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基于微结构定量分析的非饱和土广义有效应力原理 被引量:3
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作者 杨庆 张传庆 栾茂田 《大连理工大学学报》 EI CAS CSCD 北大核心 2004年第4期556-559,共4页
为解决各种概念分歧,采用神经网络方法建立了非饱和土的广义吸力模型.该模型理论突出了土的微结构效应,将微结构状态和含水量状态结合起来研究非饱和土的吸力和有效应力,认为广义吸力由土体微结构和含水状态惟一确定.
关键词 微结构定量分析 非饱和土 广义有效应力 吸力 土体 微结构力学 神经网络
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Li_(2)O-GeO_(2)二元系功能晶体的熔体微结构的拉曼光谱定量研究
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作者 赵玉帆 尤静林 +7 位作者 王世祥 刘国鹏 夏翔 解迎芳 盛美琴 徐飞燕 TANG Kai LU Liming 《无机化学学报》 北大核心 2025年第8期1533-1544,共12页
采用固相烧结法制备了Li_(4)GeO_(4)、Li_(6)Ge_(2)O_(7)、Li_(2)GeO_(3)和Li_(2)Ge_(2)O_(5)四种Li_(2)O-GeO_(2)二元系晶体,并通过原位高温拉曼光谱技术结合理论计算的方法对晶态到熔态的结构演变过程以及熔体微结构进行定性和定量分... 采用固相烧结法制备了Li_(4)GeO_(4)、Li_(6)Ge_(2)O_(7)、Li_(2)GeO_(3)和Li_(2)Ge_(2)O_(5)四种Li_(2)O-GeO_(2)二元系晶体,并通过原位高温拉曼光谱技术结合理论计算的方法对晶态到熔态的结构演变过程以及熔体微结构进行定性和定量分析。研究表明:Li_(4)GeO_(4)、Li_(6)Ge_(2)O_(7)和Li_(2)GeO_(3)熔体分别由[GeO_(4)]^(4-)、[Ge_(2)O_(7)]^(6-)、[GeO_(3)]^(2-)和Li^(+)构成,而Li_(2)Ge_(2)O_(5)晶体在升温至熔融状态过程中由[GeO_(4)]^(4-)四面体形成的三维网络结构逐渐向更小的[Ge_(3)O_(9)]^(6-)三元环递变。另外,通过量子化学从头计算法对团簇结构单元进行了设计、优化和计算,并将理论计算模拟与实验相结合,提出了一种校正熔体实验拉曼光谱的新方法。我们通过引入精细结构概念并利用高斯函数对拉曼光谱中[GeO_(4)]^(4-)四面体非桥氧的伸缩振动包络峰进行了分峰解谱,得到了这4种晶体在熔融状态下的不同结构(Qi,i表示每个[GeO_(4)]^(4-)四面体中桥氧的个数,i=0~4)单元含量的定量分布。 展开更多
关键词 Li_(2)O-GeO_(2)晶体 高温拉曼光谱 量子化学从头计算 微结构定量
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Mechanical properties and microscopic failure process of exemplary argillaceous interlayer from east China 被引量:1
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作者 SUN Shao-rui LIU Yong +5 位作者 HAO She-feng HE Wei HE Xun WEI Ji-hong YU Yong-xiang SONG Jing-lei 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第6期1973-1986,共14页
The landslide disaster caused by the argillaceous interlayer not only destroys buildings,cultivated land,and roads but also seriously endangers human life and safety.This study concerns the mineral composition of sele... The landslide disaster caused by the argillaceous interlayer not only destroys buildings,cultivated land,and roads but also seriously endangers human life and safety.This study concerns the mineral composition of selected argillaceous interlayer and their strength characteristics.To study the mineral composition of argillaceous interlayers,8 kinds of samples in the southern Jiangsu region of China were analyzed utilizing X-ray diffraction(XRD).The repeated direct shear strength tests(RDST)were carried out on the undisturbed specimens of the argillaceous interlayer.The results show that the argillaceous interlayer with high content of kaolinite shows ductile failure mode,which means that there is no obvious residual strength in the shear process.The arrangement of mineral particles on the shear surface of the specimens after different shear displacements was observed under the scanning electron microscope(SEM).It was observed that mineral particles on the shear surface showed a more directional arrangement with the increase of shear displacement.Furthermore,the influence of shear direction on the argillaceous interlayer with completely oriented mineral particles was studied through numerical experiments with four shear strength mechanisms proposition proposed.The influence of the mineral arrangement on the action occasion and magnitude of dilatancy component of shear strength is clarified in the shear mechanism. 展开更多
关键词 argillaceous interlayer microcosmic structure strength component directional arrangement discrete element method LANDSLIDES
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