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放射孔二氧化硅及其核壳结构的制备与表征 被引量:1
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作者 齐娟娟 徐东耀 +1 位作者 蔡强 张伟 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2012年第4期652-656,共5页
室温下以十六烷基三甲基溴化铵(CTAB)为模板剂,正硅酸乙酯(TEOS)为硅源,氨水(质量分数25%)为催化剂,在水-乙醇-乙醚作共溶剂的体系中以氨基化的实心二氧化硅(NH2-sSiO2)为添加剂,制备了放射孔二氧化硅及其核壳结构(sSiO2@rSiO2).通过扫... 室温下以十六烷基三甲基溴化铵(CTAB)为模板剂,正硅酸乙酯(TEOS)为硅源,氨水(质量分数25%)为催化剂,在水-乙醇-乙醚作共溶剂的体系中以氨基化的实心二氧化硅(NH2-sSiO2)为添加剂,制备了放射孔二氧化硅及其核壳结构(sSiO2@rSiO2).通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、小角X射线衍射(XRD)、氮气吸附-脱附实验和孔径分布测定对其进行了表征和分析.结果表明,合成的产物为0.4~1μm的球形粒子,球上存在多级放射状孔道结构,孔径从3 nm到几十纳米的多级孔径并存,样品的Brunauer-Emmett-Teller(BET)比表面积为996 m2/g.最后对放射孔二氧化硅的形成机理及核壳结构的影响因素进行了初步探讨. 展开更多
关键词 放射孔 二氧化硅 核壳结构 乙醚
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Coupled thermo-hydro-mechanical-migratory model for dual-porosity medium and numerical analysis 被引量:6
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作者 张玉军 杨朝帅 《Journal of Central South University》 SCIE EI CAS 2011年第4期1256-1262,共7页
A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the see... A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity. 展开更多
关键词 ubiquitous-joint rockmass dual-porosity medium thermo-hydro-mechanical-migratory coupling model numericalanalysis
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2D FEM analysis for coupled thermo-hydro-mechanical-migratory processes in near field of hypothetical nuclear waste repository 被引量:3
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作者 张玉军 张维庆 《Journal of Central South University》 SCIE EI CAS 2010年第3期612-620,共9页
In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hyd... In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hydro-mechanical (THM) processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m^3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m^3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process. 展开更多
关键词 radioactive nuclide CONCENTRATION thermo-hydro-mechanical-migratory coupling 2D FEM analysis
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