The mass loss in pyrolysis of macerals from Shenmu coal wa s systematically investigated by using TG-151 pressurized thermobalance at differ ent final temperatures and heating rates.The volatile yield was related to p...The mass loss in pyrolysis of macerals from Shenmu coal wa s systematically investigated by using TG-151 pressurized thermobalance at differ ent final temperatures and heating rates.The volatile yield was related to petr ographic composition.The results of ΔW,the difference of coal volatile yie lds between experimental and theoretical ones, indicated that vitrinite and iner tinite had significant synergistic effect during pyrolysis. With increasing tem perature, the synergism of vitrinite and inertinite during pyrolysis increased. The heating rate had different effect on the synergism which depended on the fin al temperature.展开更多
A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional s...A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional sensing signals.Simultaneous monitoring of the redox current and color change synchronized with the oxidation state change significantly enhances sen-sitivity and selectivity.This study aimed to elucidate the modification of an indium tin oxide(ITO)electrode with a viologen monolayer with an ordered orientation.Novel methods were developed to immobilize a viologen molecule bearing a car-boxyl group to form assembled monolayers through a condensation reaction using 1-ethyl-3-(3-dimethylaminopropyl)-car-bodiimide with N-hydroxy-succinimide(EDC/NHS).In the two methods of immobilization,one utilizes a two-step process to firstly form an aromatic siloxane base layer and subsequently attach the viologen derivative through an amide linkage by post-amidation.The other employs a direct ester linkage between the hydroxyl groups of the ITO surface and the car-boxyl group of the viologen derivative.The latter method was also applied to immobilize a ferrocenyl group at a very short distance from the ITO surface.Potential-modulated UV-visible transmission absorption spectral measurement techniques with oblique incidence of plane-polarized light were employed to determine the orientation of the longitudinal axis of the reduced form of the viologen.The frequency dependence data of the potential-modulated transmission absorption signals were utilized to analyze the electron transfer kinetics.The performance of the two viologen-modified electrodes was com-pared to that of an ITO modified by post-amidation to the most commonly used base layer prepared with 3-aminopropyl triethoxysilane.展开更多
In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradien...In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradient method.Under the condition of standard Wolfe line search,the proposed search direction is the descent direction.For general nonlinear functions,the method is globally convergent.Finally,numerical results show that the proposed method is efficient.展开更多
The complete convergence for weighted sums of sequences of independent,identically distributed random variables under sublinear expectation space is studied.By moment inequality and truncation methods,we establish the...The complete convergence for weighted sums of sequences of independent,identically distributed random variables under sublinear expectation space is studied.By moment inequality and truncation methods,we establish the equivalent conditions of complete convergence for weighted sums of sequences of independent,identically distributed random variables under sublinear expectation space.The results complement the corresponding results in probability space to those for sequences of independent,identically distributed random variables under sublinear expectation space.展开更多
The liquid ion exchange method, solid salt melt method and dry-wet circulation method were used to prepare natural porous antimicrobial materials with natural minerals, such as zeolite, spilite, palygorskite and montm...The liquid ion exchange method, solid salt melt method and dry-wet circulation method were used to prepare natural porous antimicrobial materials with natural minerals, such as zeolite, spilite, palygorskite and montmorillonite, respectively. Atomic absorption spectrum and X-ray diffraction analysis were carried out to investigate the effects of Ag^＋ , Cu^2＋ and Zn^2＋ on antimicrobial abilities of natural porous minerals, and the effect of preparation method on ion exchange capacity of antimicrobial material, respectively. The results show that for the ion exchange capacity, clay mineral is higher than fibrous mineral, i.e. both zeolite and montmorillonite are higher; the antimicrobial ability of material with Ag^＋ is the bests the exchange capacities of materials with Cu^2＋ or Zn^2＋ are all higher, but the antimicrobial ability of Cu^2＋ is better than that of Zn^2＋ .展开更多
For improving the performance of differential geometric guidance command(DGGC), a new formation of this guidance law is proposed, which can guarantee the finite time convergence(FTC) of the line of sight(LOS) rate to ...For improving the performance of differential geometric guidance command(DGGC), a new formation of this guidance law is proposed, which can guarantee the finite time convergence(FTC) of the line of sight(LOS) rate to zero or its neighborhood against maneuvering targets in three-dimensional(3D) space. The extended state observer(ESO) is employed to estimate the target acceleration, which makes the new DGGC more applicable to practical interception scenarios. Finally, the effectiveness of this newly proposed guidance command is demonstrated by the numerical simulation results.展开更多
Consensus tracking control problems for single-integrator dynamics of multi-agent systems with switching topology are investigated. In order to design effective consensus tracking protocols for a more general class of...Consensus tracking control problems for single-integrator dynamics of multi-agent systems with switching topology are investigated. In order to design effective consensus tracking protocols for a more general class of networks, which are aimed at ensuring that the concerned states of agents converge to a constant or time-varying reference state, new consensus tracking protocols with a constant and time-varying reference state are proposed, respectively. Particularly, by contrast with spanning tree, an improved condition of switching interaction topology is presented. And then, convergence analysis of two consensus tracking protocols is provided by Lyapunov stability theory. Moreover, consensus tracking protocol with a time-varying reference state is extended to achieve the fbrmation control. By introducing formation structure set, each agent can gain its individual desired trajectory. Finally, several simulations are worked out to illustrate the effectiveness of theoretical results. The test results show that the states of agents can converge to a desired constant or time-varying reference state. In addition, by selecting appropriate structure set, agents can maintain the expected formation under random switching interaction topologies.展开更多
This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antim...This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.展开更多
Swelling and shrinkage due to moisture-change is one of the characteristics of the expansive soil,which is similar to the behavior of most materials under thermal effect,If the deformation is restricted,stress in expa...Swelling and shrinkage due to moisture-change is one of the characteristics of the expansive soil,which is similar to the behavior of most materials under thermal effect,If the deformation is restricted,stress in expansive soil is caused by the swell-shrinking.The stress is defined as "moisture-change stress" and is adopted to analyze swell-shrinkage deformation based on the elasticity mechanics theory.The state when the total stress becomes equal to the soil tensile strength is considered as the cracking criterion as moisture-change increases.Then,the initial cracking mechanism due to evaporation is revealed as follows:Different rates of moisture loss at different depths result in greater shrinkage deformation on the surface while there is smaller shrinkage deformation at the underlayer in expansive soil;cracks will grow when the nonuniform shrinkage deformation increases to a certain degree.A theoretical model is established,which may be used to calculate the stress caused by moisture-change.The depth of initial cracks growing is predicted by the proposed model in expansive soil,A series of laboratory tests are carried out by exposing expansive soil samples with different moisture-changes.The process of crack propagation is investigated by resistivity method.The test results show good consistency with the predicted results by the proposed theoretical model.展开更多
In non-dedicated cooperative relay networks, each node is autonomous and selfish in nature, and thus spontaneous cooperation among nodes is challenged. To stimulate the selfish node to participate in cooperation, a pr...In non-dedicated cooperative relay networks, each node is autonomous and selfish in nature, and thus spontaneous cooperation among nodes is challenged. To stimulate the selfish node to participate in cooperation, a pricing-based cooperation engine using game theory was designed. Firstly, the feasible regions of the charge price and reimbursement price were deduced. Then, the non-cooperative and cooperative games were adopted to analyze the amount of bandwidth that initiating cooperation node(ICN) forwards data through participating cooperation node(PCN) and the amount of bandwidth that PCN helps ICN to relay data. Meanwhile, the Nash equilibrium solutions of cooperation bandwidth allocations(CBAs) were obtained through geometrical interpretation. Secondly, a pricing-based cooperation engine was proposed and a cooperative communication system model with cooperation engines was depicted. Finally, an algorithm based on game theory was proposed to realize the cooperation engine. The simulation results demonstrate that, compared with the system without pricing-based incentive, the proposed system can significantly improve the ICN's metric measured by bit-per-Joule and increase the PCN's revenue.展开更多
Successful recovery of limonite from iron fines was achieved by using flocculation-high intensity magnetic separation （FIMS） and adding hydrolyzed and causticized flocculants according to the characteristic of iron ...Successful recovery of limonite from iron fines was achieved by using flocculation-high intensity magnetic separation （FIMS） and adding hydrolyzed and causticized flocculants according to the characteristic of iron fines. The separation results of the three iron samples are as follows： iron grade 66.77%- 67.98% and the recovery of iron 69.26%-70.70% by the FIMS process with flocculants. The comparative results show that under the same separation conditions the F1MS process can effectively increase the recovery of iron by 10. 97%- 15.73%. The flowsheet results confirm the reliability of the process in a SHP high intensity magnetic separator. The concentrate product can he used as raw materials for direct reduction iron-smelting. The hydrolyzed and causticized flocculants can selectively flocculate fine feebly-magnetic iron mineral particles to increase their apparent separation sizes. The larger the separation size, the stronger the magnetic force. By comparing the separation results of the three samples it is found that among the three samples the higher the limonite content, the better the separation result. This means that the separation result relates closely to the flocculation process and the adding pattern of the flocculant.展开更多
A filtering algorithm and direction identification method are presented for the positioning system of the mid-speed maglev train. Considering the special structure of the mid-speed maglev train, the ground position es...A filtering algorithm and direction identification method are presented for the positioning system of the mid-speed maglev train. Considering the special structure of the mid-speed maglev train, the ground position estimation method is adopted for its traction system. As the train is running, the induction loop-cable receives the signal sent by the on-board antenna to detect the position and direction of the train. But the height of the on-board antenna relative to the loop-cable is highly vulnerable to the change of the suspension height and the magnetic field produced by the traction during traveling, which may lead to amplitude fluctuation of the received signal. Consequently, the position estimation may be inaccurate. Therefore, a discrete second-order nonlinear trackdifferentiator is proposed based on the boundary characteristic curves, and the new differentiator could also extract the running direction of the train for the traction system. The experimental results show that the tracking differentiator can effectively filter out the signal interference and can provide accurate direction signal.展开更多
文摘The mass loss in pyrolysis of macerals from Shenmu coal wa s systematically investigated by using TG-151 pressurized thermobalance at differ ent final temperatures and heating rates.The volatile yield was related to petr ographic composition.The results of ΔW,the difference of coal volatile yie lds between experimental and theoretical ones, indicated that vitrinite and iner tinite had significant synergistic effect during pyrolysis. With increasing tem perature, the synergism of vitrinite and inertinite during pyrolysis increased. The heating rate had different effect on the synergism which depended on the fin al temperature.
基金supports by the Grant-in-Aid of Scientific Research of Challenging Research(Exploratory)(JP23K17738)to TS from MEXT of Japanthe 41st grant of research from Nippon Sheet Glass Foundation for Materials Science and Engineering to TS.
文摘A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional sensing signals.Simultaneous monitoring of the redox current and color change synchronized with the oxidation state change significantly enhances sen-sitivity and selectivity.This study aimed to elucidate the modification of an indium tin oxide(ITO)electrode with a viologen monolayer with an ordered orientation.Novel methods were developed to immobilize a viologen molecule bearing a car-boxyl group to form assembled monolayers through a condensation reaction using 1-ethyl-3-(3-dimethylaminopropyl)-car-bodiimide with N-hydroxy-succinimide(EDC/NHS).In the two methods of immobilization,one utilizes a two-step process to firstly form an aromatic siloxane base layer and subsequently attach the viologen derivative through an amide linkage by post-amidation.The other employs a direct ester linkage between the hydroxyl groups of the ITO surface and the car-boxyl group of the viologen derivative.The latter method was also applied to immobilize a ferrocenyl group at a very short distance from the ITO surface.Potential-modulated UV-visible transmission absorption spectral measurement techniques with oblique incidence of plane-polarized light were employed to determine the orientation of the longitudinal axis of the reduced form of the viologen.The frequency dependence data of the potential-modulated transmission absorption signals were utilized to analyze the electron transfer kinetics.The performance of the two viologen-modified electrodes was com-pared to that of an ITO modified by post-amidation to the most commonly used base layer prepared with 3-aminopropyl triethoxysilane.
基金Supported by the Science and Technology Project of Guangxi(Guike AD23023002)。
文摘In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradient method.Under the condition of standard Wolfe line search,the proposed search direction is the descent direction.For general nonlinear functions,the method is globally convergent.Finally,numerical results show that the proposed method is efficient.
基金supported by Doctoral Scientific Research Starting Foundation of Jingdezhen Ceramic University(Grant No.102/01003002031)Re-accompanying Funding Project of Academic Achievements of Jingdezhen Ceramic University(Grant Nos.215/20506277,215/20506341)。
文摘The complete convergence for weighted sums of sequences of independent,identically distributed random variables under sublinear expectation space is studied.By moment inequality and truncation methods,we establish the equivalent conditions of complete convergence for weighted sums of sequences of independent,identically distributed random variables under sublinear expectation space.The results complement the corresponding results in probability space to those for sequences of independent,identically distributed random variables under sublinear expectation space.
文摘The liquid ion exchange method, solid salt melt method and dry-wet circulation method were used to prepare natural porous antimicrobial materials with natural minerals, such as zeolite, spilite, palygorskite and montmorillonite, respectively. Atomic absorption spectrum and X-ray diffraction analysis were carried out to investigate the effects of Ag^＋ , Cu^2＋ and Zn^2＋ on antimicrobial abilities of natural porous minerals, and the effect of preparation method on ion exchange capacity of antimicrobial material, respectively. The results show that for the ion exchange capacity, clay mineral is higher than fibrous mineral, i.e. both zeolite and montmorillonite are higher; the antimicrobial ability of material with Ag^＋ is the bests the exchange capacities of materials with Cu^2＋ or Zn^2＋ are all higher, but the antimicrobial ability of Cu^2＋ is better than that of Zn^2＋ .
文摘For improving the performance of differential geometric guidance command(DGGC), a new formation of this guidance law is proposed, which can guarantee the finite time convergence(FTC) of the line of sight(LOS) rate to zero or its neighborhood against maneuvering targets in three-dimensional(3D) space. The extended state observer(ESO) is employed to estimate the target acceleration, which makes the new DGGC more applicable to practical interception scenarios. Finally, the effectiveness of this newly proposed guidance command is demonstrated by the numerical simulation results.
基金Projects(61075065,60774045) supported by the National Natural Science Foundation of ChinaProject supported by the Graduate Degree Thesis Innovation Foundation of Central South University,China
文摘Consensus tracking control problems for single-integrator dynamics of multi-agent systems with switching topology are investigated. In order to design effective consensus tracking protocols for a more general class of networks, which are aimed at ensuring that the concerned states of agents converge to a constant or time-varying reference state, new consensus tracking protocols with a constant and time-varying reference state are proposed, respectively. Particularly, by contrast with spanning tree, an improved condition of switching interaction topology is presented. And then, convergence analysis of two consensus tracking protocols is provided by Lyapunov stability theory. Moreover, consensus tracking protocol with a time-varying reference state is extended to achieve the fbrmation control. By introducing formation structure set, each agent can gain its individual desired trajectory. Finally, several simulations are worked out to illustrate the effectiveness of theoretical results. The test results show that the states of agents can converge to a desired constant or time-varying reference state. In addition, by selecting appropriate structure set, agents can maintain the expected formation under random switching interaction topologies.
基金Project(51564034)supported by the National Science Fund for Distinguished Regional Scholars,China
文摘This paper mainly investigated the antimony recovery from antimony-bearing dusts through reduction roasting process after the dust firstly oxidation roasted.CO–CO2 mixture gas was used as reducing agent,and the antimony-containing phase was reduced into Sb4O6,volatilized into smoke,and finally recovered through the cooling cylinder.The antimony recovery rate increased from 66.00 wt%to 73.81 wt%in temperature range of 650 to 800°C,and decreased with temperature increased further to 900°C due to the reduction of Sb4O6 to the nonvolatile Sb.Similarly,the CO partial pressure also played a double role in this test.Under optimized conditions of roasting temperature of 800°C,CO partial pressure of 7.5 vol%and roasting time of 120 min,98.40 wt%of arsenic removal rate and 80.40 wt%antimony recovery rate could be obtained.In addition,the“As2O3”product could be used for preparing ferric arsenate which realized the harmless treatment of it.
基金Project(2006BAB04A10) supported by the National Science and Technology Pillar Program during the 11th Five Year Plan of ChinaProject(51008117) supported by the National Natural Science Foundation of China
文摘Swelling and shrinkage due to moisture-change is one of the characteristics of the expansive soil,which is similar to the behavior of most materials under thermal effect,If the deformation is restricted,stress in expansive soil is caused by the swell-shrinking.The stress is defined as "moisture-change stress" and is adopted to analyze swell-shrinkage deformation based on the elasticity mechanics theory.The state when the total stress becomes equal to the soil tensile strength is considered as the cracking criterion as moisture-change increases.Then,the initial cracking mechanism due to evaporation is revealed as follows:Different rates of moisture loss at different depths result in greater shrinkage deformation on the surface while there is smaller shrinkage deformation at the underlayer in expansive soil;cracks will grow when the nonuniform shrinkage deformation increases to a certain degree.A theoretical model is established,which may be used to calculate the stress caused by moisture-change.The depth of initial cracks growing is predicted by the proposed model in expansive soil,A series of laboratory tests are carried out by exposing expansive soil samples with different moisture-changes.The process of crack propagation is investigated by resistivity method.The test results show good consistency with the predicted results by the proposed theoretical model.
基金Project(61201143)supported by the National Natural Science Foundation of China
文摘In non-dedicated cooperative relay networks, each node is autonomous and selfish in nature, and thus spontaneous cooperation among nodes is challenged. To stimulate the selfish node to participate in cooperation, a pricing-based cooperation engine using game theory was designed. Firstly, the feasible regions of the charge price and reimbursement price were deduced. Then, the non-cooperative and cooperative games were adopted to analyze the amount of bandwidth that initiating cooperation node(ICN) forwards data through participating cooperation node(PCN) and the amount of bandwidth that PCN helps ICN to relay data. Meanwhile, the Nash equilibrium solutions of cooperation bandwidth allocations(CBAs) were obtained through geometrical interpretation. Secondly, a pricing-based cooperation engine was proposed and a cooperative communication system model with cooperation engines was depicted. Finally, an algorithm based on game theory was proposed to realize the cooperation engine. The simulation results demonstrate that, compared with the system without pricing-based incentive, the proposed system can significantly improve the ICN's metric measured by bit-per-Joule and increase the PCN's revenue.
文摘Successful recovery of limonite from iron fines was achieved by using flocculation-high intensity magnetic separation （FIMS） and adding hydrolyzed and causticized flocculants according to the characteristic of iron fines. The separation results of the three iron samples are as follows： iron grade 66.77%- 67.98% and the recovery of iron 69.26%-70.70% by the FIMS process with flocculants. The comparative results show that under the same separation conditions the F1MS process can effectively increase the recovery of iron by 10. 97%- 15.73%. The flowsheet results confirm the reliability of the process in a SHP high intensity magnetic separator. The concentrate product can he used as raw materials for direct reduction iron-smelting. The hydrolyzed and causticized flocculants can selectively flocculate fine feebly-magnetic iron mineral particles to increase their apparent separation sizes. The larger the separation size, the stronger the magnetic force. By comparing the separation results of the three samples it is found that among the three samples the higher the limonite content, the better the separation result. This means that the separation result relates closely to the flocculation process and the adding pattern of the flocculant.
基金Project(11226144) supported by the National Natural Science Foundation of China
文摘A filtering algorithm and direction identification method are presented for the positioning system of the mid-speed maglev train. Considering the special structure of the mid-speed maglev train, the ground position estimation method is adopted for its traction system. As the train is running, the induction loop-cable receives the signal sent by the on-board antenna to detect the position and direction of the train. But the height of the on-board antenna relative to the loop-cable is highly vulnerable to the change of the suspension height and the magnetic field produced by the traction during traveling, which may lead to amplitude fluctuation of the received signal. Consequently, the position estimation may be inaccurate. Therefore, a discrete second-order nonlinear trackdifferentiator is proposed based on the boundary characteristic curves, and the new differentiator could also extract the running direction of the train for the traction system. The experimental results show that the tracking differentiator can effectively filter out the signal interference and can provide accurate direction signal.
