaction would take place between ethylene and the un-dissociated adsorbed oxygen O2 a on the solo active sites, while the deep oxidation would occur between ethylene and the dissociated adsorbed oxygen Oa on the adjacent multi-active sites. In order to describe the effect of 1,2-C2H4Cl2(EDC) inhibitor on the ethylene epoxidation process, the reversible reactions between EDC and vinyl chloride(VC) on the active sites of silver catalyst was introduced. According to the assumed mechanism, the hyperbolic macro-kinetic model of ethylene epoxidation over the A-type silver catalyst was established, and the macrokinetic experiments were carried out in an internal-recycle gradientless reactor operating at a pressure of 2.1 MPa and a temperature in the range of 217.8—249.0 ℃, with the gas composition(molar fraction) consisting of 15.82%—34.65% C2H4, 2.55%—7.80% O2, 0.88%—6.15% CO2, 0.15—2.61 μmol/mol of 1,2-C2H4Cl2 and 0.14—1.28 μmol/mol of C2H3 Cl. By means of the Simplex Optimal Method, the parameters of the macrokinetic models were estimated. Statistical test showed that the macrokinetic models developed for the A-type silver catalyst agree well with the experimental results.
