2017 aluminum alloy plates with an ultrafine grained （UFG） structure were produced by equal channel angular processing （ECAP） and then were joined by underwater friction stir welding （underwater FSW）. X-ray diff...2017 aluminum alloy plates with an ultrafine grained （UFG） structure were produced by equal channel angular processing （ECAP） and then were joined by underwater friction stir welding （underwater FSW）. X-ray diffractometer （XRD）, transmission electron microscope （TEM）, scanning electron microscope （SEM） and microhardness tester were adopted to investigate the microstructural and mechanical characteristics of the FSW joint. The results indicate that an ultrafine grained microstructure with the mean grain size of-0.7 Ixm is obtained in the weld nugget by using water cooling. However, The FSW joint exhibits softening compared with the ultrafine grained based material and the heat affected zone （HAZ） has the lowest hardness owing to the coarsening of the strengthening precipitates.展开更多
In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal...In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal conductivities of the prepared glass ceramics were investigated by using X-ray diffractometer, scanning electron microscopy, vibrating sample magnetometer and thermophysical properties tester, respectively. The results show that orthorhombic olivine-type phase and triclinic sunstone-type phase formed when the glass was annealed at 700 oC, the concentration of olivine-type and sunstone-type phases decreased, the spinel-type cubic phase occurred and the amount increased when the annealing temperatures increased. The magnetic properties from the cubic spinel ferrites were detected in the glass ceramics, and the related saturation magnetization increased with the annealing temperature increasing. The porous glass ceramics with magnetic property showed much lower thermal conductivity, compared with the non-magnetic porous glass-ceramic and the dense glass-ceramics.展开更多
Alkali metal(Li, Na, K) doped ZnO powders were synthesized by solid-state reaction at different calcination temperatures and holding time. Effects of holding time and K sources on the infrared emissivity of ZnO were i...Alkali metal(Li, Na, K) doped ZnO powders were synthesized by solid-state reaction at different calcination temperatures and holding time. Effects of holding time and K sources on the infrared emissivity of ZnO were investigated. The structure and surface morphologies of samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The UV-Vis absorption and infrared emissivities were investigated by a UV-Vis spectrophotometer and an infrared emissometer, respectively. XRD patterns confirm the wurtzite structure of the as prepared samples with single phase. Smooth grain surfaces are detected in all doped ZnO samples, while ZnO:Li and ZnO:Na present the aggregation of grains. The redshifts in the optical band-gap are observed in K-, Na-, and Li-doped ZnO with the values 3.150, 3.144, and 3.142 eV. Due to better crystalline quality, ZnO:K shows a lower emissivity than others. The emissivity of K-doped ZnO decreases to the minimum value(0.804), at 1200 °C and holding 2 h. Compared with KNO3 as K source, K2CO3 doped ZnO has lower emissivities.展开更多
Large scaled uniform and size-controllable magnetic submicroparticles(MSPs) were synthesized via solvothermal method with ferric chloride as iron source and sodium acetate as trapping agent. The influence of Fe^(3+) a...Large scaled uniform and size-controllable magnetic submicroparticles(MSPs) were synthesized via solvothermal method with ferric chloride as iron source and sodium acetate as trapping agent. The influence of Fe^(3+) and Na Ac contents on the size distribution of MSPs was investigated. The structural and morphological properties of the synthesized particles were studied by scanning electron microscopy(SEM), X-ray power diffraction(XRD) and vibrating sample magnetometer(VSM). The well-dispersed MSPs with size of 100-1000 nm were obtained by simply adjusting the contents of Fe^(3+) and NaA c. In addition, the hemolysis and cytotoxicity of Fe_3O_4 MSPs, and their ability to case arrest in cell life-cycles were studied. The results indicate that larger size could lead to lower hemolysis. From MTT(3-(4,5-dimethylthuazol-2-yl)-2,5-diphenyltetrazolium bromide) assay, the interactions between MSPs and adhesive mouse fibroblast cell line(L929) were probed. Larger size of Fe_3O_4 MSPs demonstrates lower cell viability following an exposure to the cells.展开更多
Li2Fe0.5Mn0.5SiO4 material was synthesized by a citric acid-assisted sol-gel method. The influence of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+) on the electrochemical properties of Li2Fe0.5Mn0.5...Li2Fe0.5Mn0.5SiO4 material was synthesized by a citric acid-assisted sol-gel method. The influence of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+) on the electrochemical properties of Li2Fe0.5Mn0.5SiO4 was studied. The final sample was identified as Li2Fe0.5Mn0.5SiO4 with a Pmn21 monoclinic structure by X-ray diffraction analysis. The crystal phases components and crystal phase structure of the Li2Fe0.5Mn0.4SiO4 material were improved as the increase of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+). Field-emission scanning electron microscopy verified that the Li2Fe0.5Mn0.5SiO4 particles are agglomerates of Li2Fe0.5Mn0.5SiO4 primary particles with a geometric mean diameter of 220 nm. The Li2Fe0.5Mn0.5SiO4 sample was used as an electrode material for rechargeable lithium ion batteries, and the electrochemical measurements were carried out at room temperature. The Li2Fe0.5Mn0.5SiO4 electrode delivered a first discharge capacity of 230.1 mAh/g at the current density of 10 mA/g in first cycle and about 162 mAh/g after 20 cycles at the current density of 20 mA/g.展开更多
A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were pre...A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were prepared by chemical coprecipitation method. Scanning electron microscope (SEM) and vibrating sample magnetometer (VSM) were used to identify its surfacetopography and magnetization, respectively. Laccase was immobilized on the MMCNT modified magnetic carbon paste electrode by the aid of chitosan/silica (CS) hybrid membrane. Using current-time detection method, the biosensor shows a linear response related to the concentration of catechol in the range from 10-7 to 0.165×10-3 mol/L. The corresponding detection limit is 3.34×10-8 mol/L based on signal-to-noise ratios (S/N) ≥3 under the optimized conditions. In addition, its response current retains 90% of the original after being stored for 45 d. The results indicate that this proposed strategy can be expected to develop other enzyme-based biosensors.展开更多
基金Projects(50774059, 51074119) supported by the National Natural Science Foundation of China
文摘2017 aluminum alloy plates with an ultrafine grained （UFG） structure were produced by equal channel angular processing （ECAP） and then were joined by underwater friction stir welding （underwater FSW）. X-ray diffractometer （XRD）, transmission electron microscope （TEM）, scanning electron microscope （SEM） and microhardness tester were adopted to investigate the microstructural and mechanical characteristics of the FSW joint. The results indicate that an ultrafine grained microstructure with the mean grain size of-0.7 Ixm is obtained in the weld nugget by using water cooling. However, The FSW joint exhibits softening compared with the ultrafine grained based material and the heat affected zone （HAZ） has the lowest hardness owing to the coarsening of the strengthening precipitates.
基金Project(51172287)supported by the National Natural Science Foundation of ChinaProject(2012-2013)supported by the Laboratory Research Fund of the State Key Laboratory of Powder Metallurgy,China
文摘In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal conductivities of the prepared glass ceramics were investigated by using X-ray diffractometer, scanning electron microscopy, vibrating sample magnetometer and thermophysical properties tester, respectively. The results show that orthorhombic olivine-type phase and triclinic sunstone-type phase formed when the glass was annealed at 700 oC, the concentration of olivine-type and sunstone-type phases decreased, the spinel-type cubic phase occurred and the amount increased when the annealing temperatures increased. The magnetic properties from the cubic spinel ferrites were detected in the glass ceramics, and the related saturation magnetization increased with the annealing temperature increasing. The porous glass ceramics with magnetic property showed much lower thermal conductivity, compared with the non-magnetic porous glass-ceramic and the dense glass-ceramics.
基金Project(JB141405)supported by the Fundamental Research Funds for the Central Universities of China
文摘Alkali metal(Li, Na, K) doped ZnO powders were synthesized by solid-state reaction at different calcination temperatures and holding time. Effects of holding time and K sources on the infrared emissivity of ZnO were investigated. The structure and surface morphologies of samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The UV-Vis absorption and infrared emissivities were investigated by a UV-Vis spectrophotometer and an infrared emissometer, respectively. XRD patterns confirm the wurtzite structure of the as prepared samples with single phase. Smooth grain surfaces are detected in all doped ZnO samples, while ZnO:Li and ZnO:Na present the aggregation of grains. The redshifts in the optical band-gap are observed in K-, Na-, and Li-doped ZnO with the values 3.150, 3.144, and 3.142 eV. Due to better crystalline quality, ZnO:K shows a lower emissivity than others. The emissivity of K-doped ZnO decreases to the minimum value(0.804), at 1200 °C and holding 2 h. Compared with KNO3 as K source, K2CO3 doped ZnO has lower emissivities.
基金Project(2013DFA5129)supported by the International Science and Technology Cooperation Program of China
文摘Large scaled uniform and size-controllable magnetic submicroparticles(MSPs) were synthesized via solvothermal method with ferric chloride as iron source and sodium acetate as trapping agent. The influence of Fe^(3+) and Na Ac contents on the size distribution of MSPs was investigated. The structural and morphological properties of the synthesized particles were studied by scanning electron microscopy(SEM), X-ray power diffraction(XRD) and vibrating sample magnetometer(VSM). The well-dispersed MSPs with size of 100-1000 nm were obtained by simply adjusting the contents of Fe^(3+) and NaA c. In addition, the hemolysis and cytotoxicity of Fe_3O_4 MSPs, and their ability to case arrest in cell life-cycles were studied. The results indicate that larger size could lead to lower hemolysis. From MTT(3-(4,5-dimethylthuazol-2-yl)-2,5-diphenyltetrazolium bromide) assay, the interactions between MSPs and adhesive mouse fibroblast cell line(L929) were probed. Larger size of Fe_3O_4 MSPs demonstrates lower cell viability following an exposure to the cells.
基金Projects(13A047,10B054)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProjects(2011GK2002,2011FJ3160)supported by the Planned Science and Technology Project of Hunan Province,China
文摘Li2Fe0.5Mn0.5SiO4 material was synthesized by a citric acid-assisted sol-gel method. The influence of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+) on the electrochemical properties of Li2Fe0.5Mn0.5SiO4 was studied. The final sample was identified as Li2Fe0.5Mn0.5SiO4 with a Pmn21 monoclinic structure by X-ray diffraction analysis. The crystal phases components and crystal phase structure of the Li2Fe0.5Mn0.4SiO4 material were improved as the increase of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+). Field-emission scanning electron microscopy verified that the Li2Fe0.5Mn0.5SiO4 particles are agglomerates of Li2Fe0.5Mn0.5SiO4 primary particles with a geometric mean diameter of 220 nm. The Li2Fe0.5Mn0.5SiO4 sample was used as an electrode material for rechargeable lithium ion batteries, and the electrochemical measurements were carried out at room temperature. The Li2Fe0.5Mn0.5SiO4 electrode delivered a first discharge capacity of 230.1 mAh/g at the current density of 10 mA/g in first cycle and about 162 mAh/g after 20 cycles at the current density of 20 mA/g.
基金Project(IRT0719) supported by the Program for Changjiang Scholars and Innovative Research Team in University, ChinaProjects (50978088, 51039001) supported by the National Natural Science Foundation of China+3 种基金Project(2009FJ1010) supported by the Hunan Key Scientific Research Program, ChinaProject(10JJ7005) supported by the Natural Science Foundation of Hunan Province, ChinaProjects(CX2009B080, CX2010B157) supported by the Hunan Provincial Innovation Foundation For PostgraduateProject supported by the Fundamental Research Funds for the Central Universities, Hunan University, China
文摘A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were prepared by chemical coprecipitation method. Scanning electron microscope (SEM) and vibrating sample magnetometer (VSM) were used to identify its surfacetopography and magnetization, respectively. Laccase was immobilized on the MMCNT modified magnetic carbon paste electrode by the aid of chitosan/silica (CS) hybrid membrane. Using current-time detection method, the biosensor shows a linear response related to the concentration of catechol in the range from 10-7 to 0.165×10-3 mol/L. The corresponding detection limit is 3.34×10-8 mol/L based on signal-to-noise ratios (S/N) ≥3 under the optimized conditions. In addition, its response current retains 90% of the original after being stored for 45 d. The results indicate that this proposed strategy can be expected to develop other enzyme-based biosensors.
