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TC4钛合金表面类金刚石薄膜在模拟体液中的摩擦-腐蚀性能
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作者 苏峰华 陈艺昌 +2 位作者 唐邕涛 孙建芳 陈彦军 《润滑与密封》 北大核心 2025年第8期1-10,共10页
TC4钛合金用作人工关节时长期处于摩擦与腐蚀的耦合作用下,需对其表面进行合理改性以提升其服役寿命。类金刚石薄膜(DLC)因其优异的自润滑性和化学惰性在改善金属耐磨耐蚀方面具有应用的潜力。通过等离子体增强化学气相沉积(PECVD)技术... TC4钛合金用作人工关节时长期处于摩擦与腐蚀的耦合作用下,需对其表面进行合理改性以提升其服役寿命。类金刚石薄膜(DLC)因其优异的自润滑性和化学惰性在改善金属耐磨耐蚀方面具有应用的潜力。通过等离子体增强化学气相沉积(PECVD)技术在TC4钛合金表面制备含氢DLC薄膜,同时采用表面热氧化(TO)钛合金作为对照。采用扫描电子显微镜(SEM)和拉曼光谱(Raman)研究DLC薄膜和TO钛合金的表面形貌和化学组成;采用纳米压痕和划痕仪测试DLC薄膜和TO钛合金的表面硬度和结合力;采用摩擦-腐蚀试验机研究DLC薄膜和TO钛合金在Hank′s模拟体液中的摩擦-腐蚀性能。结果表明,DLC薄膜和TO处理均改善了TC4钛合金的磨损腐蚀性能。其中,DLC薄膜的腐蚀速率比TO钛合金低,且其摩擦因数和磨损率均远小于TO钛合金。尤其是,DLC薄膜的摩擦开路电位仅为-0.27 V,表现出优异的耐磨和耐蚀效果。这主要得益于DLC薄膜的致密性好、化学惰性强、耐磨性好且结合力高,导致Hank′s溶液难以通过DLC薄膜的表面从而侵蚀基材。 展开更多
关键词 TC4钛合金 类金刚石薄膜 热氧化 模拟体液 摩擦-腐蚀
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碳基和氮化物基涂层的摩擦-腐蚀交互行为的原位研究 被引量:19
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作者 高溥 何东青 +2 位作者 郑韶先 蒲吉斌 郭峰 《摩擦学学报》 EI CAS CSCD 北大核心 2015年第2期138-146,共9页
海洋装备大量关键金属运动部件同时承受摩擦与腐蚀作用,其表面防护涂层在海水环境下的抗磨擦-腐蚀性能成为考察涂层性能优劣的关键.本文中采用摩擦-腐蚀试验机原位实时监测了DLC、Cr-DLC、Cr N与Ti N四种涂层与氧化铝陶瓷摩擦副在人工... 海洋装备大量关键金属运动部件同时承受摩擦与腐蚀作用,其表面防护涂层在海水环境下的抗磨擦-腐蚀性能成为考察涂层性能优劣的关键.本文中采用摩擦-腐蚀试验机原位实时监测了DLC、Cr-DLC、Cr N与Ti N四种涂层与氧化铝陶瓷摩擦副在人工海水环境下的开路电位和摩擦系数等腐蚀-磨损特性,并采用动电位扫描法测试了四种涂层在腐蚀和摩擦-腐蚀过程中的电化学行为,综合分析了涂层在海水介质中的磨损-腐蚀交互机制.研究结果表明:非晶结构的碳基涂层在海水介质中具有优异的抗腐蚀和抗摩擦-腐蚀性能,其中金属铬的掺入能够进一步提高DLC涂层的抗摩擦-腐蚀性能;而氮化物基涂层的粗大柱状晶结构显著削弱了其在海水环境中的抗摩擦-腐蚀性能. 展开更多
关键词 涂层 海水 摩擦-腐蚀 开路电位 动电位极化
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Tribological behavior of Cu-15Ni-8Sn/graphite under sea water, distilled water and dry-sliding conditions 被引量:5
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作者 WANG Yan ZHANG Lei +2 位作者 ZHAI Hong-fei GAO Hong-xia ZHOU Ke-chao 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第10期2623-2633,共11页
The tribological behaviors of Cu-15Ni-8Sn/graphite composites with the graphite content of 38 vol.%against AISI321 stainless steel under dry-sliding,deionized water and sea water were investigated on a block-on-ring c... The tribological behaviors of Cu-15Ni-8Sn/graphite composites with the graphite content of 38 vol.%against AISI321 stainless steel under dry-sliding,deionized water and sea water were investigated on a block-on-ring configuration.The results indicated that the friction coefficient was the lowest under dry-sliding,and the highest in deionized water.The wear rate decreased to reach the minimum value of 1.39×10-15 m^(3)/(N·m)in sea water and in deionized water,it increased to the maximum value of 5.56×10-15 m^(3)/(N·m).The deionized water hindered the formation of tribo-oxide layer and lubricating film,which resulted in the largest friction coefficient and wear rate.In sea water,however,the corrosion products comprised of oxides,hydroxides and chlorides were found on the worn surface,and the compacted layer composed of corrosion products and graphite played an important role in keeping the excellent wear resistance.It was elucidated that the tribological behaviors of Cu-15Ni-8Sn/graphite composite were powerful influenced by the friction environments. 展开更多
关键词 self-lubricating composites tribological behavior compacted layers corrosion products sea water
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热带海洋盐雾气氛自润滑耐磨防腐涂层技术研究新进展 被引量:6
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作者 罗一旻 杨军华 +5 位作者 李霞 谭生 王伟 罗荘竹 张广安 张俊彦 《摩擦学学报》 EI CAS CSCD 北大核心 2023年第1期104-120,共17页
随着“南海海洋纵深开发”和“深海深地深空”国家战略持续推进,热带海洋气氛下的磨损与腐蚀耦合损伤成为海洋装备的关键技术瓶颈.本文中通过对比我国四大海域(渤海、黄海、东海及南海)海洋多场作用因素及装备苛刻服役环境,重点指出了... 随着“南海海洋纵深开发”和“深海深地深空”国家战略持续推进,热带海洋气氛下的磨损与腐蚀耦合损伤成为海洋装备的关键技术瓶颈.本文中通过对比我国四大海域(渤海、黄海、东海及南海)海洋多场作用因素及装备苛刻服役环境,重点指出了热带海洋(南海海域)工程装备运动传动系统/部件所面临的“摩擦-磨损-腐蚀”共性技术难题;讨论分析模拟海洋腐蚀介质与实海环境下DLC薄膜、陶瓷涂层、轻合金微弧氧化涂层、MoS_(2)基粘结涂层(软质)和功能一体化高分子合金(软质)等自润滑涂层的摩擦磨损行为及其损伤失效特点;从界面协同与功能匹配角度提出了热带海洋动态自润滑耐磨防腐的科学问题及研究新思路,寄望提升我国在热带海洋高技术装备关键传动部件/系统自润滑防腐方面的技术水平. 展开更多
关键词 热带海洋 海工装备 盐雾气氛 摩擦-腐蚀 自润滑防腐
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Influence of welding speed on corrosion behaviour of friction stir welded AA5086 aluminium alloy 被引量:5
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作者 Kamran Amini Farhad Gharavi 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第6期1301-1311,共11页
The plates of AA5086 aluminium alloy were joined together by friction stir welding at a fixed rotation speed of 1000 r/min various welding speeds ranging from 63 to 100 mm/min.Corrosion behavior of the parent alloy(PA... The plates of AA5086 aluminium alloy were joined together by friction stir welding at a fixed rotation speed of 1000 r/min various welding speeds ranging from 63 to 100 mm/min.Corrosion behavior of the parent alloy(PA),the heat affected zone(HAZ),and the weld nugget zone(WNZ)of the joints were studied in 3.5%(mass fraction)aerated aqueous Na Cl solution by potentiodynamic polarization and electrochemical impedance spectroscopy(EIS).The corrosion susceptibility of the weldments increases when the welding speed increases to 63 and 100 mm/min.However,the value of corrosion rate in the weldments is lower than that in the PA.Additionally,the corrosion current density increases with increasing the welding speed in the HAZ and the WNZ.On the contrary,the corrosion potential in the WNZ appears more positive than in the HAZ with decreasing the welding speed.The WNZ exhibits higher resistance compared to the HAZ and the PA as the welding speed decreases.The results obtained from the EIS measurements suggest that the weld regions have higher corrosion resistance than the parent alloy.With increasing the welding speed,the distribution and extent of the corroded areas in the WNZ region are lower than those of the HAZ region.In the HAZ region,in addition to the pits in the corroded area,some cracks can be seen around the corroded areas,which confirms that intergranular corrosion is formed in this area.The alkaline localized corrosion and the pitting corrosion are the main corrosion mechanisms in the corroded areas within the weld regions.Crystallographic pits are observed within the weld regions. 展开更多
关键词 friction stir welding aluminum alloy corrosion properties welding speed
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Mechanism of corrosion fatigue fracture of friction stir welding joints of 7075 aluminium alloy in 3.5% NaCl solution 被引量:1
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作者 BAI Lin-yue SHAO Fei +3 位作者 MA Qing-na XU Qian HU Jian-xiang HOU Yi-nan 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第3期1015-1028,共14页
The corrosion fatigue fracture mechanism of friction stir welding(FSW) joints of 7075 aluminium alloy in3.5% NaCl solution is investigated. The corrosion fatigue crack source originates from the junction of nugget zon... The corrosion fatigue fracture mechanism of friction stir welding(FSW) joints of 7075 aluminium alloy in3.5% NaCl solution is investigated. The corrosion fatigue crack source originates from the junction of nugget zone(NZ)and thermo-mechanical affected zone(TMAZ). Multiple crack sources are developed at the same time, and they merge into large cracks along the boundary line of NZ and TMAZ during the propagation stage. Furthermore, a mutual reinforcement coupling always exists between corrosion and cyclic loading during the initiation and propagation of corrosion fatigue crack. It is necessary to consider the effect of welding residual stress for understanding the mechanism of corrosion fatigue fracture of FSW joints. 展开更多
关键词 aluminium alloy friction stir welding welded joint corrosion fatigue FRACTURE
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Corrosion behavior of dissimilar copper/brass joints welded by friction stir lap welding in alkaline solution 被引量:2
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作者 Kamran AMINI Farhad GHARAVI 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第6期1573-1581,共9页
This study was done to evaluate the nugget zone(NZ)corrosion behavior of dissimilar copper/brass joints welded by friction stir lap welding(FSLW)in a solution of 0.015 mol/L borax(pH 9.3).To this end,dissimilar copper... This study was done to evaluate the nugget zone(NZ)corrosion behavior of dissimilar copper/brass joints welded by friction stir lap welding(FSLW)in a solution of 0.015 mol/L borax(pH 9.3).To this end,dissimilar copper/brass plates were welded with two dissimilar heat inputs(low and high)during the welding procedure.The high and low heat inputs were conducted with 710 r/min,16 mm/min and 450 r/min,25 mm/min,respectively.Using open circuit potential(OCP)measurements,electrochemical impedance spectroscopy(EIS)and Tafel polarization tests,the electrochemical behavior of the specimens in borate buffer solution was assessed.With the help of scanning electron microscope(SEM),the morphology of welded specimen surfaces was examined after immersion in the test solution.According to the results,the NZ grain size and resistance improvement reduced due to the nugget zone corrosion with a decreased heat input.The results obtained from Tafel polarization and EIS indicated the improved corrosion behavior of the welded specimen NZ with a decrease in the heat input during the welding process unlike the copper and brass metals.Furthermore,an increased heat input during the welding process shows a reduction in the conditions for forming the passive films with higher protection behavior. 展开更多
关键词 friction stir welding COPPER brass alloy corrosion behavior alkaline solution dissimilar joint
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