Stability analysis of gravity retaining wall was currently based on the assumption that the wall had no embedment depth. The effect of earth berm was usually neglected. The present work highlighted the importance of e...Stability analysis of gravity retaining wall was currently based on the assumption that the wall had no embedment depth. The effect of earth berm was usually neglected. The present work highlighted the importance of embedment depth when assessing the seismic stability of gravity retaining walls with the pattern of pure rotation. In the framework of upper bound theorem of limit analysis, pseudo-static method was applied into two groups of parallel rigid soil slices methods in order to account for the effect of embedment depth on evaluating the critical acceleration of wall-soil system. The present analytical solution is identical to the results obtained from using limit equilibrium method, and the two methods are based on different theory backgrounds. Parameter analysis indicates that the critical acceleration increases slowly when the ratio of the embedment depth to the total height of the wall is from 0 to 0.15 and increases drastically when the ratio exceeds 0.15.展开更多
Na-montruorillonite (Na-MMT) was exchanged with three quaternary atkylphosphonium salts: decyl tributylphosphonium bromide (DTBPBr), dodecyl tributylphosphonium bromide (DDTBPBr) and hexadecyl tributylphosphoni...Na-montruorillonite (Na-MMT) was exchanged with three quaternary atkylphosphonium salts: decyl tributylphosphonium bromide (DTBPBr), dodecyl tributylphosphonium bromide (DDTBPBr) and hexadecyl tributylphosphonium bromide (HDTBPBr), to investigate the effects of phosphonium salts species and relative molecular mass on the characteristics, morphology, thermal stability and long-acting antibacterial property of phosphonium montmorillonites. The resulting modified montmorillonites were characterized by the FTIR, XRD, TEM, and TG/DTG techniques. And minimum inhibitory concentration (MIC) was used to investigate antibacterial activity. The results show that the phosphonium salts are intercalated into Na-MMT, and the basal spacing of P-MMTs is enlarged with the increase of phosphonium salt content or the growth of alkyl chain length. DDTBP-MMT-3 with 19.83% (mass fraction of dodecyl tributylphosphonium salts, displays excellent thermal stability and long-acting antibacterial activity.展开更多
The waste fiuorgypsum was modified and applied as a cement retarder. The main chemical composition and mineral structure of the waste fluorgypsum were analyzed. Scanning electron microscopy (SEM) and eight-channel m...The waste fiuorgypsum was modified and applied as a cement retarder. The main chemical composition and mineral structure of the waste fluorgypsum were analyzed. Scanning electron microscopy (SEM) and eight-channel micro-calorimeter (TAM Air) were employed to analyze the changes in morphology and study the application performance of the modified fluorgypsum, respectively. Experimental results indicate that the flexural strength and compressive strength of the modified fiuorgypsurn are roughly equal to those of the natural gypsum. The morphology of the crystal of the fiuorgypsum changes from block particle into trimetric short column. The fluorgypsum crystals stagger mutually and improve the strength of the hardened body. The modified fluorgypsum as cement retarder could delay the hydration, reduce the heat of the hydration and make the setting time, volume stability, and the S03 content of the cement meet the national standards. The modified fluorgypsum is a good substitute for the natural gypsum.展开更多
基金Project(41472245)supported by the National Natural Science Foundation of ChinaProject(CQGT-KJ-2014049)supported by the Chongqing Administration of Land,Resources and Housing,ChinaProject(106112014CDJZR200009)supported by the Fundamental Research Funds for the Central Universities,China
文摘Stability analysis of gravity retaining wall was currently based on the assumption that the wall had no embedment depth. The effect of earth berm was usually neglected. The present work highlighted the importance of embedment depth when assessing the seismic stability of gravity retaining walls with the pattern of pure rotation. In the framework of upper bound theorem of limit analysis, pseudo-static method was applied into two groups of parallel rigid soil slices methods in order to account for the effect of embedment depth on evaluating the critical acceleration of wall-soil system. The present analytical solution is identical to the results obtained from using limit equilibrium method, and the two methods are based on different theory backgrounds. Parameter analysis indicates that the critical acceleration increases slowly when the ratio of the embedment depth to the total height of the wall is from 0 to 0.15 and increases drastically when the ratio exceeds 0.15.
基金Projects(20676049, 20871058) supported by the National Natural Science Foundation of China Project(05200555) supported by the Natural Science Foundation of Guangdong Province, China Projects(2007B090400105, 2008A010500005) supported by the Foundation of Enterprise-University-Research Institute Cooperation from Guangdong Province and Ministry of Education of China
文摘Na-montruorillonite (Na-MMT) was exchanged with three quaternary atkylphosphonium salts: decyl tributylphosphonium bromide (DTBPBr), dodecyl tributylphosphonium bromide (DDTBPBr) and hexadecyl tributylphosphonium bromide (HDTBPBr), to investigate the effects of phosphonium salts species and relative molecular mass on the characteristics, morphology, thermal stability and long-acting antibacterial property of phosphonium montmorillonites. The resulting modified montmorillonites were characterized by the FTIR, XRD, TEM, and TG/DTG techniques. And minimum inhibitory concentration (MIC) was used to investigate antibacterial activity. The results show that the phosphonium salts are intercalated into Na-MMT, and the basal spacing of P-MMTs is enlarged with the increase of phosphonium salt content or the growth of alkyl chain length. DDTBP-MMT-3 with 19.83% (mass fraction of dodecyl tributylphosphonium salts, displays excellent thermal stability and long-acting antibacterial activity.
基金Project(21003014) supported by the National Natural Science Foundation of ChinaProject(2010FJ3167) supported by the Hunan Provincial Science and Technology Program,ChinaProject(K1104029-11) supported by the Changsha IT Project
文摘The waste fiuorgypsum was modified and applied as a cement retarder. The main chemical composition and mineral structure of the waste fluorgypsum were analyzed. Scanning electron microscopy (SEM) and eight-channel micro-calorimeter (TAM Air) were employed to analyze the changes in morphology and study the application performance of the modified fluorgypsum, respectively. Experimental results indicate that the flexural strength and compressive strength of the modified fiuorgypsurn are roughly equal to those of the natural gypsum. The morphology of the crystal of the fiuorgypsum changes from block particle into trimetric short column. The fluorgypsum crystals stagger mutually and improve the strength of the hardened body. The modified fluorgypsum as cement retarder could delay the hydration, reduce the heat of the hydration and make the setting time, volume stability, and the S03 content of the cement meet the national standards. The modified fluorgypsum is a good substitute for the natural gypsum.