The residue drying area(RDA)is the major source of fugitive red sand(RS)dust emissions in the bauxite mining industry and causes serious environmental and safety detriments.Polymer stabilizer(PS)is one of the promisin...The residue drying area(RDA)is the major source of fugitive red sand(RS)dust emissions in the bauxite mining industry and causes serious environmental and safety detriments.Polymer stabilizer(PS)is one of the promising non-traditional stabilizers to mitigate such issues.This research investigated the unconfined compressive strength(UCS)of RS using synthetic polymer stabilizer(SPS)and natural polymer stabilizer(NPS),and to determine the optimum application concentration and mixing ratio of the PAM and Guar gum mixture.Results illustrated that PAM apparently outperform Guar gum in stabilizing sand particles.The mixture of PAM and Guar gum is more effective than individual use.The optimum polymer concentration and the mixing ratio are 0.94 wt.%and 0.6(PAM:total(PAM+Guar gum)),respectively.A rigorous regression model was developed to predict the UCS value based on application concentration and mixing ratio for the purpose of cost and time efficiency.展开更多
In order to investigate the influence of three key molar ratios （n（SiO2）/n（Al2O3）, n（K2O）/n（Al2O3） and n（H2O）/n（K2O））, a total of nine potassium poly-sialate-disiloxo （K-PSDS） geopolymeric cement matri...In order to investigate the influence of three key molar ratios （n（SiO2）/n（Al2O3）, n（K2O）/n（Al2O3） and n（H2O）/n（K2O））, a total of nine potassium poly-sialate-disiloxo （K-PSDS） geopolymeric cement matrices were designed according to orthogonal design principle. Subsequently, XRD, ESEM-EDXA and MAS-NMR techniques were employed to further characterize the microstructure of the most fully reacted geopolymeric cement matrix. The experimental results show that n（K2O）/n（Al2O3） has the most significant effect on compressive strength amongst the three ratios. The highest compressive strength （20.1 MPa） can be achieved when n（SiO2）/n（Al2O3）=6.5, n（K2O）/n（Al2O3）=0.8 and n（HEO）/n（K2O）=10.0. The FTIR spectra of nine PSDS geopolymeric cement matrices also indicate that geopolymeric cement matrix with the highest strength is the most fully reacted one and possesses the largest amount of geopolymeric cement products. The microscopic analysis reveals that PSDS geopolymeric cement matrix possesses structural characteristics similar to gel substances in having a wide range of Si endowments, but predominantly the framework molecular chains of Si partially replaced by 4-coordinated Al tetrahedral.展开更多
基金Project(2016YFC0501103)supported by the National Key Research and Development Program of ChinaProject(51574222)supported by the General Program of National Science Foundation of China+1 种基金Project(SKLCRSM15KF01)supported by Independent Research Projects of State Key Laboratory of Coal Resources and Safe Mining,CUMT,ChinaProject(2015)supported by the Mining Education Australia Collaborative Research Grant Scheme
文摘The residue drying area(RDA)is the major source of fugitive red sand(RS)dust emissions in the bauxite mining industry and causes serious environmental and safety detriments.Polymer stabilizer(PS)is one of the promising non-traditional stabilizers to mitigate such issues.This research investigated the unconfined compressive strength(UCS)of RS using synthetic polymer stabilizer(SPS)and natural polymer stabilizer(NPS),and to determine the optimum application concentration and mixing ratio of the PAM and Guar gum mixture.Results illustrated that PAM apparently outperform Guar gum in stabilizing sand particles.The mixture of PAM and Guar gum is more effective than individual use.The optimum polymer concentration and the mixing ratio are 0.94 wt.%and 0.6(PAM:total(PAM+Guar gum)),respectively.A rigorous regression model was developed to predict the UCS value based on application concentration and mixing ratio for the purpose of cost and time efficiency.
基金Project(2009CB623200) supported by the National Basic Research Program of ChinaProjects(50702014, 50878043) supported by the National Natural Science Foundation of ChinaProject(NCET-08-0116) supported by the Program for New Century Excellent Talents in University of Ministry of Education, China
文摘In order to investigate the influence of three key molar ratios （n（SiO2）/n（Al2O3）, n（K2O）/n（Al2O3） and n（H2O）/n（K2O））, a total of nine potassium poly-sialate-disiloxo （K-PSDS） geopolymeric cement matrices were designed according to orthogonal design principle. Subsequently, XRD, ESEM-EDXA and MAS-NMR techniques were employed to further characterize the microstructure of the most fully reacted geopolymeric cement matrix. The experimental results show that n（K2O）/n（Al2O3） has the most significant effect on compressive strength amongst the three ratios. The highest compressive strength （20.1 MPa） can be achieved when n（SiO2）/n（Al2O3）=6.5, n（K2O）/n（Al2O3）=0.8 and n（HEO）/n（K2O）=10.0. The FTIR spectra of nine PSDS geopolymeric cement matrices also indicate that geopolymeric cement matrix with the highest strength is the most fully reacted one and possesses the largest amount of geopolymeric cement products. The microscopic analysis reveals that PSDS geopolymeric cement matrix possesses structural characteristics similar to gel substances in having a wide range of Si endowments, but predominantly the framework molecular chains of Si partially replaced by 4-coordinated Al tetrahedral.
