A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diamino...A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.展开更多
Chial Complexes of Mn3+, Fe3+, Ni2+ and Cu2+ were prepared from chiral Schiff Base ligand obtained by condensation of new type methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate synthesized by this work with (1R,...Chial Complexes of Mn3+, Fe3+, Ni2+ and Cu2+ were prepared from chiral Schiff Base ligand obtained by condensation of new type methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate synthesized by this work with (1R, 2R)-1,2-diaminocyclohexane. The new chiral ligand and complexes were characterized by elementary analysis, 1H NMR, IR and UV-Vis.展开更多
New chiral lipophilic macrocyclic oxo polyamines derived from L glutamic acid and L aspartic acid,respectively,have been synthesized and characterized by MS, 1H NMR and elemental analysis.
文摘A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.
文摘Chial Complexes of Mn3+, Fe3+, Ni2+ and Cu2+ were prepared from chiral Schiff Base ligand obtained by condensation of new type methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate synthesized by this work with (1R, 2R)-1,2-diaminocyclohexane. The new chiral ligand and complexes were characterized by elementary analysis, 1H NMR, IR and UV-Vis.
文摘New chiral lipophilic macrocyclic oxo polyamines derived from L glutamic acid and L aspartic acid,respectively,have been synthesized and characterized by MS, 1H NMR and elemental analysis.
